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简介:Fractionalpyrolysisandone-steppyrolysisofnaturalalgaeCyanobacteriafromTaihuLakewerecomparativelystudiedfrom200to500°C.One-steppyrolysisproducedbio-oilwithcomplexcompositionandlowhighheatingvalue(HHV30.9MJ/kg).FractionalpyrolysisseparatedthedegradationofdifferentcomponentsinCyanobacteriaandimprovedtheselectivitytoproductsinbio-oil.Thatis,acidsat200°C,amidesandacidsat300°C,phenolsandnitrilesat400°C,andphenolsat500°C,weregotasmainproducts,respectively.HZSM-5couldpromotethedehydration,crackingandaromatizationofpyrolyticintermediatesinfractionalpyrolysis.AtoptimalHZSM-5catalystdosageof1.0g,theselectivitytoproductsandthequalityofbio-oilwereimprovedobviously.Themainproductsinbio-oilchangedtonitriles(47.2%)at300°C,indoles(51.3%)andphenols(36.3%)at400°C.Theoxygencontentwasreducedto7.2wt%and9.4wt%,andtheHHVwasraisedto38.1and37.3MJ/kgat300and400°C,respectively.Fractionalcatalyticpyrolysiswasproposedtobeanefficientmethodnotonlytoprovideapotentialsolutionforalleviatingenvironmentalpressurefromwaterblooms,butalsotoimprovetheselectivitytoproductsandobtainhighqualitybio-oil.
简介:SINOPECResearchInstituteofPetroleumProcessing(RIPP)hasdevelopedthedieselengineoilAPICJ-4,afterhavingpassedthe9enginetestsrequiredbytherelevantAPIspecificationstofillChina’sgapintheindependentdevelopmentofformulationsfordieselengineoilCJ-4,whichisasuccessfulattemptinbreakingtheforeigncompanies’technicalmonopolyonhigh-gradedieselengineoils.
简介:TheslidingfrictionandwearbehaviorsofMg–11Y–5Gd–2Zn–0.5Zr(wt%)alloywereinvestigatedunderoillubricantconditionbypin-on-diskconfigurationwithaconstantslidingdistanceof1,000minthetemperaturerangeof25–200°C.Resultsindicatethatthevolumetricwearratesandaveragefrictioncoefficientsdecreasewiththeincreaseofslidingspeeds,andincreasewiththeincreaseoftesttemperaturebelow150°C.ThehardandthermallystableMg12(Y,Gd)Znphasewithlong-periodstackingorderstructureinthealloypresentssignificantwearresistance.Thewearmechanismbelow100°Cisabrasivewearasaresultofplasticextrusiondeformation.Thecorporateeffectsofsevereabrasive,oxidative,anddelaminatingwearresultinthetribologicalmechanismabove100°C.
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简介:ThepolycrystallinephaseWO3/g-C3N4wassynthesizedunderstirringusingtungstenicacid(H2WO4)andgraphiticcarbonnitride(g-C3N4)asrawmaterials.ThecatalystwascharacterizedbyX-raydiffraction(XRD),scanningelectronmicroscopy(SEM),energydispersivespectroscopy(EDS),theFouriertransforminfraredspectroscopy(FT-IR),andtheBrunauer-Emmett-Telleranalysis(BET).ThepolycrystallinephaseWO3/g-C3N4wasdeterminedbyXRDtechnique.TheoxidativedesulfurizationprocesswasinvestigatedusingWO3/g-C3N4asthecatalyst,30%hydrogenperoxide(H202)astheoxidant,and1-butyl-3-methylimidazoliumtetrafluoroborate([bmim]BF4)ionicliquids(ILs)astheextractant.Theoperatingconditions,includingH2WO4amount,ILdose,H2O2volume,temperature,catalystdosage,andtypesofsulfurcompounds,weresystematicallyresearched.Thedesulfurizationratecouldreach98.46%forremovingdibenzothiophene(DBT)fromthemodeloilunderoptimalreactionconditions.Inaddition,thecatalyticactivitywasslightlydecreasedafterfiverecyclesofcatalysts.Thereactionkineticsanalysisshowsthattheoxidativedesulfurizationsystemwasinaccordwiththefirst-orderreactionkineticsequation.Themechanismofoxidativedesulfurizationwasproposed.
简介:1.ObjectiveAseriesofMesozoic-CenozoiccontinentalsedimentarybasinsexistinNorthChina,coexistingwithcoal,oil/gas,andsaltresources.Manypreviousdrillingprojectshavebeenconductedwithinthesebasinstoexplorecoal,petroleum,andmineralresources,however,thesedatahavenotbeenintegratedduetodifferentindustriesowners.Inordertoefficientlyexplorethelarge-sized,easilyextracted,andenvironmentallyfriendly,sandstone-typeuraniumdeposits,previouscoalandoilexplorationdrilling-holedataaresystematicallycollected,processed,andanalyzedtoimprovethesandstone-typeuraniumprospectingexploitation.Atthesametime,wealsodiscussedtheuraniumsource,ore-formingprocessandmodelforthesandstone-typeuraniumdeposits.
简介:ThemoleculartransformationsofcarboxylicacidsinheavyacidicSLcrudebeforeandaftertrueboilingpointdistillationwereexaminedbyultra-highresolutionnegative-ionelectrosprayionization(ESI)Fouriertransformioncyclotronresonancemassspectrometry(FT-ICRMS).Theacidclass(heteroatomnumber),type(znumbers)andcarbonnumberdistributionswerepositivelycharacterized.Itwasfoundoutthatthetotalacidnumber(TAN)ofSLcrudedecreasedaftertrueboilingpointdistillation,andtheabundanceofO2classinmassspectrawasalsofoundtobereducedfrom67.6%to34.5%inSLTBPmixedcrudeasmeasuredbyMSspectra,indicatingtoapotentialcarboxylicaciddecomposition.However,itwasinterestingthatthecarboxylicacidstypedistributioninbothoilswasalmostthesamealthoughtheirrelativeabundanceinSLTBPmixedcrudeturnedtobemuchlower,suggestingthatvariouspetroleumcarboxylicacidtypeshavethesimilarthermaldecompositionreactionbehavior.Furthermore,foreachO2typeofacidsinSLTBPmixedcrude,theabundanceofcarboxylicacidswithcarbonnumberhigherthan35wasreducedgreatly,especiallyforthosewithcarbonnumberhigherthan60,themasspeaksofwhichwerenearlytotallyremoved,indicatingthatthelargecarboxylicacidmoleculesinheavyfractionsdecomposedmoresignificantlybecauseoflongerheatingtimeduringthetrueboilingpointdistillationprocess.Asaresult,thereductionofTANmaybecausedbythethermaldecompositionofcarboxylicacidsespeciallythosewithhighcarbonnumber,suggestingthatquickdistillationormuchlowerpressureisrequiredtoavoidthethermaldecomposition.
简介:[摘 要] 随着经济飞速发展,社会对于石油等化石能源的依赖程度越来越高,长输管道作为其重要运输载体得到迅猛发展。然而管道的腐蚀问题作为影响输油管道的安全稳定使用的最大因素,逐渐被相关部门列为重点关注问题。本文以油气管道为对象,结合石油管道所面临的主要腐蚀环境,分析影响管道腐蚀的主要因素,进一步探讨管道相关防腐措施,提升管道的防腐质量,延长管道的运行寿命。
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简介:Thisexperimentusedwhole-cellpatch-clamptechniquetoinvestigatethecourseofrecoveryfromuse-dependentblockofNa+channels(Nav1.5)inhumanembryonickidney(HEK)cells,onwhichtoverifytheeffectsofvolatileoilofNardostachychinesisBatal(Gansong).MethodsTwopulsesgeneratedbycomputerfollowedbyarecoverypulseandatestpulse,theintervaldurationbetweenthetwopulsesvariedfrom16msto1s,andholdingpotentialis-80mVto-140mV.ThepeakNa+currentforagivenrecoverytimewasnormalizedtothefullyrecoveredpeakcurrent,andthenormalizedvaluewastheplotasafunctionoftherecoverytimetostudytheeffectsof3ppmconcentrationGansongvolatileoilonrecoveryfromuse-dependentblockofNav1.5inHEK.ResultsItshowedthatGansonggroup,comparingwithcontrolgroup,delayedthetimecoursesofrecoveryfromuse-dependentblock[(33.2±5.77)msforcontrolgroupand(52.5±6.08)msfor3ppmGansonggroup,P<0.05].InthepresenceofGansong,inhibitionoftheNa+currentwasenhancedbyincreasingfrequencyofdepolarizingpulsefrom56.5msto16ms.Inthecontrolgroup,thetimecourseofrecoveryshowedthatrecoverystartedat19.5msandfinishedby36.5ms.InthepresenceofGansong,thetimecourseofrecoveryshowedthatrecoverystartedat36.5msandfinishedby56.5ms.Na+currentsrecoveredfromtheuse-dependentblockvaryingwithholdingpotential(holdingpotential-dependent).ConclusionsTheresultssuggestedthatNa+currentsrecoveredfromtheuse-dependentblockcorrelatedwithpersistenttime,holdingpotential.TheGansongvolatileoilhasinhibitiveeffectontheNa+currentrecovery.
简介:摘要: 本文针对海上采油平台井下作业连续油管作业的常见类型进行了列举,结合海上平台的特点及常见作业的特点进行了可能出现的井控事件分析,对井控演习预案及应急逃生方案进行了研究。