简介:LuminescencelifetimeofCe(Ⅲ)forCe0.9RE0.1P5O14,whereREdenotesrareearthionsotherthanCe(Ⅲ),wasmeasuredbymeansofthetime-correlatedsinglephotoncountingtechnique.Ithasbeenfoundthatthelifetimedataarecapableofelucidatingtheenhancementorquenchingofcerium(Ⅲ)luminescencebyalienREions(otherthanCe)indoublydopedceriumpentaphosphatecrystal.
简介:Baiyuneboite-(Ce)isanewfluor-carbonatemineral.Basedonthefinedataonthestructureofthemineral,thefactorgroupandnormalcoordinateanalysesforitsinfraredspectrumhavebeencarriedout.ThefactorgroupanalysesindicatethatthesitegroupandfactorgroupsplittingsoftheinternalvibrationbandsofCO3^2-ionsdonotoccurandthatthedoublebandsofnormalmodesresultfromtwonon-equalsetsofCO3^2-ionsinthecrystalstructure,Thenormalcoordinateanalysesgivethestretchingforceconstants.bendforceconstantsandcalculatedfrequenciesofCO3^2-ions.Thecalculationsofpotentialenergydistributionallowustoassignv3andv4tothestretchingvibrationandthebendvibrationofCO3^2-ions.respectively.
简介:Inthepasttenyearstheeomplementarytristimulusspeetrophotometryll],eTs,hasseenitsdiverseappli-eations{2一61thoughmostresearehesremaininrelativelysimpesystems,andlessworkhasbeeninvolvinkinetiereaetions.AnattemPthasbeenmadeontheinvestigationofsomecomPlieatedsystemseontainingrareearthsandmeta一acetylchloroPhosPhonaz