简介:1.IntroductionLightrareearthadditioncanremarkablyenhancetheservicelifeofFe-Cr-Alalloyforelectricalheatingelement,butitscontentinthealloymustbecontrolledbelowthelevelof0.1wt-%.Whenthecontentexceedsthat,theperformance
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简介:WehavestudiedtheMossbauereffectofYBa2Cu2.88Fe0.12O7-xsuperconductiveoxidefrom78to273K.TwominimaofrecoillessfractionandDebyetemperaturewerefoundnear110Kand220K.Itmeansthatlatticesofteninghappenednearthesetwotemperatures.Wealsoobservedminimaofisomershiftnear110Kandquadrupolesplittingincreasewhentemperatureislowerthan110K.Wesuggestthatlatticesofteningwouldleadtothedisplacementofoxygenatoms.Thismayberelativetosuperconductivetransition.
简介:TheRamanspectraof3%(molefraction)Y2O3-ZrO2(3Y)areobtainedatdifferenttemperaturefrom77Kto853K.Theresultsshowthat260cm-1Egand460cm-1Egmodesonthespectrashifttowardlowerwavenumberwiththeincreaseoftemperature;meanwhile,thecontinuityoftheHalfWidthatHalfMaximum(HWHM)andwavenumber(frequency)ofRamanbandsarebrokenandt-phaseonlypartiallytransformstom-phaseat523K.Basedontheexperimentalresults,thispaperdiscussesthet-phaselatticevibrationof3YandpresentstheimagesofvibrationdisplacementofsixRaman-activemodesfort-phaseofZrO2.TheanalysisindicatesthattherearediversitiesexistinginthedisplacementoftheatomicvibrationofRaman-activemodesbecauseoftheirdifferentsymmetriesatvarioustemperature,whichleadstothedifferentchangetendenciesofRamanbands.Furthermore,theabruptchangesofsomeRaman-activemodesindicatingtheatomicdisplacementareassumedtobethecondensationsofphononmodesinthet→mphasetransition.
简介:biomagnesium合金被认为由于它的好机械相容性,生物相容性,生物安全和可被细菌破坏的特征是最潜在的可被细菌破坏的金属材料之一。然而,在生理的环境和低机械性质的高降级率的二个主要问题阻止biomagnesium合金的发展。在现在的工作,Mg-Zn-Y-Nd合金的样品被周期的挤出压缩(CEC)和相等的隧道准备尖紧迫(ECAP)。微观结构,合金的机械性质和它在模仿的身体液体(SBF)的腐蚀行为被评估。结果表明那Mg-Zn-Y-Nd合金与测微计尺寸和缩放nano的秒阶段的同类的分发由equiaxial罚款谷物结构组成,它被动态再结晶在ECAP和CEC期间引起。合金的腐蚀抵抗被改进。张力并且腐蚀抵抗被改进,特别处理合金展览制服腐蚀表演和减少的腐蚀评价。这将作为脉管的stent申请为Mg-Zn-Y-Nd合金提供理论地面。
简介:Thisstudywasconductedtodiscusstheeffectofrollingstrainonmicrostructureandtensilepropertiesofdual-phaseMg-8Li-3Al-2Zn-0.5Y(wt%)alloy,whichwaspreparedbycasting,andthenhomogenizedandrolledat200℃.Therollingprocesswasconductedwith10%reductionperpassandfivedifferentaccumulatedstrains,varyingfrom10%to70%.Theresultsindicatethattheas-castandas-rolledMg-8Li-3Al-2Zn-0.5Yalloysarecomposedofα-Mg,β-Li,AlLiandAl2Yphases.Afterrollingprocess,anisotropicmicrostructurewasobserved.a-Mgphasegotelongatedinbothrollingdirectionandtransversedirectionwiththeadditionofrollingstrain.Consequently,thestrengthofthealloyinbothdirectionswasnotablyimprovedwhereastheelongationdeclined,mainlycausedbystrainhardeninganddispersionstrengthening.Thetensilepropertiesoftheas-rolledalloysintheRD,nomattertheYS,UTSortheelongation,arehigherthanthoseoftheTDduetotheirlargerdeformationstrainandsignificantanisotropyinthehcpα-Mgphase.Inaddition,thefractureandstrengtheningmechanismofthetestedalloyswerealsoinvestigatedsystematically.
简介:Withpositronannihilationradiationonedimensionangular-correlationdevice,itismeasuredthatpositronannihilationradiationonedimensionangular-correlationcurvesofpolycrystalsodiumionconductorNa5Y1-xCrxSi4O12(NYCS)system.Afterelectronmomentumdistributioncurvesarenormalized,linearparametersarecalculated.TheparametersH,WandSshowthechangeofNa+ionvacancyconcentrationinNYCSseriessamples.TheresultsshowthatparametersH,WandSofonedimensionangular-correlationcurvesofthosesamplesvarygreatlywithCr2O3contents.WithCr2O3contentincreasing,HandSparametersincrease,butWdecreases,andreachesextremesatx=0.05;thenwithCr203addingcontinually,parametersHandSdecreasegradually,parameterWincreasesgradually.Thisshowsthat,inaddtiontoCr2O3,theconductivityhascloserelation