摘要
Twohydrogen-bondingadsorbents-macroporouscrosslinkedpoly(P-nitrostyrene)andpoly(p-vinylbenzylamide)-weresynthesized,andtheadsorptionpropertyofphenolfromcyclohexanesolutionontotheadsorbentswasstudied,ThedifferentialadsorptionheastsforvariedadsorptioncapacitiescalculatedfromtheadsorptionisothermsaccordingtotheClaperyron-Clausiusequationlayintherangeofhydrogenbondenergy(8-50kJ/mol),Theadsorptioncapaccityofo-nitrophenolincyclohexanewasmochlessthanthatofphenolunderthesamecondition.Theadsorptioncapacityofphenolfromcyclohexaneontopolyacrylonitrilewasmuchlessthanthatontopoly(p-nitrostyrene)orpoly(p-vinylbenzylamide),Alltheseresultsrevealedthatadsorptionofphenolfromcyclohexanebypoly(p-nitrostyrene)orpoly(p-vinylbenzylamide)isbasedonhydrogen-bonding.
出版日期
2000年01月11日(中国期刊网平台首次上网日期,不代表论文的发表时间)