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简介：Inthispaper,westudytheperturbationofspectrafor2×2operatormatricessuchasMX=(AX0B)andMZ=(ACZB)ontheHilbertspaceH⊕Kandthesets∩X∈B(K,H)Pσ(MX),∩X∈B(K,H)Rσ(MX)and∩Z∈B(H,K)σ(MZ),∩Z∈B(H,K)Pσ(MZ),∩Z∈B(H,K)Rσ(MZ),∩Z∈B(H,K)Cσ(MZ),whereR(C)isaclosedsubspace,arecharacterized

简介：Twooxo-vanadium(IV)complexes,[VO(C2O4)(2,2′-bipy)(H2O)]·C2H5OH(1)andVO(C2O4)(phen)(H2O)(2),where2,2′-bipy=2,2′-bipyridyl,phen=1,10-phenanthroline,weresynthesizedaspotentialfunctionalmodelsofvanadiumhaloperoxidases(VHPOs)inmixedsolventofethanolandwateratroomtemperature.Thecomplexeswerecharacterizedbyelementalanalysis,infrared(IR),UV-VisandX-raycrystallography.Structuralanalysesshowedthatvanadiumatomwascoordinatedbyaterminaloxygen,oneoxygenatomfromcoordinatedwater,twooxygenatomsfromthecarboxylategroupofoxalicacid,andtwonitrogenatoms(N1andN2)from2,2′-bipy/phen.Centralvanadiumatomsincomplexes1and2werebothinadistorted-octahedralenvironment,andsomeintermolecularhydrogenbondinglinkageswerealsoobservedineachcomplex.BrominationreactionactivityofthetwocomplexeswasevaluatedwithphenolredasorganicsubstrateinthepresenceofH2O2,Br-andphosphatebuffer,indicatingthattheycanbeconsideredasapotentialfunctionalmodelofVHPO.Inaddition,thermalanalysiswasalsoperformedanddiscussedindetail.

简介：应用量子化学从头计算和密度泛函理论（DFT）对HO2＋C2H2反应体系的反应机理进行了研究.在B3LYP/6-311G＊＊和CCSD（T）/6-311G＊＊水平上计算了HO2＋C2H2反应的二重态反应势能面.计算结果表明,主要反应方式为自由基HO2的H原子和C2H2分子中的C原子结合,经过一系列异构化,最后分解得到主要产物P1（CH2O＋HCO）.此反应是放热反应,化学反应热为-321.99kJ.mol-1.次要产物为P2（CO2＋CH3）,也是放热反应.

简介：Three-dimensional(3D)flowerlikehierarchicalZn2GeO4andMn2+-dopedZn2GeO4microstructureshavebeenpreparedbyafacilehydrothermalapproach.X-Raydiffraction(XRD),fieldemissionscanningelectronmicro-scopy(FESEM),transmissionelectronmicroscopy(TEM)andphotoluminescence(PL)spectrometrywereemployedtocharacterizethesamples.SuchflowerlikehierarchicalZn2GeO4microstructureswithanaveragediameterof3―4μmwerefoundtobeconstructedbyabundantsinglecrystallinenanorodsofabout90nmindiameter.TheluminescentpropertiesofZn2GeO4:xMnphosphorswithdifferentcontentsofMn2+asanactivatorwereinvestigated.TheMn2+-dopedsamplesshowedgreenluminescencecorrespondingtothed-dtransitionofMn2+undertheirradiationofUVlight.Theredshift(from531nmto538nm)inλemwithincreasingMn2+contentwasobservedintheluminescentspectra,whichshouldbeattributedtoaweakcrystalfieldbecauseofthesubstitutionofZn2+byMn2+atadistortedtetrahedrallatticesite.

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简介：LetAbead×drealexpansivematrix.AnA-dilationParsevalframewaveletisafunctionψ∈L2(Rd),suchthattheset{|detA|n/2ψ(Ant-l):n∈Z,l∈Zd}formsaParsevalframeforL2(R~d).AmeasurablefunctionfiscalledanA-dilationParsevalframewaveletmultiplieriftheinverseFouriertransformoff■isanA-dilationParsevalframewaveletwheneverψisanA-dilationParsevalframewavelet,where■denotestheFouriertransformofψ.Inthispaper,theauthorscompletelycharacterizeallA-dilationParsevalframewaveletmultipliersforanyintegralexpansivematrixAwith|det(A)|=2.Asanapplication,thepath-connectivityofthesetofallA-dilationParsevalframewaveletswithaframeMRAinL2(Rd)isdiscussed.

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简介：作者在H2(Bn)上给一个作文操作符的必要标准的上面的界限，它在S.S定义的更高维的值分发理论包含数的函数。Chern。一个标准也被给保证H2(Bn)上的作文操作员被围住或压缩。

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