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简介：ＥｌｅｃｔｒｏｎＭｏｂｉｌｉｔｙｉｎＴｒｉｓ（８－Ｈｙｄｒｏｘｙｑｕｉｎｏｌｉｎｏｌａｔｏ）ＡｌｕｍｉｎｕｍＴｈｉｎＦｉｌｍＢａｓｅｄｏｎＳｉｌｉｃｉｕｍ①②ＣＨＥＮＢａｉｊｕｎ，ＬＩＵＳｈｉｙｏｎｇ（ＳｔａｔｅＫｅｙＬａｂ．ｏｎＩｎｔｅｇｒａｔｅｄ...

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简介：Thecellulosetris(4-methylbenzoate)hasbeensynthesisedbythecatalyticmethodandwassupportedatGasChromQ.Theabsorptioncapabilityofcellulosetris(4-methylbenzoate)usedasagaschromatographicstationaryphasewascharacterizedbychromatographicmethodandtheClausius-Clapeyronequation.However,n-alcohols(C1-C8)weresuccessfullyseparatedonthecolumnpackedwithGasChromQcoatedwithcellullosetris(4-methylbenzoate).

简介：Ru(bpy)_(3~(2+))electrochemiluminescence(ECL)wasappliedtodeterminationofrutin.ECLintensityofRu(bpy)_(3~(2+))couldbeenhancedinthepresenceofrutininbasicsolutiononplatinumelectrode.AtpH9.9,lightemissionintensitywasfoundtobelinearwithrutinintherangeof1-50mmol/L.

简介：美国华盛顿州引入《无毒儿童法案》，对使用对象为12岁以下儿童的产品中的磷酸酯类阻燃剂：磷酸三（1，3-二氯丙基）酯和磷酸三（β-氯乙基）酯，颁布禁令。该法案预计于2014年7月1日生效。

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简介：Organicmultiplequantumwells(OMQWs)consistingofalternatinglayersoforganicmaterialshavebeenfabricatedfromtris(8-hdroxyquinoline)aluminum(Alq)and2-(4-biphenylyl)-5-(4-tertbutylphenyl)-1,3,3-oxadiazole(PBD)byamultisource-typehigh-vacuumorganicmoleculardeposition.Fromthesmall-angleX-raydiffractionpatternsofAlq/PBDOMQWs,aperiodicallylayeredstructureisconfirmedthroughtheentirestack.TheAlqlayerthicknessintheOMQWswasvariedfrom1nmto4nm.Fromtheopticalaborption,photoluminescenceandelectroluminescencemeasurements,itisfoundthattheexcitonenergyshiftstohigherenergywithdecreasingAlqlayerthickness,ThechangesoftheexcitonenergycouldbeinterpretedastheconfinementeffectsofexcitonintheAlqthinlayers.Narrowingoftheemissionspectrumhasalsobeenobservedfortheelectroluminescentdevices(ELDs)withtheOMQWsstructureatroomtemperature.

简介：Asurface-renewabletris(1,10-phenanthroline-5,6-dione)iron(Ⅱ）hexafluorophosphate(FePD)modifiedcarbonceramicelectrodewasconstructedbydispersingFePDandgraphitepowderinmethyltrimethoxysilane(MTMOS)basedgels.TheFePD-modifiedelectrodepresentedpH-dependentvoltannetricbehavior,anditspeakcurrentswerediffusion-controlledin0.1mol/LNa2SO4+H2SO4solution(pH=0.4).Inthepresenceofiodate,clearelectrocatalyticreductionwaveswereobservedandthusthechemicallymodiffiedelectrodewasusedasanamperometricsensorforiodatencommonsalt.Thelinearrange,sensitivity,detectionlimitandresponsetimeoftheiodatesensorwere5×10^-6-1×10^-2mol/L,7.448μA·L/mmol,1.2×10^-6mol/Land5s,respectively.Adistinctadvantageofthissensorisitsgoodreproducibilityofsurface-renewalbysimplemechanicalpolishing.

简介：Tris)(η5-cyclopentadienyl-μ-carbonyl-iron)-μ3-nitrosylclusterwasobtainedfromthereactionofcyclopentadienyldicarbonylirondimerwithnitrogenmonoxideinxylene.Theclusterwascharacterizedbyelementalanalyses,IR,MSand1HNMR.Thecrystalstructureof[(η5-C5H5)(μ-CO)Fe]3(μ3-NO).C4H8OwasdeterminedbyX-raydiffractionanalysis.ItcrystallizesintheorthorhombicspacegroupPnma,a=9.053(2),6=10.545(2),c=22.525(4)A,V=2150.3(7)A3,Z=4,Dc=1.68g.cm-3;structuresolutionandrefinementbasedon1141reflectionswithI>3.0(I)(MoKa,A=0.71073A)convergedatR=0.0540.Theinfraredabsorptionbandat1325cm-1oftheμ3-NOinthecluster,whichisredshifted,showsthatμ3-NOisactivated.

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