简介：合成了一种未见报道的标题化合物（（C5N2H6）3（C5N2H7）3[（PO4）Mo12O36]·2H2O,Mr=2403.00）并得到单晶,晶体衍射实验发现其属于单斜晶系,P2（1）/n空间群,晶体学参数：a=13.316（3）,b=22.414（5）,c=20.063（4）,α=90.00（4）°,β=100.743（3）°,γ=90.00°,V=5883（2）3,Z=4,Dc=2.713Mg/m3,μ（MoKα）=2.608mm-1,F000=4604,最终R=0.0596,wR=0.1345,GoF=1.042.配体由由簇阴离子[（PO4）Mo12O36]3-之间通过端基氧与2-氨基吡啶形成氢键而相互连接,中间填充了一些水分子及2-氨基吡啶.
简介：本文报道了Ｃ６Ｈ１２Ｏ６（ＮＨ４）２ＳＯ４Ｃ２Ｈ５ＯＨＨ２Ｏ（Ｃ２Ｈ５ＯＨ／Ｈ２Ｏ＝０．９０）体系在３５℃时体系溶解度和饱和溶液的折光指数，并绘出了体系相应的溶度图和饱和溶液的折光指数曲线图。结果表明：所研究的体系为四元体系Ｃ６Ｈ１２Ｏ６（ＮＨ４）２ＳＯ４Ｃ２Ｈ５ＯＨＨ２Ｏ中的一部分。当溶液中肌醇饱和时，溶度曲线落在约５０％的等醇水比面上。当（ＮＨ４）２ＳＯ４在溶液中达到饱和时，出现共饱点。其组成为（ＮＨ４）２ＳＯ４：２１０％，Ｃ６Ｈ１２Ｏ６：２．０８％，Ｃ２Ｈ５ＯＨ：４４７５％。同时出现分层，在富醇相随着乙醇浓度的增加，出现肌醇与硫酸铵共饱线。在富水相硫酸铵饱和溶度曲线落在约５％乙醇的等醇水比面上，折光指数曲线由三支组成，其中两条分别与Ｃ６Ｈ１２Ｏ６·Ｈ２Ｏ和（ＮＨ４）２ＳＯ４相对应，另外一条线与（ＮＨ４）２ＳＯ４和Ｃ６Ｈ１２Ｏ６·Ｈ２Ｏ的共饱线相对应
简介：含有ONO给体原子的N-邻甲氧基苯甲酰基水杨酰肼配体与[VO(acac)2]在乙醇中反应得到钒(V)酰配合物VO[(C15H12N2O4)(OC2H5)].标题化合物晶体属三斜晶系,空间群Pī,晶胞参数:a＝0.89411(5)nm,b＝1.0063(2)nm,c＝1.0392(2)nm,α＝110.171(7)°,β＝95.219(3)°,γ＝93.822(2)°;V＝0.8692(2)nm3,Z＝2,R1＝0.0513,wR＝0.1532.研究结果表明:钒原子具有扭曲的四方锥配位构型,钒酰氧原子处在锥顶位置,配体的3个给体原子与溶剂分子形成锥底平面.
简介：本文就n-C4H9-Br制备实验的反应过程以及分别用KBr和NaBr制备n-C4H9-Br时出现的不同实验现象和结果进行了探讨。提出KBr的溶解速率比NaBr的溶解速率小是产生不同实验现象和结果的原因，并通过用块状NaBr进行对比实验得到验证。用块状的NaBr有利于提高n-C4H9-Br的产率。
简介：Twooxo-vanadium(IV)complexes,[VO(C2O4)(2,2′-bipy)(H2O)]·C2H5OH(1)andVO(C2O4)(phen)(H2O)(2),where2,2′-bipy=2,2′-bipyridyl,phen=1,10-phenanthroline,weresynthesizedaspotentialfunctionalmodelsofvanadiumhaloperoxidases(VHPOs)inmixedsolventofethanolandwateratroomtemperature.Thecomplexeswerecharacterizedbyelementalanalysis,infrared(IR),UV-VisandX-raycrystallography.Structuralanalysesshowedthatvanadiumatomwascoordinatedbyaterminaloxygen,oneoxygenatomfromcoordinatedwater,twooxygenatomsfromthecarboxylategroupofoxalicacid,andtwonitrogenatoms(N1andN2)from2,2′-bipy/phen.Centralvanadiumatomsincomplexes1and2werebothinadistorted-octahedralenvironment,andsomeintermolecularhydrogenbondinglinkageswerealsoobservedineachcomplex.BrominationreactionactivityofthetwocomplexeswasevaluatedwithphenolredasorganicsubstrateinthepresenceofH2O2,Br-andphosphatebuffer,indicatingthattheycanbeconsideredasapotentialfunctionalmodelofVHPO.Inaddition,thermalanalysiswasalsoperformedanddiscussedindetail.
简介：合成了一个新的配合物,经元素分析及X-射线衍射对其结构进行了表征.化合物晶体属单斜晶系,P2（1）/c空间群,晶胞参数：a=6.4824（13）,b=6.1325（12）,c=19.980（4）,α=90°,β=91.925（2）°,γ=90°,V=793.8（3）A3,M=245.05,Z=4,Dc=2.050Mg.m-3,F（000）=492,吸收系数μ=1.671mm-1,最终偏离因子R1=0.0263,wR2=0.0692.化合物的分子结构存在一维链状的结构,由于复杂氢键的存在,它的堆积结构呈二维网状排列,而且在[010]方向看到了纳米空洞.
简介：Tetrabutylammoniumorpotassiumsaltsoforganometalllicderivativesoflacunarypolyanion(RM)3P2W15O59^n-(RM=CpTi,CpZr,C4H7O2SnorC5H9O2Sn)havebeenpreparedandstructurallycharacterizedbyelementalanalysis,IR,UV-Vis,^1HNMRand^183WNMRspectroscopies.Thetitlecomplexesexhibitantitumoractivityinvitro.
简介：The2-Dheteronuclearcoordinationpolymer{[Ag4Fe2(SCN)12(H2O)2][(inaH)2(H2O)2]}n(1)(inaHistheabbreviationofprotonatedisonicotinicacid)withchemicalformulaC24H20Ag4Fe2N14O8S12hasbeensynthesizedandcharacterizedbysinglecrystalX-raydiffraction,elementalanalysisandIRspectroscopy.TheAgES2ringsconnecttwokindsofoctahedralgeometriesofFe(Ⅲ)ions,[Fe(NCS)6]^3-and[Fe(H2O)E(NCS)4]^-unitswithbridgingthiocyanateionsleadingto2-D[Ag4Fe2(SCN)12(H2O)2]^2-anionframework.Fourkindsofringsincludingtheunprecedentedthirty-twomemberedAg4Fe4(SCN)8ringssharecomersoredgesinthe2-Danionlayerstructure.AllthiocyanatescoordinatetothemetalionsaccordingtotheHSABprinciplewithNatomsbindingtotheFe(Ⅲ)ionsandwithSatomsbindingtoAg(I)ions.Pronoatedinacationsstabilizethelayerstructureascounterionsandhydrogenbondswereformedwithinthepronoatedinacationsdimerandbetweenthedimersandthelatticewaters.Crystaldata:Mr=1560.44,triclinic,P-↑1,a=0.76082(1)nm,b=0.9234nm,c=1.85611(4)nm,α=103.0170(10)°,β=93.7780(10)°,γ=97.4080(10)°,V=1.25385(3)nm^3,Z=1,μ(MoKα)=2.650mm^-1,Dc=2.067g·cm^-3,F(000)=758,R1=0.0412,wR2=0.1003.
简介：对化合物[Na_2（H_2O）_（10）][Cu_4（H_2O）_（12）（H_2W_（12）O_（42））]·15H_2O（简称Na_2Cu_4W_（12））进行了体外抗肿瘤活性研究.应用四甲基偶氮唑盐（3-[4,5-dimethylthiazo-2-y]-2,5-diphenyltetrazoliumbromide,MTT）比色法分析Na_2Cu_4W_（12）对人肝癌细胞（HepG2）、人神经母细胞瘤细胞（SHY5Y）增殖抑制活性.采用光学显微镜观察肿瘤细胞的凋亡形态变化,用流式细胞术分析细胞周期和细胞凋亡,计算各期细胞比例及细胞凋亡率.结果表明,Na_2Cu_4W_（12）对HepG2和SHY5Y2种肿瘤细胞增殖半数抑制浓度IC_（50）值分别为5.3和10.2μmol·L~（-1）,且呈剂量依赖性.光学显微镜下处理组细胞出现皱缩、变圆、缩小等形态变化,不同浓度Na_2Cu_4W_（12）处理12h早期凋亡细胞所占的百分比显著增加且呈剂量依赖性.综上所述,Na_2Cu_4W_（12）能够抑制胞瘤细胞增殖,诱导细胞凋亡.
简介：Ionothermalsynthesiswasusedtoprepareanovelaminoacidcontaininghybridzincophosphatemonomer,[Zn(HPO4)(H2PO4)][C6H10N3O2](denotedasZnPO-CJ58).Theinorganicframeworkof[Zn(HPO4)(H2PO4)]·[C6H10N3O2]consistsof4-memberedringsformedbyZnO3OHisandPO2(OH)2tetrahedra.TheHPO4andaminoacidmoietieshangontheZncenter.Suchaframeworkisstabilizedbyextensivemultipointhydrogenbondsinvolvingthephosphateunitsandhistidinemoleculestoformapseudo-3Dsupramolecularstructure.ItisnoteworthythatZnPO-CJ58isthefirstzincphosphateclusterwithaminoacidactingastheligand.Itexhibitsphotoluminescenceexcitedatawavelengthof220nm.Interestingly,ZnPO-CJ58cantransformintoalayeredstructure(C6H10N3O2)Zn2·(HPO4)(PO4)·H2O(ZnPO-CJ36)throughfurtherreactingwithwaterorzincacetatedihydrateinwaterat85℃for1h.Thisworkwillbehelpfulforthesynthesisofcrystallineinorganic-organichybridmaterialswithbiofunctionalmolecules.
简介：ThehydrolysisofcephanoneinTritonX-100micelleandTritonX-100/n-C5H11OH/H2O(O/W)microemulsionwerestudiedbymeansofUV-Visabsorptionspectroscopy.Theresultsshowthatcomparedwithwater,TritonX-100micelleandTritonX-100/n-C5H11OH/H2O(O/W)microemulsioncaninhibitthehydrolysisofcephanone.TheinhibitioneffectsofTritonX-100micelleandTritonX-100/n-C5H11OH/H2O(O/W)microemulsiononthehydrolysisofcephanonearerelatedtothelocationofcephanoneintheinterphasesofTritonX-100micellesandTritonX-100/n-C5H11OH/H2O(O/W)microemulsiondroplets.
简介：Aneworganicsemiconductortartaricaciddopedsaltofemeraldinepolyaniline(PANI-C4H6O6)hasbeenobtainedbythemethodofoxidativepolymerizationofmonomericanilinewithammoniumpersulfateinacidicsolution.ThestructurewascharacterizedbyFourierTransformInfraredtechnique(FTIR)andX-raydiffraction(XRD).Thetemperaturedependencedcconductivityδdc(T)showsasemiconductorbehaviorandfollowsthequasionedimensionalvariablerangehopping(Q1D-VRH)model.Dataonδdc(T)arealsodiscussed.
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![Crystal Structure and Bioactivity of Complex [Gd（<b style='color:red'>C</b>10<b style='color:red'>H</b>9<b style='color:red'>N</b>2<b style='color:red'>O</b><b style='color:red'>4</b>）（<b style='color:red'>C</b>10<b style='color:red'>H</b>8<b style='color:red'>N</b>2<b style='color:red'>O</b><b style='color:red'>4</b>）（<b style='color:red'>H</b>2<b style='color:red'>O</b>）3]2·phen·<b style='color:red'>4</b><b style='color:red'>H</b>2<b style='color:red'>O</b>](/image/thesis0 "Crystal Structure and Bioactivity of Complex [Gd（<b style='color:red'>C</b>10<b style='color:red'>H</b>9<b style='color:red'>N</b>2<b style='color:red'>O</b><b style='color:red'>4</b>）（<b style='color:red'>C</b>10<b style='color:red'>H</b>8<b style='color:red'>N</b>2<b style='color:red'>O</b><b style='color:red'>4</b>）（<b style='color:red'>H</b>2<b style='color:red'>O</b>）3]2·phen·<b style='color:red'>4</b><b style='color:red'>H</b>2<b style='color:red'>O</b>")
![新型杂多酸（<b style='color:red'>C</b>5<b style='color:red'>N</b>2<b style='color:red'>H</b>6）3（<b style='color:red'>C</b>5<b style='color:red'>N</b>2<b style='color:red'>H</b>7）3[（PO<b style='color:red'>4</b>）Mo<b style='color:red'>12</b><b style='color:red'>O</b><b style='color:red'>36</b>]·2<b style='color:red'>H</b>2<b style='color:red'>O</b>的水热合成与晶体结构](/image/thesis1 "新型杂多酸（<b style='color:red'>C</b>5<b style='color:red'>N</b>2<b style='color:red'>H</b>6）3（<b style='color:red'>C</b>5<b style='color:red'>N</b>2<b style='color:red'>H</b>7）3[（PO<b style='color:red'>4</b>）Mo<b style='color:red'>12</b><b style='color:red'>O</b><b style='color:red'>36</b>]·2<b style='color:red'>H</b>2<b style='color:red'>O</b>的水热合成与晶体结构")
![Synthesis and Characterization of Surfactant-encapsulated Polyoxoanions: [(CnH2<b style='color:red'>n</b>+1)2<b style='color:red'>N</b>（CH3）2]<b style='color:red'>12</b>[Mo<b style='color:red'>36</b>（NO）<b style='color:red'>4</b><b style='color:red'>O</b>108（<b style='color:red'>H</b>）2<b style='color:red'>O</b>)16] （<b style='color:red'>n</b>=<b style='color:red'>12</b>, 18）](/image/thesis3 "Synthesis and Characterization of Surfactant-encapsulated Polyoxoanions: [(CnH2<b style='color:red'>n</b>+1)2<b style='color:red'>N</b>（CH3）2]<b style='color:red'>12</b>[Mo<b style='color:red'>36</b>（NO）<b style='color:red'>4</b><b style='color:red'>O</b>108（<b style='color:red'>H</b>）2<b style='color:red'>O</b>)16] （<b style='color:red'>n</b>=<b style='color:red'>12</b>, 18）")
![Imidazole Coordinated Sandwich-type Antimony Polyoxotungstates Na9[ {Na（<b style='color:red'>H</b>=<b style='color:red'>O</b>2}3{<b style='color:red'>M</b>（<b style='color:red'>C</b>3<b style='color:red'>H</b><b style='color:red'>4</b><b style='color:red'>N</b>2）}3（ Sb W9<b style='color:red'>O</b>33）2]·xH=<b style='color:red'>O</b>（<b style='color:red'>M</b>=Ni^Ⅱ, Co^Ⅱ, Zn^Ⅱ, Mn^Ⅱ）](/image/thesis5 "Imidazole Coordinated Sandwich-type Antimony Polyoxotungstates Na9[ {Na（<b style='color:red'>H</b>=<b style='color:red'>O</b>2}3{<b style='color:red'>M</b>（<b style='color:red'>C</b>3<b style='color:red'>H</b><b style='color:red'>4</b><b style='color:red'>N</b>2）}3（ Sb W9<b style='color:red'>O</b>33）2]·xH=<b style='color:red'>O</b>（<b style='color:red'>M</b>=Ni^Ⅱ, Co^Ⅱ, Zn^Ⅱ, Mn^Ⅱ）")
![配合物VO[（<b style='color:red'>C</b>15<b style='color:red'>H</b><b style='color:red'>12</b><b style='color:red'>N</b>2<b style='color:red'>O</b><b style='color:red'>4</b>）（OC2<b style='color:red'>H</b>5）]的合成晶体结构和氧化还原性质](/image/thesis6 "配合物VO[（<b style='color:red'>C</b>15<b style='color:red'>H</b><b style='color:red'>12</b><b style='color:red'>N</b>2<b style='color:red'>O</b><b style='color:red'>4</b>）（OC2<b style='color:red'>H</b>5）]的合成晶体结构和氧化还原性质")
![Vanadium Haloperoxidases Model Compounds： Synthesis, Structural Characterization and Mimic Catalytic Bromination Activity of [VO（<b style='color:red'>C</b>_2<b style='color:red'>O</b>_<b style='color:red'>4</b>）（2,2′-bipy）（<b style='color:red'>H</b>_2<b style='color:red'>O</b>）]·<b style='color:red'>C</b>_2<b style='color:red'>H</b>_5OH and VO（<b style='color:red'>C</b>_2<b style='color:red'>O</b>_<b style='color:red'>4</b>）（phen）（<b style='color:red'>H</b>_2<b style='color:red'>O</b>）](/image/thesis9 "Vanadium Haloperoxidases Model Compounds： Synthesis, Structural Characterization and Mimic Catalytic Bromination Activity of [VO（<b style='color:red'>C</b>_2<b style='color:red'>O</b>_<b style='color:red'>4</b>）（2,2′-bipy）（<b style='color:red'>H</b>_2<b style='color:red'>O</b>）]·<b style='color:red'>C</b>_2<b style='color:red'>H</b>_5OH and VO（<b style='color:red'>C</b>_2<b style='color:red'>O</b>_<b style='color:red'>4</b>）（phen）（<b style='color:red'>H</b>_2<b style='color:red'>O</b>）")
![配合物[Mn（<b style='color:red'>C</b>_5<b style='color:red'>H</b>_2<b style='color:red'>N</b>_2<b style='color:red'>O</b>_6）·2<b style='color:red'>H</b>_2<b style='color:red'>O</b>]_<b style='color:red'>n</b>的合成、晶体结构及光谱性质](/image/thesis11 "配合物[Mn（<b style='color:red'>C</b>_5<b style='color:red'>H</b>_2<b style='color:red'>N</b>_2<b style='color:red'>O</b>_6）·2<b style='color:red'>H</b>_2<b style='color:red'>O</b>]_<b style='color:red'>n</b>的合成、晶体结构及光谱性质")
![Synthesis and Crystal Structure of a Two-dimensional Silver（Ⅰ）-Iron（Ⅲ） Heteronuclear Coordination Polymer： {[Ag<b style='color:red'>4</b>Fe2（SCN）<b style='color:red'>12</b>（<b style='color:red'>H</b>2<b style='color:red'>O</b>）2] [（inaH）2（<b style='color:red'>H</b>2<b style='color:red'>O</b>）2]}<b style='color:red'>n</b>](/image/thesis15 "Synthesis and Crystal Structure of a Two-dimensional Silver（Ⅰ）-Iron（Ⅲ） Heteronuclear Coordination Polymer： {[Ag<b style='color:red'>4</b>Fe2（SCN）<b style='color:red'>12</b>（<b style='color:red'>H</b>2<b style='color:red'>O</b>）2] [（inaH）2（<b style='color:red'>H</b>2<b style='color:red'>O</b>）2]}<b style='color:red'>n</b>")
![新型仲钨酸盐-B化合物[Na_2（<b style='color:red'>H</b>_2<b style='color:red'>O</b>）_（10）][Cu_<b style='color:red'>4</b>（<b style='color:red'>H</b>_2<b style='color:red'>O</b>）_（<b style='color:red'>12</b>）（<b style='color:red'>H</b>_2W_（<b style='color:red'>12</b>）<b style='color:red'>O</b>_（42））]·15<b style='color:red'>H</b>_2<b style='color:red'>O</b>体外抗肿瘤活性研究](/image/thesis16 "新型仲钨酸盐-B化合物[Na_2（<b style='color:red'>H</b>_2<b style='color:red'>O</b>）_（10）][Cu_<b style='color:red'>4</b>（<b style='color:red'>H</b>_2<b style='color:red'>O</b>）_（<b style='color:red'>12</b>）（<b style='color:red'>H</b>_2W_（<b style='color:red'>12</b>）<b style='color:red'>O</b>_（42））]·15<b style='color:red'>H</b>_2<b style='color:red'>O</b>体外抗肿瘤活性研究")
![Ionothermal Synthesis and Phase Transformation of Organic-inorganic Hybrid Neutral Zincophosphate Cluster [Zn（HPO<b style='color:red'>4</b>）（<b style='color:red'>H</b>2PO<b style='color:red'>4</b>）][<b style='color:red'>C</b>6<b style='color:red'>H</b>（10）<b style='color:red'>N</b>3<b style='color:red'>O</b>2]](/image/thesis17 "Ionothermal Synthesis and Phase Transformation of Organic-inorganic Hybrid Neutral Zincophosphate Cluster [Zn（HPO<b style='color:red'>4</b>）（<b style='color:red'>H</b>2PO<b style='color:red'>4</b>）][<b style='color:red'>C</b>6<b style='color:red'>H</b>（10）<b style='color:red'>N</b>3<b style='color:red'>O</b>2]")
