Calculation of the PrCl3-CaCl2-MgCl2 Phase Diagram-中国期刊网

摘要 Basedonthethermodynamicallyself-consistentanalysisandoptimizationofthreesub-binarysystemsoftheternarysystemPrCl3-CaCl2-MgCl2,thethermodynamicsofthisternarysystemhasbeenstudied.UsingHillertmodelandtakingMgCl2asanasymmetriccomponent,thePrCl3-CaCl2-MgCl2phasediagramhasbeencalculated.Theagreementbetweencalculatedandmeasuredcompositionsandtemperaturesatdeflectingpointsonliquidusisgood.Thesystemisasimpleeutecticonewithaeutecticpointat26.0mol%PrCl3,41.5mol%CaCl2,32.5mol%MgCl2;560℃（calculated）and26.0mol%PrCl3,39.4mol%CaCl2,34.6mol%MgCl2;546℃（measured）,respectively.

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Calculation of the PrCl3-CaCl2-MgCl2 Phase Diagram

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Calculation of the PrCl3-CaCl2-MgCl2 Phase Diagram

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