简介:Theaveragebondenergymethodispopularizedandappliedtostudybandoffsetsatstrainedlayerheterojunctions.BycarefulexaminationofhydrostaticanduniaxialstrainactionsonthebandoffsetparameterEmv,itisfoundthattheaveragebandoffsetparameterEmv,av=Em-Ev,avremainsbasicallyunchangedunderdifferentstrainconditions.Therefore,providedthebandoffsetparameterbeforestrainEmv,0ofbulkmaterialiscalculated,andtheexperimentvaluesofdeformationpotentialbandspin-orbit(SO)splittingenergy△0arequoted,theEmvatstrainedlayercanbeobtainedbyasimpleandconvenientalgebraiccalculation.Thusthevalencebandoffset△Evatstrainedlayerheterojunctincanalsobepredictedconveniently.Thissimplifiedcalcultationmethodischaracterizedbydecreasedcalculationamountandincreasedconvictionduetouseasmanyaspossibletheexperimentvalues.
简介:小分子有铟听氧化物(ITO)的结构的器官的太阳能电池(振荡)/molybdenum三氧化物(MoO3)(5nm)/rubrene(nm)/fullerene(C70)(ynm)/2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline(BCP)(6nm)/aluminum(艾尔)(150nm)被制作。为设备的活跃的层的厚度在细节被调查。结果证明rubrene层和C70层的最佳厚度分别地是30nm和25nm。设备的降级也被调查。,结果显示开电路的电压(Voc)不变化电线走火电流密度(Jsc),用时间连续地填满因素(FF)和功率变换效率(PCE)减少。降级能在周围的扩散并且渗透到活跃材料并且在房间与C70反应被归因于氧,它能导致界面的系列电阻的增加。
简介:Ionimplantationmayfavorablymodifythepropertiesofpolyaniline/Siheterojunctionsolarcellsfabricatedbytheelectrochemicalmethod.Influencesoftheimplantationontheabsorptionspectrumandthethermalstabilitywerediscussedandoutputpropertiesweremeasured.Theresultsshowthattheabsorptionspectrumofthepolyanilinefilmsmodifiedbyionimplantationismuchwider;itspyrolytictemperatureincreasesby40℃,andthepolyaniline/Sicellefficiencyincreases18and3timesundertheilluminationof10.92and37.2W/m2,respectively.
简介:我们与经由化学方法获得的Agnanoparticles(AgNPs)报导提高电浆子的聚合物体积异质接面太阳能电池。这里,有不同粒子密度的AgNPs电影被介绍在之间poly(3,4乙烯dioxythiophene)poly(styrenesulfonate)(PEDOT:PSS)缓冲区层并且poly(3-hexythiophene):[6,6]-phenyl-C61奶油的酸甲基酉旨(P3HT:PCBM)层。由由于局部性的表面电浆子改进活跃的层的光吸收,太阳能电池的力量变换效率与控制设备相比被增加。设备的效率与AgNPs的密度增加,这被显示出。为采用更高的密度的设备,结果的力量变换效率被发现从2.89%~3.38%增加,在16.96%提高了。
简介:Owingtoitsthickness-modulateddirectenergybandgap,relativelystronglight–matterinteraction,anduniquenonlinearopticalresponseatalongwavelength,few-layerblackphosphorus,orphosphorene,becomesveryattractiveinultrafastphotonicsapplications.Herein,wesynthesizedagraphene/phosphorenenano-heterojunctionusingaliquidphase-strippingmethod.Tinylatticedistortionsingrapheneandphosphorenesuggesttheformationofanano-heterojunctionbetweengrapheneandphosphorenenanosheets.Inaddition,wesystematicallyinvestigatetheirnonlinearopticalresponsesatdifferentwavelengthregimes.Ourexperimentsindicatethatthecombinedadvantagesofultrafastrelaxation,broadbandresponseingraphene,andthestronglight–matterinteractioninphosphorenecanbecombinedtogetherbynano-heterojunction.Wehavefurtherfabricatedtwo-dimensional(2D)nano-heterojunctionbasedopticalsaturableabsorbersandintegratedthemintoanerbium-dopedfiberlasertodemonstratethegenerationofastableultrashortpulsedownto148fs.Ourresultsindicatethatagraphene/phosphorenenano-heterojunctioncanoperateasapromisingsaturableabsorberforultrafastlasersystemswithultrahighpulseenergyandultranarrowpulseduration.Webelievethisworkopensupanewapproachtodesigning2Dheterointerfacesforapplicationsinultrafastphotonicsandotherresearch.Thefabricationofa2Dnano-heterojunctionassembledfromstackingdifferent2Dmaterials,viathisfacileandscalablegrowthapproach,pavesthewayfortheformationandtuningofnew2Dmaterialswithdesirablephotonicpropertiesandapplications.
简介:Basedonsimpleanalyticalequations,shortcircuitcurrentdensity(JSC)oftheorganicbulkheterojunctionsolarcellshasbeencalculated.ItisfoundthattheopticalinterferenceeffectplaysaveryimportantroleinthedeterminationofJSC;andobviousoscillatorybehaviourofJSCwasobservedasafunctionofthickness.Atthesametime,theinfluenceofthecarrierlifetimeonJSCalsocannotbeneglected.Whenthecarrierlifetimeisrelativelyshort,JSConlyincreasesattheinitialstageandthendecreasesrapidlywiththeincreaseofactivelayerthickness.However,forarelativelylongcarrierlifetime,theexcitondissociationprobabilitymustbeconsidered,andJSCbehaveswave-likewiththeincreaseofactivelayerthickness.Thevalidityofthismodelisconfirmedbytheexperimentalresults.
简介:ZnOnanoconearrays(NCAs)decoratedwithblackTiO2nanoparticles(BTiO2NPs)wereuniformlyanchoredonthesurfaceofcarboncloth(CC)directlybyasimplyelectrochemicaldepositionmethod.ThusanovelB-TiO2NPs/ZnONCAs-CChierarchicalheterostructurewasformed.Itdisplayedsuperiorperformanceandachievedahigherphotocurrentover0.4mA·cm^-2beforetheonsetofthedarkcurrent,attributedtotheseparationofthephotogeneratedelectron-holepair.BasedontheB-TiO2NPs/ZnONCAs-CCheterostructure,thecatalystwasfabricatedforpromotingtheseparationofchargecarriers.Moreover,theintroductionofTi^3+andoxygenvacanciesonthesurfaceofTiO2NPsexpandedtheabsorptionbandedgeandenhancedtheelectricalconductivityaswellasthechargetransportationonthecatalyticsurface.ItindicatesthattheB-TiO2NPs/ZnONCAs-CCcompositeisbeneficialtotheimprovementofthephotoelectrochemical(PEC)activity.
简介:水晶的Au5Si2/Si异质接面nanowires(Au5Si2/SiNWs)被热蒸发的SiO粉末在一个低真空系统在厚黄金涂的硅底层上获得。生产Au5Si2/Si异质接面的结构分析被采用一台传播电子显微镜(TEM)和一个选择区域执行电的衍射计。化学作文被纳入TEM的一个精力散的X光分光镜学习。一个二拍子的圆舞生长模型被建议描述Au5Si2/SiNWs的形成。在第一步期间,水晶的SiNWs经由在相对高的温度把帮助氧化物的生长过程与vapour-liquid-solid模型相结合的生长机制被形成。在第二步,preformedSiNWs的温度减少和减少片断与残余Au反应由一个solid-liquid-solid过程形成单个水晶的Au5Si2nanowires。现在的工作应该基于nanowires为未来合成和高质量的金silicidenanowires和微电子设备的研究是有用的。
简介:Inthisstudy,weinvestigatetheinfluenceofdopingonthechargetransferanddevicecharacteristicsparametersinthebulkheterojunctionsolarcellsbasedonpoly(3-hexylthiophene)(P3HT)andamethanofuUerenederivative(PCBM).Organicsemiconductorsarealsoknowntobenotpureandtheyhavedefectsandimpurities,someofthemarebeingchargedandactasp-typeorn-typedopants.Calculationsofthesolarcellcharacteristicsparametersversusthep-dopinglevelhavebeendoneatthreedifferentn-dopings(N_d)thatconsistof5×10~(17)cm~(-3),10~(18)cm~(-3),and5×10~(18)cm~(-3).Weperformtheanalysisofthedopingconcentrationthroughthedrift-diffusionmodel,andcalculatethecurrentandvoltagedopingdependency.Wefindthatatthreedifferentn-dopantlevels,optimump-typedopingisaboutN_p=6×10~(18)cm~(-3).Simulationresultshaveshownthatbyincreasingdopinglevel,V_(oc)monotonicallyincreasesbydoping.CellefficiencyreachesitsmaximumatsomewhathigherdopingasFFhasitspeakatN_p=3×10~(18)cm~(-3).Moreover,thispaperdemonstratesthattheoptimumvalueforthep-dopingisaboutN_p=6×10~(18)cm~(-3)andoptimumvalueforn-dopantisN_d=10~(18)cm~(-3),respectively.Thesimulatedresultsconfirmthatdopingconsiderablyaffectstheperformanceoforganicsolarcells.
简介:Theelectrontransportlayer(ETL)playsanimportantroleinplanarheterojunctionperovskitesolarcell(PSCs),byaffectingthelight-harvesting,electroninjectionandtransportationprocesses,andespeciallythecrystallizationofperovskiteabsorber.Inthiswork,weutilizedacommercialTKD-TiO_2nanoparticlewithasmalldiameterof6nmforthefirsttimetoprepareacompactETLbyspincoating.Thepackingofsmall-sizeparticlesendowedTKD-TiO_2ETLanappropriatesurface-wettability,whichisbeneficialtothecrystallizationofperovskitedepositedviasolution-processedmethod.Theuniformandhigh-transmittanceTKD-TiO_2filmsweresuccessfullyincorporatedintoPSCsasETLs.FurthercarefuloptimizationofETLthicknessgavebirthtoahighestpowerconversionefficiencyof11.0%,whichwasmuchhigherthanthatofPSCusinganETLwiththesamethicknessmadebyspraypyrolysis.ThisTKD-TiO_2providedauniversalsolarmaterialsuitableforthefurtherlarge-scaleproductionofPSCs.TheexcellentmorphologyandtheconvenientpreparationmethodofTKD-TiO_2filmgaveitanextensiveapplicationinphotovoltaicdevices.