简介:Fourpolymerscontainingfive-memberedringsinthemainchain,withorwithoutconjugationstructurealongthebackboneandwithorwithoutconjugatedpendentgroups,weredesignedandsynthesizedbymetathesiscyclopolymerizationoffunctionalizedα,ω-diynes,andcyclopolymerizationoffunctionalizedα,ω-dienescatalyzedbytheα-diiminepalladium-basedcatalyst,respectively.Hightomoderatemonomerconversionswereachieved.Chainstructure,molecularweight,andmolecularweightdistribution(MWD)ofthecyclopolymerizationproductswerecharacterizedby1H-,13C-NMR,FTIR,andGPC.Thepolymersshowedregularmainchainstructures,moderatelyhighmolecularweight,andnarrowMWD.Thermalpropertiesandchainstackingbehaviorsofthepolymerswereinvestigatedbydifferentialscanningcalorimetry(DSC)andX-raydiffraction(XRD)aswellasatomicforcemicroscopy(AFM).ThepolymerwithconjugationsysteminboththebackboneandthependentgroupsexhibitedUV-Visabsorptionatamuchlongerwavelengththanthosewiththeconjugationonlyinthebackboneoronlyinthesidegroups.Thepolymerswithconjugatedbackboneneedmorespaceforchainstacking,andtheconjugatedbackbonecausesenhancedsizeofpolymerparticlesassembledfromsolution.Theresultsshowedthatprimarymicrostructuresofthepolymerexertedsignificantinfluencesonthephysicalproperties.
简介:Highlydiversifiedcolorationsamongspringtails(Collembola)havebeenwidelyusedforspeciesdiagnosis,buttheirphylogeneticsignificanceispoorlyknown.WeaddressedthisissueinthelargestEntomobryinaegenusEntomobrya,whichpossessesvariablecolorpatternsamongspecies.Therelationshipswithinthegenusandtoothergenerahavealsorarelybeenstudied.BasedonmaterialmainlyfromChina,wehaveconductedamultilocusphylogenyandtopologytestswithlikelihoodandBayesianalgorithms,andaccordinglydemonstratedthenon-monophylyofChineseEntomobrya.Thedivisionoffiveclades,includingEntomobryaandseveralrelatedgenera,coincidedwellwithfivetypesofcolorations,respectively.FurtheranalysesofdivergencetimeandhistoricalbiogeographyrevealedthatChineseEntomobryaoriginatedmainlyfromPalearctic(northernandwestern)ChinainthePaleoceneandEocene.Thisstudyhighlightsthegreatphylo?geneticvaluesaswellastaxonomicusesofcolorationinChineseEntomobrya.MultiplephylogeneticandbiogeographicoriginsofEntomobryaimplyitscomplicatedrelationshipswithbothscaledandunsealedgeneraofEntomobryinae.
简介:Pillar[n]arenesareanewkindofsupramolecularmacrocyclichostswhichhavedevelopedrapidlyduetotheiruniquetopologyandhighfunctionality,givingrisetomanyapplicationsintheconstructionofinterestingandfunctionalmaterials.Amongthem,water-solublepillar[n]arenesbearingtriethyleneoxide(TEO)chainshavedrawnincreasingresearchinterestduetotheiradvantageousproperties.Inthisreview,wesummarizedtherecentprogressofdynamicmaterialsfabricatedfromwatersolublepillar[n]arenesbearingTEOgroups,includingthermoresponsivematerialswithlowercriticalsolutiontemperature(LCST)behavior,cyclichostliquids,andsmartwindows.Itisanticipatedthatmoreandmore‘smart’supramolecularmaterialsbasedonmodifiedpillar[n]areneswillbedevelopedinthisburgeoningareaofresearch.
简介:TaijiquanisamartialartofthehighestorderisculturallyetchedintheChineseheritageandentrenchedinwushupulpfictionandkungfumovies.Thereinliestheenigma.Thegentleslow-motionpracticecannotbemoreremotefromthespeedandpowerofcombat.AndaddingtothemystiqueisthepropositionthatTaijiquan'skungfuprowessisnotdrawnfromthephysicalstrengthofthemusculaturebutfromsome"innerstrength"orNeijin.ThissacredbeliefwasdesecratedwhenafighterthrashedaselfproclaimedTaijiquangrandmasterignominiouslyin10secondsinanopenmatch.Taijiquanwasthenderidedasaboguscombatart.TheincidentshakesthefoundationofTaijiquanandputsintoquestionsmanyofitstoutedclaims,whichchallengesthescientificquestoftheart.ThepaperconfrontstheissuedirectlybystudyingthemanifestationofNeijinintheframeworkofsciencetoprovideascientificbasisfortheart.Ittranscribestheyin-yangmetaphysicsthatregulatesTaijiquantrainingintermsofthealignmentofmuscleactionstobalanceandtounifymomentum,whichdevelopsthecorestrengthofNeijinandtheunderlyinglife-forceQienergy.Fromthisflowsthekungfumarvels,whichlieinthelivelinessandagilityofNeijin'sresponseandintheforceensuingthatisoftherightvectorvalues,allessentialinthefluidityofcombatapplication.ThemartialaspectofTaijiquanprovidesaconcreterepresentationofNeijin,whichgivesanexperientialinsightintothemultifacetedconceptofQi,andinturnapathwaytotheexplorationofQiinphysiologyandthusinQienergymedicine.
简介:春节过了,咱们就正式进入了“猪年”,猪是十二生肖里的最后一位,这年翻过去就又是一个新的轮回。在猪年开始没多久,咱们就在“档案馆”里做了一个稿子,讲的是人类对猪的驯化。虽然猪老是跟不好的词儿连在一起,比如“猪头猪脑”——可是猪头猪脑真的很好吃啊——不过,猪其实真算得上是人类的好朋友了,因为它在很大范围内给人类提供了食用的肉,还有可供加工的皮革,甚至是它们的猪鬃毛,都曾经是重要的军需用品呢。第二次世界大战时,枪炮、军舰、飞机等的清洁和喷漆,一样也离不开猪鬃,中国还是最大的猪鬃出口国。从猪的驯化历史,我们可以看出人类是怎么样将自然资源变为自己可用,而在不同文化背景下的人类,又是如何看待自然。
简介:1997)andhasbecomeoneofthetwoflagshipsofjournalismprograms(TheotheristhejournalismprogramofthePeople’sUniversity)acrossChina.TheFudanJournalismCollegenotonlyhasitstraditionalsequenceinJournalism,thewriterhasconductedasurveyamongthejournalismstudentsaswellassomefacultymembersamongthefivejournalismprogramsinShanghaiinSeptember1999.,aconsistentprocessoflocalizationinitscurriculumandteachingmethodsaswellasitstargets.Thepaperwillfirstdiscusstheprocessoflocalizationinthe50yearsdevelopmentofjournalismeducationinChinaintermsofeducationalpurposesandchangesofcurriculum.BasedontheasurveyofthefivejournalismprogramsinShanghai
简介:APeruviannative,Dr.VelardeearnedhermedicaldegreefromtheNewYorkUniversitySchoolofMedicineinNewYorkandwentontocompleteherresidencytraininginInternalMedicineatColumbiaPresbyterianMedicalCenterandCardiovascularDiseasefellowshiptrainingatMountSinaiHospitalinNewYorkandBostonUniversity.Dr.GladysP.VelardeisAssociateProfessorofMedicine/CardiologyatTheUniversityofFlorida,JacksonvillewhereshedirectstheWomen’sCardiovascularHealthProgramandisDirectoroftheCardiovascularDiseaseFellowshiptrainingprogram.
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简介:WiththearchitecturalhistoryupontheQinghai-TibetPlateauspanningbackfourtofivethousandyears,theTibetanarchitecturehasgivenrisetothreebasicforms:palaces,monasteriesandcivilianresidences.
简介:ThomasHardy'scharactersinTheReturnoftheNativeliveinaworldgovernedbyaharshandindifferentironicGod.Hardyseesthereigningpoweroftheuniverseasbeingessentiallyunjustandmorallyblind,Hardy'spowerfulchancedeniesMrs.YeobrightandClymareunion,Hardyistellingatruthtoreaders
简介:通过对20世纪80年代以来具有代表性的华北夏谷区审(鉴)定的20个主栽谷子品种进行SSR标记多态性分析,研究了华北地区育成谷子品种的遗传多样性。49对引物在20个谷子品种中扩增出具有多态性的条带,共检测出142个等位变异,平均每个位点检测出的等位变异数为2.96个。标记位点多态性信息含量(PIC)变幅为0.0904~0.6896,平均为0.4168。20份材料间的遗传距离变幅为0.0173~0.9000,聚类分析将其分成3个类群,其中谷丰1号自成一类,表明谷丰1号的遗传距离较其他品种大。不同年代谷子品种间遗传距离分析结果显示,各年代品种之间的平均遗传距离由大到小依次是1980s>1990s>2000s>2010s,表明随着年代的递进育成品种的遗传差异减小,亲缘关系增近。
简介:Thispaperaimsatunderstandinghowpeopleexcludedfromtheconsumermarketendupinthecriminalmilieuasaviablesolutionforthem.Theliteraturereviewaddressesoneoftheaspectsofthecapitalistsystem,whichleadstoexclusionandsegregationinalargepartoftheconsumermarketpopulationand,thus,canengenderalienationandincursionintothecriminalworld.Weintendtoreferourstudytothemethodofarchivalethnography,sincethematerialofouranalysisispartofaresearchwithpeopleindeprivationofliberty.Theprocessofinterpretationmakesitpossibletounderstandthatthesegregatingdynamicsoftheconsumermarketisresponsiblebyanattemptofincludingpeople,eventhoughinanalienatedway,sincetheychosethecrimeinstead.