简介：Thesimplemodelfor4f-5dtransitionsoflanthanideionsincrystalswasextendedtodealwiththecaseoftheoctahedralcrystalfield,whereforthet2componentof5dorbitalsthespin-orbitinteractioncouldnotbeneglectedduetoincompletequenchingofthe5dorbitalangularmomentum.Theenergylevelsforthe4fN-15dconfigurationandtherelativelinestrengthsforthe4fN4fN-15dtransitionwerecalculatedindetail.Theresultwasappliedtotheinterpretationofthelow-temperature4f-5dexcitationspectrumofCs2NaYCl6∶Tb3+.

简介：ThesinglecrystalgrowthofstoichiometrichostluminescentcrystalNa5Eu（WO4）4hasbeeninvestigated.UsingNa2WO4asaflux,theoptimumconditionstogrowapuresinglecrystalbyflux-slow-coolingmethodhavebeendetermined.Ahighopticalqualitysinglecrystalofdimention4.5mmhasbeengrown,whichisthelargestoneasweknowsofar.Themicro-hardnessofNa5Eu（WO4）4singlecrystalis3.46×103MPa.Itsrefractiveindexis1.81inwhitelightwavelengthregionandthespecificgravityis5.65g/cm3.Thefluorescentandexcitationspectrahavebeendeterminedandthereasonofthefluorescentquenchof5D2and5D1to7FjofEu3+canbeexplainedasmulti-phononnon-radiationtransition.

简介：在达到一定勘查程度的金矿区,有条件的合理利用部分D级储量作为矿山建设依据,可以减少投资风险,保障黄金生产稳步发展。

简介：ＳｐｅｃｔｒａｌＰａｒａｍｅｔｅｒＳｔｕｄｙｏｎＴｍ３＋ｉｎＮａ５Ｔｍ（ＷＯ４）４ＣｒｙｓｔａｌＹａｏＬｉａｎｚｅｎｇ（姚连增）（ＤｅｐａｒｔｍｅｎｔｏｆＭａｔｅｒｉａｌｓＳｃｉｅｎｃｅａｎｄＥｎｇｉｎｅｒｉｎｇ，ＵｎｉｖｅｒｓｉｔｙｏｆＳｃｉｅｎｃ...

简介：以奥氏体再结晶型控制轧制和未再结晶型控制轧制相结合的轧制工艺生产的Q345D钢板,其组织均匀、晶粒细小、性能良好,特别是低温韧性较好,达到了控制轧制的目的。

简介：ThephotoluminescencepropertiesofBiTaO4∶Pr3+andBiTaO4atroomtemperaturewerestudied,andtheinfraredtransmissionanddiffusionreflectionspectraofBiTaO4weremeasured.ThephotoluminescencespectrumofBiTaO4peaksatabout420,440and465nm.Therehasanobviousexcitationbandfrom330to370nm.ThephotoluminescencespectrumofBiTaO4∶Pr3+consistsofthecharacteristicemissionofPr3+,anditsmainpeakisat606nmfrom3P0→3H6transitionofPr3+.Itsexcitationspectrumconsistsofthewidebandwithmaximumat325nm,thewidebandintherangeof375～430nm,andthecharacteristicexcitationofPr3+.Thebandsat325nmand375～430nmmaybefromtheabsorptionofthechargetransfertransitionofthetantalategroupanddefectenergylevelsinitsforbiddenband,respectively.ThereisenergytransferfromhosttoPr3+.BecauseboththehostdensityandphotoluminescencepeakintensityofBiTaO4∶Pr3+aresuperiortoPbWO4,BiTaO4∶Pr3+maybeapotentialheavyscintillator.

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简介：电炉炼钢厂应用"70tConsteel电炉+LF+CCM"三位一体短流程工艺,成功开发出电动玩具用硅钢片D2。此钢的试制成功,为电工硅钢在电炉上生产提供了实际经验,且进一步拓展了我厂电炉钢产品结构,为适应市场需要创造了有利条件。

简介：针对4#高炉炉缸堆积事故，分析产生的原因，确定处理方案，阐述处理过程。探讨处理方法和预防措施。

简介：4#高炉自2004年10月份开炉以来经过几个月的操作实践和摸索,在逐步调整的过程中,实现了高压操作技术,并确立了与之配套的各种工艺操作参数,在创造良好的技术经济指标的同时,成功地实现了高产低耗的目标。

简介：4#高炉2014年5月份以来不断尝试探索新的布料模式,并最终实现由中心加焦操作到＂平台＋漏斗＂模式的转变。分析对比炉内燃料消耗、顺行情况和中心加焦时期操作炉型的变化以及高炉抗干扰能力的改善。

简介：介绍炼铁厂4^#高炉达产前高炉状况：炉况不顺，冶强上不去。经过分析，进风面积偏小，气流偏行是制约因素。通过采取扩大风口面积，加强槽下筛分等一系列措施，确保顺利达产。

简介：本文介绍了4~#连铸机生产工艺优化的具体措施。采用新技术,实行工艺优化后,铸坯实物质量显著改善,为转炉品种研制和开发创造了条件。

简介：Ca8Mg(SiO4)4Cl2:Eu2+phosphordopedwithSr2+cationforCa2+partially,wassynthesizedbysolid-statereactionathightemperatureunderreducingatmosphere,anditsluminescentpropertieswereinvestigated.TheexperimentalresultsindicatethattheemissionintensityofthephosphorincreasesafterbeingdopedwithafewamountofSr2+ion.Theemissionpeakofthephosphorblueshifttoabout464nmwhenthephosphorisdopedwithlargequantityofSr2+ions.TheexcitationspectrumindicatesthatthephosphorcanbewellexcitedbyUVandbluelightfrom300to460nm,andthephosphorwasfittedwellfortheexcitationbyUVorblue-LED.

简介：Trivalentdysprosium(Dy3+)activatednanocrystallineyttriumvanadate（YVO4）phosphorwassynthesizedviaco-precipitationmethod.ThepreparedsampleswerecharacterizedbyX-raydiffraction（XRD）,Fouriertransforminfraredspectroscopy（FTIR）,scanningelectronmicroscopy（SEM）,opticalabsorptionandphotoluminescence（PL）techniques.TheXRDpatternsrevealthetetragonalcrystallinephase.SEMimagesrevealthatDydopedYVO4nanocrystalsareagglomerated.EDAXconfirmstheformationofYVO4:Dy.FTIRspectrumshowstwostrongabsorptionbandsat459and761cm-1.Opticalabsorptionspectrumshowedthesurfacedefectsintheas-preparedsamples.ThePLemissionspectrumshowstwocharacteristicemissionbandsat485and575nm.Thestrongyellowemissionpeakat575nmisassignedto4F9/2→6H13/2hypersensitivetransitionofDy3+ions,StudyofCIEchromaticitydiagramindicatesthesuitabilityofthephosphorforthedevelopmentofyellow-greenLEDs.

简介：对3~#、4~#高炉原喷煤系统存在的问题进行了分析,综述了喷煤系统经过技术改造后产生的效果。

简介：通过加入锰矿来处理炉缸堆积，清除炉墙粘结，达到高炉稳定、顺行的目的。

简介：南钢4号1800m~3高炉于2014年1月24日点火开炉,高炉投产后顺利达产达效,随着高炉冶炼强度的提高,2016年上半年,铁口区域冒煤气严重,铁口难以维护,同时大量的煤气外泄严重威胁炉前工的人身安全。2016年10月17日计划检修,采取铁口框架内整体浇注技术、铁口及风口区域压浆技术、加强炉外管理和炉内管理、提高炮泥质量等措施,治理效果显著,煤气火逐渐减小。

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简介：TheextractionofCe(Ⅳ)inH2SO4/H3PO4systemwasinvestigatedsystematicallyusingbifunctionalionicliquidextractants(Bif-ILES)[A336][P507],[A336][P204]and[A336][C272]inn-heptane.TheeffectsofH2SO4concentration,extractantconcentrationandsalting-outagentconcentrationwereobservedindetail.TheextractionmechanismofCe(Ⅳ)inH2SO4/H3PO4systemwasobtained.ThecomparisonwithotherextractantssuchasCyanex923,TBPwasalsostudied.Thermodynamicfunctionsoftheextractionreactionwerecalculated,showingthattheextractionwasanexothermicprocess.TheseparationofCe(Ⅳ)fromRE(Ⅲ)andTh(Ⅳ)wasalsoinvestigated.TheresultindicatedthatCe(Ⅳ)couldbeselectivelyextractedinthissystem.CePO4nanoparticleswereobtainedintheprocessofstrippingusingH2O2inH2SO4/H3PO4system.X-raydiffraction(XRD),scanningelectronmicroscopy(SEM)andspectroscopywereadoptedforthecharacterizationofthesample.