简介:ThemaindisadvantageofmicroporousSSZ-13catalystusedinthemethanoltoolefins(MTO)processisitsrapiddeactivationduetoitsrelativelylowcokeresistance.Meanwhile,thehierarchicalzeolitesusuallyexhibitimprovedcatalyticstabilitythankstotheirbettermasstransferability.Herein,thehierarchicallynanoporousSSZ-13zeoliteswereone-potsynthesizedbyusingN,N,N-trimethyl-1-adamantanammoniumhydroxideasamicroporousstructuredirectingagentandC18H37N+(CH3)2C6H12N+(CH3)2C6H13(Br-)2(hereinafterabbreviatedasC18-6-6Br2)asamesoporogen.ThehierarchicallynanoporousSSZ-13catalystwascharacterizedbyXRD,N2physisorption,SEM,TEM,TG-DTG,27Aland29SiNMRspectroscopyandNH3-TPDtechniques.TheresultsshowedthatthehierarchicalSSZ-13zeolitesynthesizedinthepresenceoftheC18-6-6Br2surfactantexhibitsaggregatesofprimarynanocrystalsandcontainsthewell-developedmesoporesandexcellentacidity.Comparedtoitsconventionalcounterpart,thehierarchicalSSZ-13zeolitehaslongercatalyticlifetimeandhigherselectivityforethyleneandpropyleneintheMTOreaction,whichcanbeattributedtothesynergisticeffectoftheirgoodacidityandimproveddiffusionpropertiesresultedfromthehierarchicalporestructure.
简介:Inordertostudytheflammabilityandexplosionpropertyofgasesduringthepropaneoxidationtoacrylicacidprocess,theexplosionlimitsandthesafetyoxygencontentofgasesattherecyclegascompressoroutlet,thereactorinlet,andthereactoroutletweretheoreticallycalculatedandexperimentallytested.Finally,theinertlimitwasalsodetermined.Itshowedthatgasesattherecyclegascompressoroutletandthereactoroutletwerenonflammablebasedonthreeindicators:theexplosionlimits,thesafetyoxygencontentandtheinertlimit.TheC3H6andO2contentswerehigheratthereactorinlet,whichmadethemixedgaseseasilyignitable.However,thelargeamountofinertgasessuppressedthepossibilityofexplosioneffectively.Asaconsequence,noexplosionphenomenonwouldhappeninallthreelocations.Butgasesatthereactorinletaremostdangerous,wheremoresupervisionontheconcentrationofgasesandmorestrictcontrolonthetemperatureandpressureshouldbeimplemented.Besidesthis,openflame,hotsurfacesandothersourcesofignitionareprohibitedinworkingspaces.Theexperimentalresultscanbeappliedtosimilarprocessforoxidationofpropane.
简介:TheYangziPetrochemicalCompanyisthefirstoneamongdomesticaromaticsmanufacturerstoadopttheUOP’slatestnoveladsorbentduringqualityupgradingofitsNo.2xyleneunit.OnOctober23,2013thisunithasbeencontinuouslydeliveringxyleneproductwithapurityof
简介:ThenickelcatalystSHN-01/Fforone-stagehydrotreatingofpyrolysisgasolinedevelopedbySINOPECShanghaiPetrochemicalResearchInstitutehassuccessfullycompletedcommercialtests,symbolizingthebeginningofcommercialapplicationphaseofthisnickel-basedcatalystforone-stagehydrotreatingofpyrolysisgasolinewithSINOPEC'sindependentintellectualpropertyrights.
简介:根据新成立的海湾石化和化工协会(GPCA)宣称,海湾合作集团(GCC)国家在2007年期间将可能向全球市场出售超过6千万吨的石油化工产品。SABIC的副总裁和首席执行官AlMady兼任GPCA的主席,他说,GCC国家对于全球的石化和化学工业具有极端重要的意义。估计到2010年前这一地区这两个工业领域将增长13%。GCC在石化、化工领域的优势得益于原料的充沛供应、最新型的技术及其处于美洲、亚洲和世界其他地区交叉点上的优越地理位置。而且该地区市场上资金充足,更增加了其竞争力。而建设和劳务费用又相对低廉,对外国投资者的税收政策也很优惠。