简介:PositronannihilationbehaviorshavebeenstudiedinthesinglephaseNd2Fe14BmagnetandthenanocompositeNd2Fe14B/α-Femagnet,preparedbymeltspinning.Theresultsshowedthatthenumberofvacancy-clusteratgrainboundariesincreaseswithincreasingannealingtemperatureforthebothtypesofmagnets.Theincreaseofthiskindofdefectcanimprovethecoercivityof
简介:Ionbeamenhanceddeposition(IBED)wasemployedtoincreasethefrettingfatigueresistanceofTi6AI4V.CrNandTiNhardcoatingswereappliedonthebasematerialandshotpeeningwascombinedwiththehardcoatingstostudytheduplexeffectonfrettingfatigueresistance,TheIBEDcoatingsexhibitedagoodbondingstrength.Theydidnotspalloffevenaftershotpeening.However,anoptimumcompositionofCrNshowedbetterfrettingfatigueresistancethanthatofTiNwiththesameprocessingparameters.
简介:研究的目的是讨论采用非均相碱脱乙酰法制备壳聚糖时,反应时间及反应温度对壳聚糖脱乙酰度(DD)及分子质量(MW)的影响,并建立合适的反应条件,制备具有适当脱乙酰度及分子量的壳聚糖产品。甲壳素是从红虾的残渣中提取的。DD和MW分别由红外光谱及静态光散射仪测定。甲壳素的DD值及MW的测量结果分别为31.9%、5637kDa。实验结果表明壳聚糖的DD值随反应时间、反应温度的增加而增加。反应温度为140℃时制备的壳聚糖的DD值比反应温度为99℃时制备的壳聚糖DD值高。反应温度为99、140℃制备的壳聚糖的加最大值分别92.2%、95.1%。壳聚糖的DD值在反应初期增长较快,随着时间的延长,增长变慢。脱乙酰反应的反应速率及速率常数随反应物DD值的增加而减少。壳聚糖的分子量随脱乙酰反应时间的延长而减小。反应温度为140℃时制备的壳聚糖的分子量比反应温度为99℃时制备的壳聚糖的分子量小。反应初期壳聚糖的分解速率为43.6%/h,随着时间的延长其值减小到20%/h,在反应后期,分解反应速率常数增加。
简介:FenanowirearraywithstrongshapeanisotropywasemployedasthesoftphaseinNd-Fe-Bbasednanocomposites.TheeffectsoftheFenanowiredistributiononmagneticpropertiesofthenanocompositeswereinvestigatedbymicromagneticsimulation.TheresultsindicatethattheshapeanisotropyofFewiresaddedinthesamedirectionastheuniaxialmagnetocrystallineanisotropyofthehardphasecannotincreasethecoercivityofthenanocomposite.Whenthenanowiresaredistributedperpendiculartotheeasyaxisofthehardphase,theshapeanisotropyofsoftphasecanretardthemomentsfromrotatingtothefullreverseddirection,leadingtoenhancedcoercivity.Inaddition,withincreasingthenanowirediameter,thecoercivityofthenanocompositedecreases,butthedipolarinteractionshowsdifferentrolesinmagneticreversalofnanocompositefordifferentdistributionsofnanowires.ThecurrentresultssuggestthatthecoercivityoftheNd2Fe14B/α-Fenanocompositecanbeenhancedbyintroducingthesoftmagneticnanowirearraywiththediameterlessthantheexchangelengthandwiththelongaxisalongthedirectionotherthantheeasyaxisofhardphase.
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简介:Three-dimensional-printed(3D-P)titaniumimplantsdisplaymanyadvantages,suchasdesignflexibility,higherefficiency,thecapabilitytoeasilyconstructcomplexorcustomizedstructures,etc.,andisbelievedtopotentiallyreplacetraditionalimplants.However,thebiologicalperformanceofthe3D-Ptitaniumsurfacehasnotbeeninvestigatedsystematically.Herein,weanalyzedthesurfacecharacteristicsof3D-PTi6AI4Vimplantsandevaluatedthebiologicalresponsesofbonemarrowderivedmesenchymalstromalcells(BMSCs)tothe3D-Psurfaceinvitro.Moreover,afterimplantationintotheratfemoralcondylefor3and6weeks,theosseointegrationperformaneewasevaluated.Theresultsshowedthe3D-PTi6Al4Vimplantpresenteddistinctfluctuantmacroscaleroughsurfaceandrelativelybetterhydrophilicitywhichenhancedtheadhesion,proliferation,osteogenicdifferentiationandangiogeneticfactorexpressionofBMSCs.Moreover,theinvivoosseointegrationperformancewasalsobetterthanthatofthecontrolgroupattheearlystage.Thepresentstudysuggestedthe3D-Ptitaniumalloyisapromisingcandidatetobeusedasimplantmaterial.
简介:双相不锈钢1Cr18Ni11Si4AlTi由前苏联研制,目前在我国某些特殊行业中有重要的作用。根据我国现有标准GJB2294—95和GB/T1220—92组织生产,发现按标准中现行成分设计、热处理制度生产的产品与标准要求的力学性能(屈服强度σ0.2)需达到的规定值存在较大差异,很难达到所需要的屈服强度。通过完善相关成分和工艺参数,获得了满意的金相组织和优良的综合力学性能。通过试验探讨了生产实际与标准中的部分规定存在的差距。
简介:实现锡铁矿的资源化利用,采用高硫煤硫化磁化复合焙烧法对其进行处理。以最大限度脱除锡铁矿中锡为目标,对锡铁矿硫化磁化复合焙烧脱锡的热力学条件进行了系统研究。结果表明,SnS的挥发性能最好,且SnO的硫化趋势相对较大。同步实现锡的挥发脱除和铁的磁化富集,应控制焙烧条件为CO浓度介于0.014%~8.06%、焙烧温度高于793K。高硫煤中含硫物相硫铁矿硫、有机硫等的高温加氢裂解产物为S2、H2S、S02和FeS,其均可将SnO硫化成SnS实现锡的挥发脱除,且以硫铁矿硫分解产物S2的硫化作用居主要地位。该工艺为高硫煤的短流程清洁利用提供了一个新的方向。