简介:AUltrafineamorphousNiBalloywaspreparedviachemicalreductionmethod;ItsstructuresduringthecrystallizatioinprecesswascharacterizedbysuchtechniquesasDifferentialthermalanalysis(DTA),X-rayabsorptionfinestructure(XAFS)andX-raydiffraction(XRD),andcorrelatedtothecatalyticpropertiesforbenzenehydrogenation.ItwasfoundthatthecrystallizationofamorphousNiBalloywascarriedoutintwosteps,asindicatedbytwoexothermicpeakscenteredat598and652Krespectively.Duringthefirststep.twometastablecrystallinephases,i.e.,Ni3BandanoaocrstallineNiphase(Ni-richNiBalloy),wereformed.Furtherannealingathighertemperatureof652KmayresultinthedecompositionofcrystallineNi3BandaggregationofnanocrystallineNi,thebenzenehydrogenationisoptimizedaroundtheannealingtemperatureof623K.ItmostprobablyresultsfromthemaximumamountofactivesiteonnanocrystallineNiformedbythermaltreatmentatappropriateannealingtemperature.
简介:Tetrahedralamorphoushydrogenatedcarbon(ta-C:H)filmsonSi(lO0)substrateswerepreparedbyusingamagnetic-field-filterplasmastreamdepositionsystem.Sampleswithdifferentratiosofsp^3-bondtosp^2-bondwereobtainedbychangingthebiasvoltageappliedtothesubstrates.Theellipsometricspectraofvariouscarbonfilmsinthephotonenergyrangeof1.9-5.4eVweremeasured.Therefractiveindexnandtherelativesp^3CratioofthesefilmswereobtainedbysimulatingtheirellipsometricspectrausingtheForouhi-BloomermodelandbyusingtheBruggemaneffectivemediumapproximation,respectively.Thehaemocompatibilityoftheseta-C:Hfilmswasanalysedbyobservationofplateletadhesionandmeasurementofkineticclottingtime.Theresultsshowthatthesp^3Cfractionisdependentonthesubstratebiasvoltage,andthehaemocompatibilityisdependentontheratioofsp^3-bondtosp^2-bond.Agoodhaemocompatibilitymaterialofta-C:Hfilmswithasuitablesp^3Cfractioncanbepreparedbychangingthesubstratebiasvoltage.
简介:Wepresentintegrated-opticbuildingblocksandfunctionalphotonicdevicesbasedonamorphoussiliconon-insulatortechnology.Efficientdeep-etchedfiber-to-chipgratingcouplers,low-losssingle-modephotonicwirewaveguides,andcompactpowersplittersarepresented.Basedonthesub-μmphotonicwires,2×2Mach–Zehnderinterferometersandadd/dropmicroringresonators(MRRs)withlowdevicefootprintsandhighfinesseupto200wererealizedandstudied.Compactpolarizationrotatorsandsplitterswith≥10dBpolarizationextinctionratiowerefabricatedforthepolarizationmanagementon-chip.Thetuningandtrimmingcapabilitiesofthematerialplatformaredemonstratedwithefficientmicroheatersandapermanentdevicetrimmingmethod,whichenabledtherealizationofenergy-efficientphotoniccircuits.Wavelengthmultiplexersintheformofcascadedfilterbanksand4×4routersbasedonMRRswitchesarepresented.Fabricationimperfectionswereanalyzedandpermanentlycorrectedbyanaccuratelaser-trimmingmethod,thusenablingeight-channelmultiplexerswithrecordlowmetricsofsub-mWstaticpowerconsumptionand≤1°Ctemperatureoverhead.Thehighqualityofthefunctionaldevices,thehightuningefficiency,andtheexcellenttrimmingcapabilitiesdemonstratethepotentialtorealizelow-cost,denselyintegrated,andultralow-power3D-stackedphotoniccircuitsontopofCMOSmicroelectronics.
简介:在不同温度的非结晶的CuHf合金的结构的因素由使用高温度X光衍射计的redetermined。theshort范围顺序结构而且中等范围的顺序结构在非结晶的CuHfalloys存在,这被发现不仅。合金融化的CuHf的动态粘性被扭力的摆动粘度计测量。脆弱过热CuHf合金融化基于粘性数据被计算。形成CuHf的能力的玻璃是的试验性的结果表演仔细与脆弱有关他们的超级加热融化。在中等范围顺序结构和脆弱之间的关系过热融化也在非结晶的CuHfalloys被建立了。与supercooled液体的脆弱相对照,过热的液体的脆弱答应一条更好的途径到反映形成液体的玻璃的动力学。
简介:内在的hydrogenated非结晶的硅(a-Si:H)电影在n类型上被扔由到分析的热电线的化学蒸汽免职(HWCVD)的水晶的硅(c-Si)晶片非结晶/水晶的heterointerface钝化性质。对称的heterostructure的少数搬运人一生被使用请教WCT-120一生测试者系统,和决定从一生测量的接口状态密度被建议的一个简单方法的Sinton测量。接口状态密度测量被使用深水平的短暂光谱学(DLTS)证明简单方法的有效性也执行。微观结构和a-Si的氢结合配置:有不同的氢冲淡的H电影被使用分光镜的ellipsometry(SE)和Fourier变换调查红外线的光谱学(FTIR)分别地。接口状态密度的更低的值被使用a-Si获得:有水晶的硅上的更一致的、紧缩的微观结构和更少体积缺点的H电影由HWCVD扔了。
简介:WedemonstrateafacilerouteforthemassiveproductionofSnCb/carbonnanocompositeusedashigh-capacityanodematerialsofnextgenerationlithium-ionbatteries.ThenanocompositehadauniquestructureofultrafineSnO2nanocrystals(5nm,80wt%)homogeneouslydispersedinamorphouscarbonmatrix.ThisstructuredesigncanwellaccommodatethevolumechangeofLi+insertion/desertioninSnO2,andpreventtheaggregationofthenanosizedactivematerialsduringcycling,leadingtosuperiorcycleperformancewithstablereversiblecapacityof400mAh/gatahighcurrentrateof3.3A/g.
简介:Theglass-formingability(GFA)andmagneticpropertiesoftheGd_(50)Coso-basedamorphousaiioywithAladditionsubstitutionforCoareinvestigated.ItisfoundthattheGFAandmagneto-caloriceffectoftheGd_(50)Co_(45)Al_5amorphousaiioyarebetterthanGd_(50)Co_(50)amorphousalloy.Themaximummagneticentropychange(-△S_m~(peak))andthemagneticrefrigerantcapacityoftheamorphousalloyunderafieldof5Tareabout6.64J·kg~(-1)K~(-1)and764J·kg~(-1),respectively.Thefielddependenceofmagneticentropychangemeetstheonepredictedbythemeanfieldtheory,whichisinvestigatedforabetterunderstandingofthemagneto-caloricbehaviorsoftheGd_(50)Co_(45)Al_5amorphousalloy.
简介:Inthiswork,amethodbasedonscanningKelvinprobemicroscopyisproposedtoseparatelyextractsource/drain(S/D)seriesresistanceinoperatingamorphousindium–gallium–zinc–oxide(a-IGZO)thin-filmtransistors.TheasymmetrybehaviorofS/Dcontactresistanceisdeducedandtheunderlyingphysicsisdiscussed.ThepresentresultssuggestthattheasymmetryofS/DcontactresistanceiscausedbythedifferenceinbiasconditionsoftheSchottky-likejunctionatthecontactinterfaceinducedbytheparasiticreactionbetweencontactmetalanda-IGZO.Theoverallcontactresistanceshouldbedeterminedbyboththebulkchannelresistanceofthecontactregionandtheinterfacepropertiesofthemetalsemiconductorjunction.
简介:Wedemonstratelow-losshydrogenatedamorphoussilicon(a-Si:H)waveguidesbyhot-wirechemicalvapordeposition(HWCVD).Theeffectofhydrogenationina-SiatdifferentdepositiontemperatureshasbeeninvestigatedandanalyzedbyRamanspectroscopy.Weobtainedanopticalqualitya-Si:Hwaveguidedepositedat230°CthathasastrongRamanpeakshiftat480cm-1,peakwidth(fullwidthathalf-maximum)of68.9cm-1,andbondangledeviationof8.98°.Opticaltransmissionmeasurementshowsalowpropagationlossof0.8dB/cmatthe1550nmwavelength,whichisthefirst,toourknowledge,reportforaHWCVDa-Si:Hwaveguide.
简介:Amorphouscarbonandgrapheneco-modifiedLiFePO4nanocompositehasbeensynthesizedviaafacilepolyolprocessinconnectionwithafollowingthermaltreatment.Variouscharacterizationtechniques,includingXRD.Mossbauerspectra,Ramanspectra,SEM,TEM,BET,O2-TPO,galvanocharge-discharge,CVandEISwereappliedtoinvestigatethephasecomposition,carboncontent,morphologicalstructureandelectrochemicalperformanceofthesynthesizedsamples.TheeffectofintroducingwayofcarbonsourcesonthepropertiesandperformanceofLiFePO4/C/graphenecompositewaspaidspecialattention.Underoptimizedsyntheticconditions,highlycrystalizedolivine-typeLiFePO4wassuccessfullyobtainedwithelectronconductiveFe2PandFePasthemainimpurityphases.SEMandTEManalysesdemonstratedthegraphenesheetswererandomlydistributedinsidethesampletocreateanopenstructuredLiFePO4withrespecttographene,whiletheglucosederivedcarbonmainlycoatedoverLiFeP04particleswhicheffectivelyconnectedthegraphenesheetsandLiFePO4particlestoresultinamoreefficientchargetransferprocess.Asaresult,favorableelectrochemicalperformancewasachieved.Theperformanceoftheamorphouscarbon-grapheneco-modifiedLiFePO4wasfurtherprogressivelyimproveduponcyclinginthefirst200cyclestoreachareversiblespecificcapacityashighas97mAh·g-1at10Crate.