简介:Aconductionchannelmodelispropsedtoexplainthehighconductivitypropertyofnc-Si:H.Detailedenergybanddiagramisdevelopedbasedontheanalysisandcalculation,andtheconductivityofthenc-Si:Hwasthenanalysedonthebasisofenergybandtheory.Itisassumedthattheconductivityofthenc-Si:Hstemsfromtwoparts:theconductanceoftheinterface,wherethetransportmechanismisidentifiedasathermal-assistedtunnelingprocess,andtheconductancealongthechannelaroundthegrain,whichmainlydeterminedthehighconductivityofthenc-Si:H.Theconductivityofnc-Si:Hiscalculatedandcomparedwiththeexperimentdata.Thetheoryisinagreementwiththeexperiment.
简介:Inthispaper,anewcollocationBEMfortheRobinboundaryvalueproblemoftheconductivityequation▽(γ▽u)=0isdiscussed,wheretheγisapiecewiseconstantfunction.Bytheintegralrepresentationformulaofthesolutionoftheconductivityequationontheboundaryandinterface,theboundaryintegralequationsareobtained.Wediscussthepropertiesoftheseintegralequationsandproposeacollocationmethodforsolvingtheseboundaryintegralequations.Boththetheoreticalanalysisandtheerroranalysisarepresentedandanumericalexampleisgiven.
简介:这研究的目的是用作为矩阵树脂作为传导性的fillers和修改环氧基树脂的organosilicone树脂经由solvothermal方法准备的银nanowires开发传导性的粘合剂。电的传导性的粘合剂和机械性质上的银nanowires/flakes的增加的效果被调查。与有银薄片fillers的常规传导性的粘合剂相比,有银nanowiresfillers的传导性的粘合剂的过滤阀值是10?%近似降低。然而,银nanowires的内容的进一步的上升没在传导性的粘合剂的电的传导性的改进上有明显的影响。传导性的粘合剂的传导性、机械的性质能由增加银nanowires是兼容的,哪个传统的银传导性的粘合剂reach.Graphical不能提炼银nanowires,舒适形态学经由alcohothermal准备了方法被介绍进传导性的粘合剂作文。它能被发现尽管存在,发现银nanowires在传导性的粘合剂相当被重叠crosslinking到某程度,然而,银nanowires不出现凝块的现象。有传导性的fillers能展出有利电、机械的性质的银nanowires的传导性的粘合剂。
简介:Theanalyticaltechniqueofconductometrictitrationisusedtocharacterizepolymericmaterials.Thistechniqueallowsobtainingthepolymerdryweightcapacity(DWC)andtheextentofreactionandestablishingtheoptimalnumberofwatermoleculespersulfonicgroups.InthisparticularcasethepolymermaterialunderstudywasNafion?117.Twodifferentreactionsweremade:Neutralizationandexchange.Bothofthemallowobtainingthesameresult.Conductometrictitrationscouldbeconsideredasagoodmethodtostudytheneutralizationandexchangereactionsforpolymericmaterialsusedinfuelcellsorelectrolyzers.Theimplementationofthisanalyticaltechniqueallowsreducingoperationtimeofthosetypesofmaterials.Thewaitingtimebetweendeterminationspermitstosaythattheamountofreactantconsumedandproductsobtainedwerethesameaftereachadditionoftitrant.
简介:Optimizationofcompositionandmicrostructureisimportanttoenhanceperformanceofsolidoxidefuelcells(SOFC)andlithium-ionbatteries(LIB).Forthis,theporouselectrodestructuresofbothSOFCandLIBaremodeledasabinarymixtureofelectronicandionicconductingparticlestoestimateefectivetransportproperties.Particlepackingsof10000spherical,binarysizedandrandomlypositionedparticlesarecreatednumericallyanddensifiedconsideringthediferentmanufacturingprocessesinSOFCandLIB:thesinteringofSOFCelectrodesisapproximatedgeometrically,whereasthecalenderingprocessandvolumechangeduetointercalationinLIBaremodeledphysicallybyadiscreteelementapproach.Acombinationofatrackingalgorithmandaresistornetworkapproachisdevelopedtopredicttheconnectivityandefectiveconductivityforthevariousdensifiedstructures.ForSOFC,asystematicstudyoftheinfluenceofmorphologyonconnectivityandconductivityisperformedonalargenumberofassemblieswithdiferentcompositionsandparticlesizeratiosbetween1and10.Incomparisontopercolationtheory,anenlargedpercolationareaisfound,especiallyforlargesizeratios.Itisshownthatincontrasttoformerstudiesthepercolationthresholdcorrelatestovaryingcoordinationnumbers.Theefectiveconductivityshowsnotonlyanincreasewithvolumefractionasexpectedbutalsowithsizeratio.ForLIB,ageneralincreaseofconductivityduringtheintercalationprocesswasobservedincorrelationwithincreasingcontactforces.Thepositiveinfluenceofcalenderingonthepercolationthresholdandtheefectiveconductivityofcarbonblackisshown.Theanisotropycausedbythecalenderingprocessdoesnotinfluencethecarbonblackphase.
简介:Polyparaphenylene(PPP)ispreparedbyAlCl3-CuCl2catalystswithbenzeneasthemonomerandisdopedbychemicalmethodandN^+ionimplantation.Theinfluencesoftheconcentration,temperatureandtimeofchemicaldopingandthedose,energyandtemperatureofionimplantation,onPPPconductivityareinvestigated.TheresultsshowedthattheconductivityofPPPcanbeimproved4-5ordersofmagnitudebyionimplantationandtheconductivityofPPPcanreachabout0.11S·cm^-1bychemicaldoping.Thecomparisonofstabilityofthematerialconductivebehaviorbyusingthetwodopingmethodsispresented.Itshowsthationimplantationisbetterthanchemicaldopinginstabilizingtheelectricconductivebehaviorforthematerial.
简介:Asymmetrictree-likebranchednetworksareexploredbygeometricalgorithms.Basedonthenetwork,ananalysisofthethermalconductivityispresented.Therelationshipbetweeneffectivethermalconductivityandgeometricstructuresisobtainedbyusingthethermal-electricalanalogytechnique.Inallstudiedcases,aclearbehaviourisobserved,whereangle(δ,θ)amongparentbranchingextendedlines,branchesandparameterofthegeometricstructureshavestrongereffectsontheeffectivethermalconductivity.Whentheangleδisfixed,theopticaldiameterratioβisdependentonangleθ.Moreover,γandmarenotrelatedtoβ.Thelongerthebranchis,thesmallertheeffectivethermalconductivitywillbe.Itisalsofoundthatwhentheangleθ<δ/2,thehighertheiterationmis,thelowerthethermalconductivitywillbeandittendstozero,otherwise,itisbiggerthanzero.Whenthediameterratioβ1<0.707andangleδisbigger,theoptimalkoftheperfectratioincreaseswiththeincreaseoftheangleδ;whenβ1>0.707,theoptimalkdecreases.Inaddition,theeffectivethermalconductivityisalwayslessthanthatofsinglechannelmaterial.Thepresentresultsalsoshowthattheeffectivethermalconductivityoftheasymmetrictree-likebranchednetworksdoesnotobeyMurray'slaw.
简介:ThepreparationofconductingPPQfilmwasfirstreportedinthepreviouspaper.Itisveryinterestingthatthisfilmishighlysensitivetomoistureinair.ThehydrationanddehydrationofthefilmareaccompaniedbychangenotonlyincolorbutalsoinconductivityandUV-visiblespectrum.TheconductingPPQisreducedtoPPQandlosesitsconductivityafterbeingsoakedinwater.
简介:Theeffectofpiezoelectricityonphononpropertiesandthermalconductivityofgalliumnitride(GaN)nanofilmsistheoreticallyinvestigated.TheelasticitymodelisutilizedtoderivethephononpropertiesinspatiallyconfinedGaNnanofilms.ThepiezoelectricconstitutiverelationinGaNnanofilmsistakenintoaccountincalculatingthephonondispersionrelation.Themodifiedphonongroupvelocityandphonondensityofstateaswellasthephononthermalconductivityarealsoobtainedduetothecontributionofpiezoelectricity.TheoreticalresultsshowthatthepiezoelectricityinGaNnanofilmscanchangesignificantlythephononpropertiessuchasthephonongroupvelocityanddensityofstates,resultinginthevariationofthephononthermalconductivityofGaNnanofilmsremarkably.Moreover,thepiezoelectricityofGaNcanmodifythedependenceofthermalconductivityonthegeometricalsizeandtemperature.TheseresultscanbeusefulinmodelingthethermalperformanceintheactiveregionofGaN-basedelectronicdevices.
简介:Poly(β-carboxyethylmethylsiloxane)-LiClO4andpoly(β-alkoxylethylmethylsiloxane)-LiClO4crosslinkedfllmshavebeenprepared.Theionicconductivityofthefilmsdependsonthepolymerspecies,concentrationoflithiumperchlorate,temperatureandcontentofcrosslinkingagent.Theeffectofhighpolarorganicsolvent1,4-butyrolactoneontheionicconductivityandmechanicalpropertiesofpoly(β-carhoxyethylmethylsiloxane)-LiClO4systemwasalsoinvestignied.
简介:土壤的理解在野火或控制灼伤以后的热电导率是重要的打管理和火以后的恢复努力。尽管玷污热电导率很好被学习了因为非火加热了土壤,全面数据评估在土壤上的从火的极端加热的长期的效果热电导率被限制。这研究的目的是由直接比较在土壤的有效热传导性上评估火的长期的影响加热火的,没有火控制通过一系列实验室研究玷污。热传导性在Manitou试验性的福雷斯特,以内从二个地点为十件土壤样品被测量科罗拉多,美国,为到浸透的剩余度的从浸透的水内容的一个范围。测量的热传导性与用文学用三个实验模型做的独立估计相比,包括坎贝尔等。(1994),C?t???????$
简介:Theeffectofnanoparticleaggregationonthethermalconductivityofnanocompositesornanofluidsistypicallynonnegligible.Auniversalmodel(Maxwellmodel)includingnanoparticleaggregationismodifiedinordertopredictthethermalconductivityofnanocompositesmoreaccurately.Thepredictedthermalconductivitiesofsilicaandtitaniananoparticlepowdersarecomparedfirstwiththatmeasuredbyahot-wiremethodandthenwiththoseinpreviousexperimentalworks.Theresultsshowthatthereisgoodagreementbetweenourmodelandexperiments,andthatnanoparticleaggregationinananocompositeenhancesthethermalconductivitygreatlyandshouldnotbeignored.Becauseitconsiderstheeffectofaggregation,ourmodelisexpectedtoyieldprecisepredictionsofthethermalconductivityofcomposites.
简介:Thetwo-dimensionalRayleigh-Taylorinstabilityproblemissimulatedwithamultiple-relaxation-timediscreteBoltzmannmodelwithagravityterm.Viscosity,heatconductivity,andPrandtlnumberef-fectsareprobedfrommacroscopicandnonequilibriumviewpoints.Inthemacrosense,bothviscosityandheatconductionshowasignificantinhibitoryeffectinthereaccelerationstage,whichismainlyachievedbyinhibitingthedevelopmentoftheKelvin-Helmholtzinstability.Beforethis,thePrandtlnumbereffectisnotsensitive.Viscosity,heatconductivity,andPrandtlnumbereffectsonnonequilib-riummanifestationsandthedegreeofcorrelationbetweenthenonuniformityandthenonequilibriumstrengthinthecomplexflowaresystematicallyinvestigated.