简介:Cesiumcontentintheseawateris3.0910-4mg·L-1,andammonium-typemordenitewasusedtoexchangecesiumfromcesiumsource.K-typemordenitewasobtainedbyhydrothermalsynthesismethod.Afterammonium-modified,ionexchangepropertiessuchassaturatedionexchangecapacitiesandselectivitycoefficientsforalkalimetalionsweredetermined.Atthesametime,ionexchangeisothermalcurvesofammonium-typemordeniteforCs+andNH4+weredeterminedat25°C.Pitzerelectrolytesolutiontheorywasusedtoworkoutactivitycoefficientsofthesystem,andtheKiellanddiagramoftheionexchangesystemwasobtained.Thecalculatedequilibriumconstant(Ka)andionfreeenthalpy(DG0)ofmordeniteforCs+andNH4+are1.455and-930.3J·mol-1,respectively,indicatingthationexchangeprocessofammonium-typemordeniteforcesiumisaspontaneousprocess.