简介:ThechemicalstateofgrainboundarycosegregationofCeandPinFe-P-CealloysystemwasstudiedbymeansofAugerElectronSpectroscopy(AES).TheAugerpeaksofCesegregatedatgrainboundariesarefoundwithintherangeof60~180eV.BycomparingwiththeAugerspectraoftheFe-Ce-Pintermetalliccompound,itissupposedthatthereisatwo-dimensionalinterfacialphaseatgrainboundarieswithCeandPcosegregationwhichissimilartothestructureoftheFe-Ce-Pcompound.
简介:309Lisakindofausteniticstainlesssteel.Thispaperdiscusses309L,whichwassmeltedandrolledinalab.Itsmicrostructuralcharacteristicsinstatesofas-cast,hot-rolling,cold-rollingandsolidsolutionwereinvestigatedrespectivelybyopticalmicroscope(OM).Itisfoundthat309Liscomposedofausteniteandresidualδ-ferriteundertheseconditions,andtheδ-ferritecannotbeeliminatedeasilybyheat-treatment.Itshotplasticityanddeformationresistancewereinvestigatedinaseriesofheatsim...
简介:Twothermo-mechanicalcontrolledprocesses(TMCP)includingcontrolledrollingandacceleratedcoolingareproposedfortheproductionofheavygaugeSUS304Lausteniticstainlesssteelplateswithdifferentstrengthsandothercharacteristics.BasedontherecrystallizationmechanismandcarbideprecipitationbehaviorofSUS304Lausteniticstainlesssteel,TMCPprovidesapowerfulmeanstocontrolthemicrostructureandprecipitationofthehotrolledsteelplatebythecontrolledrollingandacceleratedcoolingprocess.Thedislocationdensityandgrainsizearethemainfactorsindeterminingthestrengthofthestainlesssteelplates.Therefore,itisnecessarytostrictlycontrolthehotrollingparameters,includingparameterssuchasthefinishhotrollingtemperatureintherecrystallizationtemperatureregionandthetotalreductioninthenon-recrystallizationregion.Furthermore,inordertoavoidcarbideprecipitationandguaranteetheintergranularcorrosionresistanceofTMCPSUS304Lausteniticstainlesssteel,acriticalcoolingrateafterrollingisdetermined.
简介:Cr2O3-formingferriticstainlesssteelshavebeenwidelyexploredasintermediatetemperaturesolidoxidefuelcells(SOFCs)interconnects.However,theevaporationofchromiascalemightmigratetoandpoisonthecathode,leadingtodegradationofthecellperformance.Inthisstudy,Ni-Co-Fe-Pcoatingsweredepositedontheferriticstainlesssteelbymeansofacost-effectivetechniqueofelectrolessmethod.Theyareexpectedtobeconvertedinto(Ni,Co,Fe)3O4spinelwithahighelectricalconductivityandCTEmatchwithstainlesssteel,whichcanblocktheevaporationofchromiaformedonsteelsubstrateexposedtothecathodeenvironmentoftheSOFC.TheeffectsofpH,massratioofFeSO4/(FeSO4+NiSO4+CoSO4)andtemperatureofsolutiononthedepositionrate,compositions,surfacemorphologiesandstructuresoftheNi-Co-Fe-Pcoatingswereinvestigated.TheresultsindicatedthatthedepositionrateincreasedwithincreasingpHwhenpHwaslowerthan9andthenreducedwhenpHwashigherthan9.Thedepositionrateincreasedwithincreasingtemperaturewhentemperaturewaslowerthan80℃andthendecreasedwhentemperaturewashigherthan80℃.ThedepositionratedecreasedwiththeincreaseinmassratioofFeSO4/(NiSO4+CoSO4+FeSO4).ThecoatingsconsistedofNi,Co,FeandP.Thephasestructureofthecoatingwasamorphous.
简介:FSWandTIGwereconductedon316Lstainlesssteel.Variationduringmicrostructureandpropertiesinjointsobtainedbydifferentweldingmethodswasstudied.TheresultsshowthattheeffectofseveremechanicalstirringandintenseplasticdeformationcreatafinerecrystallizedgrainintheweldingjointduringFSW.AsforTIG,thetemperatureofweldingjointexceedsthemeltingpointofweldedmaterialitself.Theentireweldingprocessbelongstothesolidificationofasmallmoltenpool;andthemicrostructureofthejointtakesonatypicalcastingstructure.Whentheweldingparameterswereselectedappropriately,theaverageultimatetensilestrengthofFSWjointscanreach493MPa,whichis83.6%ofbasemetal;theaverageelongationis52.1%ofbasemetal.TheaverageultimatetensilestrengthofTIGjointsis475MPa,whichis80.5%ofbasemetal;theaverageelongationis40.8%ofbasemetal.ThetensiletestofFSWjointsissuperiortotheTIGjoints.ThemicrohardnessofFSWjointcomparedtobasemetalandTIGjointhavingasignificantimprovement,whicharel95.5HV,159.7HVand160.7HV,respectively;grainrefinementstrengtheningplaysanimportantroleinenhancingthemicrohardness.TheelectrochemicalcorrosiontestsshowthatthejointofFSW316Lausteniticstainlesssteelhasagoodcorrosionresistance.
简介:TheFe-Ti-Nmateralloywaspreparedthroughthein-situreactionofnitrogengaswiththeFe-Timelt.ScanningelectronmicroscoperesultsshowthattheparticlesuniformlydistributedintheironmatrixwereTiN.ThedeliberatelypreparedFe-Ti-Nmasteralloywasemployedforthe409Lferriticstainlesssteelinanattempttorefinetheas-castsolidificationstructure.ItwasfoundthattheeffectivenessofFe-Ti-Nmasteralloyonrefiningoftheas-cast409Lferriticstainlesssteelwasaffectedbyadditionlevel,holdingtimeandmeltstemperature.Itwasfoundthattheaverageequiaxedgrainsizedecreasedfrom1503μmto303μm,theproportionofequiaxedgrainzoneincreasedfrom14%to100%withincreasingtheFe-Ti-Nmasteralloyadditionlevelto2.5%.Theproportionofequiaxedgraindecreasedfrom85%to4%asthesolidificationtemperatureincreasedfrom1803Kto1883K.Whentheholdingtimereachedto8min,thesolidificationstructuresof409Lferriticstainlesssteelshowextremepointsintheproportionofequiaxedgrain.Itisclearthatthegrainrefiningefficiencygraduallyfadeawaywiththeincreasingoftheholdingtimeattheverybeginning.However,whentheholdingtimecontinuestoincreaseandexceedstheextremepoint,thegrainrefiningefficiencyoftheFe-Ti-Nmasteralloyrecoveredtoacertaindegree.Theexperimentalresultsmentionedabovehavebeenanalyzedintermsofthermodynamics.Underappropriateconditions,theFe-Ti-Nmasteralloyusedforgrainrefinementofthesolidificationstructureof409Lferriticstainlesssteelmayhavegoodprospectsforindustrialapplications.
简介:在Ar,Ar+H2,N2,N2+H2和低真空5种气氛下对MIM316L不锈钢进行了烧结,讨论了烧结气氛对合金致密化和力学性能的影响;得出烧结气氛的露点显著影响合金的致密化和最终力学性能;烧结气氛中的H2可以脱去合金中的碳来影响致密化和力学性能;尺寸精度受注射、脱脂和烧结工序的影响;在采用溶剂脱脂时,3个工序对尺寸精度的影响由大至小依次为烧结、注射和脱脂.在不同气氛下,3个工序对尺寸精度的影响相对稳定.
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简介:LuminescencelifetimeofCe(Ⅲ)forCe0.9RE0.1P5O14,whereREdenotesrareearthionsotherthanCe(Ⅲ),wasmeasuredbymeansofthetime-correlatedsinglephotoncountingtechnique.Ithasbeenfoundthatthelifetimedataarecapableofelucidatingtheenhancementorquenchingofcerium(Ⅲ)luminescencebyalienREions(otherthanCe)indoublydopedceriumpentaphosphatecrystal.