简介：Anewformulawaspresentedforlocatingdoublebondpositionindodecenols,tetrade-cenols,hexadecenolsandtheiracetates,basedonmassspectraldataofdimethyldisulfidederivatives.Inthisprocedure,molecularionandbasepeakionwereutilizedascharacteristicparameterstoidentifythepositionalisomers.Themethodwastestedwithmassspectraof25dimethyldisulfldederivativesofmono-unsaturatedacetatesandalcohols,andtheoriginaldouble-bondpositionineachisomerwaslocatedunambiguously.

简介：Aretentionpredictionsystem（RPS）ofsevenO-ethylN-isopropylphosphoro（thioureido）-thioatesinreversedphaseHPLCwasinvestigated.Thesystemisbasedonthesolventselectivitytriangleconcept.Threemolecularstructureparameters（hydrophobicityⅡ,substituentlengthL,andsubstituentmaximumwidthB5）wereusedtodescribethequantitativestructure-retentionrelation-ships.Withthesequantitativerelationships,theretentionbehavioursofothereighthomologsfordifferentmobilephasecompositionwerepredicted.Thepredictedvalueswereconsistentwiththemeasuredvalueswithinrelativeerrorof10%,whichmeansthatitispossibletoapplythereportedmethodtopredictretentionvaluesforqualitativepurposesfordifferentmobilephasecompositions.