简介：SiliconoxynitridewasaddedinshapedAl2O3-SiC-Crefractorymaterialtoimprovetheslagresistanceinthispaper.Optimumaddingquantityofsiliconoxynitridepowderwasalsostudied.TheresultsshowthattheslagresistanceofAl2O3-SiC-Cshapedrefractoryisimprovedwhen2%or3%Si2N2Oisadded.AreasonableamountofSi2N2OaddedintoAl2O3-SiC-Cshapedrefractorycanproducesiliconoxideintotheslag,whichcanimprovetheviscosityofslagandpreventtheslagerosionandpenetration.

简介：Siliconcarbide(SiC)-alumina(Al_2O_3)-mullite(Al_6Si_2O_(13))compositepowderwassuccessfullysynthesizedat1550℃for5hviacarbothermalreductionreaction,andtheeffectsofvariousmassratiosofactivecarbontoflyash(0.38,0.44and0.58)onthephasecompositionandmicrostructureofproductswereinvestigated,andtheformationprocessofthepowderwasalsoanalyzedindetail.Theproductsmainlyconsistofβ-SiC,α-Al_2O_3,Al_6Si_2O_(13)andFeSi.IncreasingcarboncontentfavorsthedecompositionofAl_6Si_2O_(13)andformationofSiC.Theaverageparticlesizeofβ-SiCandα-Al_2O_3isabout1μmandthatofAl_6Si_2O_(13)is5-10μm.TheformationprocessofSiC-Al_2O_3-Al_6Si_2O_(13)powderincludesthedecompositionofmulliteinflyashandformationofSiC.

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简介：AnO'-Sialon-Al2O3compositerefractorywaspreparedbyinsitureactionofSi3N4-ZrSiO4-Al2O3mixturewithfusedaluminaaggregates.Densification,insitureactionprocedureandmicrostructureofthematerialwereinvestigatedbymeansofX-raydiffraction,opticalandscanningelectronicmicroscopesandEDAX.

简介：Inthispaper,X-raydiffractogramanalysisandSEMobservationofAl4C3formedathightemperaturefromcarbon-containingrefractorieswithAlhavebeencarriedout.Aluminumaddedtocarbon-containingrefractoriesreactswithC(s)toformAl4C3(s)graduallyduringheatingfrom600℃to1200℃.ItisconsideredthattheinterlockedstructureofAl4C3platecrystalspromotestheoutstandingincreaseofhotmodulusofruptureofcarbon-containingrefractorieswithAl.TheHMORofcarbon-containingrefractoriesaddedwithAladditivefrom0to5wt％increasesby2.8timesbeingfrom6.5MPato18.2MPa.AfterathermochemicalcalculationforhydrationreactionprocessesofAl4C3andH2O(g),theequilibriumpartialpressurechartofH2O(g)inH2O-Al4C3-Al(OH)3systemvsvarioustemperatureshasbeenattained.TheH2O(g)partialpressureintheairneededfortheAl4C3hydrationreactionisnomorethan10～18atmatthetemperaturebelow120℃.Itisconsideredthattheburnedcarbon-containingrefractorieswithAlisextremelyeasytohydrateandthecrackingofburnedcarbon-containingrefractoriesisgeneratedbecausethatthehydrationexpansionis2.11timesduringtransformingfromAl4C3toAl(OH)3.ThefundamentalmeasureagainsthydrationoftherefractoriesistoinsulatetherefractoriesfromH2O(g)byvariousmeanssuchaspitchimpregnationorothersealingmaterials.

简介：Inthispaper,Yangquanbauxitebasedonmineralseperationareinvestigated.Itisfoundthattheglassphasewillbedecreasedandthehightemperaturemechanicalpropertiedswillbeimproved.

简介：ThemagnesiabasedcurablespecimenswithdifferentSi3N4contentswerecastedusingsinteredmagnesite(w(MgO)=95%)asstartingmaterial,SiO2micro-powderasbinder,0.3%,4%and5%β-Si3N4powderreplacingtheequaladditionofmagnesiapowderrespectively.Theslagresistancetestwascarriedoutat1550℃for3husingBaosteeltundishslagandstaticcruciblemethod.Theresultindicatesthat:introducingSi3N4couldobviouslyimprovetheslagresistanceofMgObasedcastable,whichincreasedwithincreasingSi3N4.DenseSiO2sinteredlayerformedonthesurfaceofmagnesiabasedcastablebecauseoftheoxidationofSi3N4addition,whichcanpreventthefurtherslagpenetration.Inthedeepinnerofcastable,thepartial-pressureofoxygenwasverylow,soSi3N4canexiststably.Meanwhileinreducingatmosphere,Si3N4washardtobesintered,whichresultedinthelooseinteriorstructureofMgObasedcastable.

简介：Si3N4powderandhot-pressedSi3N4ceramicsaddedwithAl2O3areusedforinvestigatetheiroxidationbehviorinairandnitrogenatmosphere(withoxygenpartialpressurePO2=1-10Pa),TheoxidationproductsofSi3N4areexaminedbychemicalanalysi,X-raydiffraction(XRD)andXPSmethod,Also,thermodynamiccalculationismadetoanalyzeoxidationbehaviorofSi3N4.TheresultsshowthatonlypassiveoxidationwilloccurwhenSi3N4isoxidizedinairathightemperature,whereasinN2athightemperature,theactiveoxidationisdominantinspiteoftheexistenceofalittlepassiveoxidation.

简介：ThemechanicalpropertiesofpressurelesssinteringFe-Si3N4bondedSiCandSi3N4bondedSiCwithsamemanufactureprocesshavebeencomparedinthispaper.TheoxidizingmechanismofFe-Si3N4bondedSiCceramicmatrixcompositehasbeeninvestigatedespeciallythroughTG-DSC(thermogravimetricanalysis-differentialscanningcalorimeter)experiment.DuringoxidationprocedurethemainreactionistheoxidationofSiCandSi3N4,SiO2whichformprotectingfilmtopreventfurtheroxidizing.AndresidualironinthesamplesbecomeFe2O3andFe3O4,theoxidationkineticsat1100～1300℃ofre-Si3N4bondedSiChasbeenstudiedespecially.Theweightgainperunitareaatinitialstagechangesaccordingtobeelinerule,inthemiddleaccordingtoconic,andinthelastoxidationperiodfollowsparabolarule.

简介：全球最大的橙油出口国——巴西，其橙油的海外销售开始逐渐复苏。2007年的前11个月里，巴西共出口橙油28611t，与2005年同期的28069t差不多持平，但其出口量远远超过2006年同期的24664t。就区域而言，出口美国的从上年同期的7963t提高到8932t；不过，荷兰却下跌6％，为5175t。剩余的六大市场分别为德国、英国、中国、日本、印度和新加坡，所有这些地区的购买量都比上年有所增长。

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简介：DenseSi3N4BNcompositeceramicswerefabricatedbysparkplasmasinteringat1500,1600and1650℃under50MPafor5minusingSi3N4andBNpowdersasstartingmaterialsand2mass%Al2O3and6mass%Y2O3assinteringadditives.ThevolumefractionofBNinSi3N4BNcompositepowderswaschosenas10%,20%,and30%,respectively.TheresultsofXRDandSEMshowthatα-Si3N4completelyturnsintoβ-Si3N4whenthecompositeceramicsaresinteredat1650℃;theadditionofBNhindersthegrowthofSi3N4grains,refiningthestructure;VickershardnessandfracturetoughnessofthecompositeceramicsdecreasewiththeincreaseofBNcontent.

简介：Inthispaper,theinflucnceofchiefprocessparametersontheontinuousproductionofSi3N4powderbyrenitridationhasbeenstudied,Thesutiableprocessparametershavebeenfound,andhighqualitySi3N4powderhasbeendeveloped.

简介：Themicrostructureandslagerosionfractaldimensionofreactioninterfaceofβ-Sialon-Al2O3brickusedin300MtironladleofBaosteelhavebeenstudiedbySEMandXRD.Theresultsindicatedthatβ-Sialon-Al2O3brickexhibitedexcellentslagresistance.Themainwearmechanismofβ-Sialon-Al2O3brickismainlyfromthespallingcausedbythermalmechanicalstressandattackedbyslagsecondly.

简介：Al2O3-MgOcastableshavebeenwidelyusedforworkingliningsofsteelladleduetotheirsuperiorhotstrengthandcorrosionresistance.Inthiswork,effectsofmicrosilica,ultrafinealuminaandMgOfinesadditionsontherheologicalbehaviorofthecastableswereinvestigatedbymeansofIBBrheometerV1.0tomeasuretorque(shearstress)undervaryingshearrates.Theresultsshowthatrheologicalpropertiesofcastablesatvaryingshearratesaresignificantlyimprovedwithincreaseofmicrosilicaadditions(from1mass%to5mass%)andcorrespondingdecreaseinwateraddition;thereisonlylittlechangeinrheologicalbehaviorwithvariationofultrafinealuminaandMgOfinesadditions.Optimumultrafinealuminaandmicrosilicaadditionsarerecommendedforcastableswithgoodrheologicalbehavior.

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简介：TheinfluencesoffourkindsofadditivesaddedintothematrixofMgO-Al2O3unbunedproductswereinvestigated,TheresultsshowthatsampleswithproperMgO/Al2O3rationandproperadditionofCr2O3(2%-4%)havegoodthermalshockresistanceandslagcorrosionresistanceaswell,XRDandSEMdeterminationresultsindicatethatakindofcompoundspinel(Mg,Al,Cr)O4wasformedandthemicrostuctureofthesamplesaredenser.

简介：TiN-Al2O3compositepowderswithdifferentTiNcontents(0,10vol%,20vol%,30vol%and40vol%)werepreparedwithmicrometerTiNandα-Al2O3powder(theirpuritieswere99%)asstartingmaterialsbywetballmillingfor5h.TiN-Al2O3compositewerethenpreparedbypressingtheabovecompositepowders,dryingat200℃for12handfiringat1800℃for3hinnitrogenatmosphereinhot-pressingfurnace.TheinfluencesofTiNcontentonmechanicalpropertiesandelectricalconductivityofTiN-Al2O3compositeswerestudied.TheresultsshowedthatthemechanicalpropertiesofthecompositeincreasedwithTiNcontentincreasing,whiletheresistivityofcompositesdecreased.Acompositewith40%TiNhad498MPabendingstrength,4.285MPa·m1/2fracturetoughness,1.34×10-3Ω·cmresistivity.TheSEManalysisshowedthatthefineTiNcrystalsdistributedamongthecrystalboundaryofAl2O3matrix.Theybondedtogetherforminganet-likestructurewhichplayedaroleofrestrainingAl2O3grainsfromgrowingup,tougheningandstrengthening,sothemechanicalpropertiesofTiN-Al2O3compositewereenhanced.