简介:TheinfluenceofNa2SO4ontheformationofZnOwhiskerswasinvestigatedinthispaper.ZnOwhiskerswithaspectratiosofupto50weresynthesizedbydissolvingε-Zn(OH)2precursorinNaOH/Na2SO4solutionatroomtemperature,followedbyagingoftheresultingsolutionat140℃for6h.Fouriertransforminfraredspectroscopy,Ramanspectroscopy,andX-rayphotoelectronspectroscopyanalysesrevealedthatSO42-ionswereprimarilyadsorbedonthe(100)planeoftheZnOwhiskersviaanouter-spherecomplexconfiguration(O-H…O),therebypromotingtheone-dimensionalgrowthofZnOwhiskersalongthec-axis.
简介:针对传统天文导航方法和GNSS导航方法应用于中高轨道航天器尤其是大椭圆轨道机动航天器自主导航的缺陷,提出一种基于低轨道天基平台实时跟踪观测的轨道机动航天器在轨绝对导航方法。其具体实施过程为布置于低轨道的天基平台利用其自带观测敏感器对轨道机动航天器进行全程实时跟踪测量,并将测量所得的星光角距信息和测距信息发送至轨道机动航天器,航天器根据接收得的量测信息结合自身状态预估信息通过最优滤波估计算法实现导航解算。仿真结果表明该方案具备较强的可行性,且该导航系统具有较高的导航估计精度,能够弥补传统天文导航和GNSS导航方法的不足之处,当天基平台自主定轨精度为80m时轨道机动航天器导航位置估计误差在120m以内。
简介:TiO2nanoparticlesweresynthesizedbyahomogeneouscontrolledprecipitationmethodusingindustrialtitaniumsulfate(Ti(SO4)2).TheobtainedpowderswerecharacterizedbyX-raydiffraction(XRD),transmissionelectronmicroscope(TEM),Fouriertransforminfraredspectroscopy(FTIR)andICPplasmaspectrometer.EDTAwasusedascomplexingagenttoimprovethepurityandtheformationofTiO2nanoparticles.Experimentalresultsindicatedthatthehigh-purityTiO2nanoparticleswere20nminmeansizeandnearlymonodispersed.
简介:AlaminarpremixedPropane/Airflamewithafuelequivalenceratioof2.1wasemployedforanalysisofsootparticles.Zeroth-orderIognormaldistributions(ZOLD)wereusedintheanalysisofexperimentaldistributionphenomenaatdifferentresidencetimesduringsootformationintheflame.Rayleigh'stheoryandMie'sscatteringtheorywerecombinedwithagglomerateanalysisusingscatteringandextinctiondatatodeterminethefollowingsootcharacteristics:agglomerateparameters,volumetricfractions,massflowratesandsurfacegrowthrate.Sootdensitymeasurementswerecarriedouttodeterminedensityvariationsatdifferentstagesofgrowth.Themeasuredresultsshowthatmetricfractionandmassflowrateindicatethatthesurfacegrowthrateofsootparticlesexceedstheoxidationratesintheflamestudied.Thedataobtainedinthisworkwouldbeusedtostudysootoxidationrateunderflamingcondition.
简介:ThecharacteristicsofsuspendedsedimentimagecanbereflectedbythecoefficientsofbiorthogonalwavelettransformofCDF(2,2).Basedonthepowerdistributionindifferentscales,anadaptivealgorithmisproposedinthispaper,wherebythecoefficientsareadjustednon-linearly.Theparticleinformationcanbewellretainedwhiletheuselessbackgroundisremoved.Inthisway,satisfactorybinaryimagecanbeobtainedforfurtheranalysisofthesedimentparticle.
简介:Duetotheirsize-dependentpropertiesandflexibleprocessingchemistry(Alivisatos,1996),monodispersednanocrystalshaveattractedconsiderableattentionfortheirdistinguishedroleinfundamentalstudiesandtechnicalapplications.AlthoughmuchhasbeenreportedonfabricationofmonodispersedinorganicnanocrystalssuchasFe2O3,CdSe,PbSeandZrO2(Peng&Peng,2002;Zhuetal.,2002;Niederbergeretal.,2002;Pangetal.,2001),littlepublishedonthepreparationofBaSO4nanocrystalsandtheircrystalsizeandmorphologywhichaffecttheirperformanceinapplication.PolymeradditiveswithcomplexfunctionshavebeenusedastemplatestodirectorientednucleationandgrowthofBaSO4(Xiaoetal.,2001;Yuetal.,2002;Summersetal.,2002),asanewclassoffunctionalpolymers,theso-calleddouble-hydrophilicblockcopolymers,designedtocontrolthemorphologyofBaSO4(Colfenetal.,2002),includingtheirnanofiberssynthesizedinAOTmicroemulsion(Li&Mann,2000).ThoughsomuchresearchhasbeendevotedtocontrollingtheBaSO4morphologies,thepresentnotewillreportonthesynthesisofBaSO4nanocrystalswithsizecontrolling.
简介:TiO2@ZrO2@Y2O3:有coremultishell结构的Eu3+合成粒子通过layer-by-layer(LBL)的联合被综合自己组装方法和一个solgel过程。获得的样品与扫描电子被描绘显微镜学(SEM),传播电子显微镜学(TEM),X光检查光电子光谱学(XPS),X光检查衍射(XRD),和荧光spectrophotometry。结果证明合成粒子有coremultishell结构,球形的形态学,和狭窄的尺寸分布。TiO2核心上的ZrO2层的存在能有效地阻止在TiO2核心和Y2O3壳之间的反应;为在在TiO2@ZrO2@Y2O3的TiO2核心和Y2O3壳之间的反应的温度:Eucoremultishell黄磷能被300提高
简介:PureAl2O3-2SiO2powderswerepreparedbysol-gelandcoprecipitationmethods,andtheiralkaliactivationreactivitieswerecompared.Thealkali-activationreactivityofthepowderpreparedbythesol-gelmethodwashigherthanthatofthepowderpreparedbythecoprecipitationmethod.Thepowderswereinvestigatedby27AIand29Simagic-anglespinningnuclearmagneticresonancespectroscopy(MASNMR)tounderstandtherelationshipbetweentheirstructureandalkali-activationreactivity.The27AlMASNMRdatashowedthatthefive-coordinateAIcontentofthepowderpreparedbythesol-gelmethodwashigherthanthatofthepowderpreparedbycoprecipitation.Thehighercontentoffive-coordinateAlcorrespondedtohigheralkali-activationreactivity.The29SiMASNMRdatashowedthatforthepowderpreparedbythesol-gelmethod,siliconwasreplacedbyaluminumatsecondarycoordinationsitesofthecentralSiatomsduringcalcination.However,forthepowderpreparedbysingle-batchcoprecipitation,themainchangewasfromalowdegreeofpolycondensationtoahighdegreeofpolycondensation.
简介:Well-dispersedBaSO4nanoparticlesweresynthesizedinthepresenceofsodiumpolyacrylate(PAAS)byasimpleprecipitationmethod,withBaCl2and(NH4)2SO4asreactants.ThedifferentrolesperformedbyPAASinthesynthesisofBaSO4nanoparticleswereinvestigatedusingX-raydiffractometry,Fouriertransforminfraredspectroscopy,andtransmissionelectronmicroscopy.TheresultsindicatethattheassynthesizedBaSO4nanoparticlesweresphereswithanaveragediameterof30nmandthattheirsurfaceswereaffectedbythePAAS.Underatypicalprocedureemployed,PAASreactedwithBaCl2toyieldanintermediate,servingasacontrolreleasingagentandseparatingthenucleationandcrystalgrowthprocessesoftheBaSO4nuclei.DuringformationoftheBaSO4nanospheres,theintermediateslowlydissolvedandreleasedbariumandpolyacrylateions,inhibitingthegrowthandaggregationofnewlyformedBaSO4seedsandresultinginparticlesofnarrowdiameterdistributionandimproveddispersibility.Moreover,thesepolyacrylateionsfurthermodifiedthesurfacesoftheBaSO4nanoparticles.
简介:HomogeneousNi2+-dopedtitaniagelwassynthesizedbyasol-gelprocess,andthexerogelwasthenobtainedthroughaginganddrying,leadingtotheformationofNi/TiO2nanocompositeafterheattreatmentunderasuitablereducingatmosphere.TheresultingnanocompositewascharacterizedbyTGA-DSC,TEM,XRDandBETmethods.Theresultsshowthatthestructureandgrainsizeofthenanocompositescouldbemanipulatedbyalteringtheheat-treatmentconditions,andthatthenanocompositepossessesamesoporousstructurewithaporeradiusofca.28nmandaspecifictheanatase-rutilephasetransformation.
简介:DrivenbycuriosityaboutpossibleflightoptionsfortheChang’e-2spacecraftafteritremainsattheSun-EarthL2point,effectiveapproachesweredevelopedfordesigningpreliminaryfuel-optimalnear-Earthasteroidflybytrajectories.Theapproachesincludetheuseofmodifiedunstablemanifolds,gridsearchofthemanifolds’parameters,andatwo-impulsemaneuverfororbitalphasematchingandz-axisbiaschange,andaredemonstratedtobeeffectiveinasteroidtargetscreeningandtrajectoryoptimization.Asteroidflybysareexpectedtobewithinadistanceof2×107kmfromtheEarthowingtotheconstrainedEarth-spacecraftcommunicationrange.Inthiscase,thespacecraft’sorbitalmotionissignificantlyaffectedbythegravitiesofboththeSunandtheEarth,andtherefore,theconceptofthe"heliocentricoscillating-Keplerorbit"isproposed,becausetheclassicalorbitalelementsoftheflybytrajectoriesreferencedintheheliocentricinertialframeoscillatesignificantlywithrespecttotime.Theanalysisandresultspresentedinthisstudyshowthat,amongtheasteroidswhoseorbitsarethemostaccuratelypredicted,"Toutatis","2005NZ6",or"2010CL19"mightbeencounteredbyChang’e-2inlate2012or2013withtotalimpulseslessthan100m/s.
简介:Fatiguepropertiesofage-hardenedAlalloy2017-T4underultrasonicloadingfrequency(20kHz)wereinvestigatedandcomparedwiththeresultsunderconventionalloadingofrotatingbending(50Hz).Thegrowthofacrackretardedatabout500μminsurfacelengthunderultrasonicloading,whileatabout20μmunderrotatingbending.Althoughstriationsbeingatypicalfracturemechanismwereobservedunderconventionalloading,mostoffracturesurfacewascoveredwithmanyfacetsunderultrasonicloading.Thesefacetswerealsoobservedunderrotatingbendinginnitrogengas.Thedifferenceingrowthmechanismdependingontheloadingfrequencyandtheretardationofacrackgrowthunderultrasonicloadingmaybecausedbytheenvironmentatthecracktipduetohighcrackgrowthrateunderultrasonicloading.
简介:有从30~80nm的尺寸的Fe3O4nanoparticles被湿milling铁粉末在一家行星的球工厂综合。阶段作文和同样综合的产品的形态学被X光检查衍射(XRD)测量,扫描电子显微镜学(SEM)和传播电子显微镜学(TEM)。NanosizedFe3O4粒子被湿milling准备金属性的铁粉末(?200网孔,99%)在与不锈钢装备的一家行星的球工厂,使用的小瓶与50:1并且以300rpm的旋转速度的ball-to-powder团比率在提取的水下面熨球。在这个方法的铁球的使用在Fe3O4formation起了一个关键作用。现在的技术简单,这个过程是容易的执行。
简介:Lithium-aluminum-cobalt-nickeloxideLiAlxCoyNi1xyO2particles,generallyusedascathodeoflithiumbattery,werepreparedbychemicalcoprecipitationfromanaqueoussolutionofLiOH,Al(NO3)3,Co(NO3)2andNi(NO3)2withNH4OH.XRD,SEMandFTIRwereusedtoexaminetheeffectofnickelcontentontheproduct.FTIRpatternsshowedthatincreaseinnickelcontentdecreasedtheabsorptionstrengthofthepeakofspinelstructureoftheproduct,attributedtotheoccupationbynickelinthealuminumsites.Particlesizeandelectricalpropertiesofthelithium-aluminum-cobalt-nickeloxide(abbreviatedasLACNO)particleswerealsodetermined.