简介：ThetransportpropertieswerestudiedforrareearthmanganeseoxideLa0.67Cao.33Mn1-xFexO3(x=0-O.3)systems.ItisfoundthatwithincreasingFe^3+-dopingcontentx,theresistanceincreasesandtheinsulator-metaltransitiontemperature(T1M)shiftstolowertemperature.Ifthedopingcontentissmall,thetransportpropertiesmanifestmetalliccharacteristicsinthetemperaturerangeofT＜T1M,whiletheywillobeyathermalactivationmodelinthetemperaturerangeofT＞T1M.SuchabehaviormaybeattributedtotheFe^3+-dopingandpossibleMnionsscatteringtoelectrons.TheFe^3+dopingmayleadtotheformationofFe^3+-O^2--Mn^4+channels,whichcouldterminatethedoubleexchangeMn^3+-O^2--Mn^4+channels.TheantiferromagneticclustersofFeionsmayinducetheMnionstoscettertotheelectrons.

简介：经光学显微镜和扫描电子显微镜观察结果表明,干壁钉用ML15钢冷拔断裂主要因材料中氧化物夹杂的大量存在所致;搓丝尖裂除与材料中氧化物夹杂存在有关外,还与热处理不当,退火温度偏高,时间较长而形成游离渗碳体有关。

简介：针对耐硫酸露点腐蚀用钢09CrCuSb连铸时出现的铸坯表面裂纹缺陷,通过实验室高温热塑性分析,研究了其形成原因及控制方法。结果表明,连铸机二冷区持续保持强冷,铸坯表面金相组织晶粒度明显细化,板坯的热塑性得到改善,铸坯表面裂纹缺陷得到有效控制。

简介：开发了160t电炉＋50t中频炉双联法生产不锈钢预熔液工艺,实现了高碳铬铁与铬镍生铁分工序熔化,缩短了电炉冶炼时间,实现了电炉、中频炉与AOD节奏匹配;采用电炉＋中频炉双联法工艺,开发了钢包内还原电炉渣中Cr2O3工艺,提高了铬回收率,降低了电极消耗,与原工艺相比,铬回收率提高2.2%,电极消耗降低0.8kg/t,降低了不锈钢冶炼成本。

简介：InordertoimprovethehydrogenationanddehydrogenationperformancesoftheMg2Ni-typealloys,MgwaspartiallysubstitutedbyLainthealloy,andmeltspinningtechnologywasusedforthepreparationoftheMg20-xLaxNi10(x=0,2,4,6)hydrogenstoragealloys.ThestructuresofthealloyswerestudiedbyX-raydiffraction(XRD),scanningelectronmicroscopy(SEM)andhigh-resolutiontransmissionelectronmicroscopy(HRTEM).Itwasfoundthatnoamorphousphaseformedintheas-spunLa-freealloy,buttheas-spunalloyscontainingLaheldamajoramorphousphase.WhenLacontentx≤2,themajorphaseintheas-castalloyswasMg2Niphase,butwithfurtherincreaseofLacontent,themajorphaseoftheas-castalloyschangedintoLaNi5+LaMg3phase.Thermalstabilityoftheas-spunalloyswasstudiedbydifferentialscanningcalorimetry(DSC),showingthatspinningratewasanegligiblefactoronthecrystallizationtemperatureoftheamorphousphase.Thehydrogenabsorptionanddesorptionkineticsoftheas-castandas-spunalloysweremeasuredusinganautomaticallycontrolledSievertsapparatus,confirmingthatthehydrogenabsorptionanddesorptioncapacitiesandkineticsoftheas-castalloysclearlyincreasedwithrisingLacontent.ForLacontentx=2,theas-spunalloydisplayedoptimalhydrogendesorptionkineticsat200°C.

简介：通过对亚硫酸钠工艺和SUPCONJX－300X集散系统结构的介绍，论述控制难点及组态、调试过程中需注意的问题。

简介：本文介绍采用新型阳极保护不锈钢酸冷却器,以解决SO3吸收工艺中铸铁列管式酸冷却器腐蚀严重的问题,同时介绍设置一套封闭式冷却水循环系统与之相配套后的运行效果和经验。

简介：文章分析了金川矿区深部开拓的围岩特点和支护方式，提出了针对金川矿区深部开拓不良岩层中采用网构钢拱架联合支护的支护结构、施工工艺和遇到典型问题的解决方法。

简介：通过分析三钢200m^2烧结机的点火现状及原因,提出了低负压点火烧结技术的改造方案。生产实践表明:改造后烧结料层厚度提高了54mm,烧结矿产量增加了4t/h,点火煤气消耗降低了159m^3/h,取得了良好的经济效益。

简介：Duetotheremarkablemagnetoresistance(MR)effectonperovskite-typemanganite,magnetoelectronicsandspintronicshavebecomeattractivesubjectsofexperimentalandtheoreticalinvestigationsfortheapplicationpurpose.(La0.9Nd0.1)2/3Ca1/3Mn1-xFexO3(x=0,x=0.05)werepreparedsuccessfullybysol-gelmethod.Thestructure,magneticproperties,andtransportpropertiesofthecompoundswereinvestigated.Themagnetoresistanceeffectdependsonthecompositionandthetemperature.XRDpatternsshowthatthecompoundisasinglephasepolycrystalwithpseudocubicstructure.Alargenegativeisotropicmagnetoresistanceeffectinthesampleswereobservedatlowtemperatureregion.ThemaximumMRofthesampleswas77%and97%,respectively.Itwasmostlikelyduetothescatteringorthetunnelingtransportofspin-polarizedcarriersinlatticeunderstrongmagneticfield.

简介：采用元胞自动机模型建立了05Cr17Ni4Cu4Nb不锈钢固溶过程的二维模型,模拟了固溶过程中的晶粒形核生长以及化合物相的扩散溶解,模拟结果动态地再现了固溶过程的微观组织特征。通过该模型分析了固溶温度和固溶时间对固溶处理后微观组织的影响。

简介：太原钢铁集团公司和成都无缝钢管公司双方利用各自装备优势，通过合作解决了生产大口径不锈钢冷拔无缝钢管的关键－大型不锈钢管坯和热穿孔。详细介绍了Φ１８０×１５冷拔不锈钢无缝管的管坯制造、热穿孔、冷拔（扩）、热处理等生产工艺和产品的良好市场前景。

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简介：NominalcompositionofCa1-xZnxTiO3:0.002Pr3+(x=0.000～0.200)phosphorswerepreparedbyconventionalsolidreactionroute.XRDandPLmeasurementswereusedtoinvestigatethesolid-solutionstructureandluminescencepropertiesofZn-dopedCa1-xZnxTiO3:0.002Pr3+phosphors.Theeffectofsolid-solutionstructureformedbysubstitutionbetweenCa2+andZn2+ionsontheluminescentpropertieswasanalyzed.Theresultsrevealthat,withtheincreaseofZnsubstitutioncontentbelow0.010,latticeparametersandtheintensityofexcitationpeakatboth260and330nmaswellasthecorresponding610nmemissionintensityaremonotonouslydecreasedquicklyinasimilartendency.Also,theevolutionofluminescenceintensityandcrystalcellparametersagainstZndopingconcentrationareingoodagreement.AboveresultsarecloselyrelatedwiththestructurechangewithinCa1-xZnxTiO3:0.002Pr3+solid-solutionphaseformedbytheZnionssubstitutionfortheCasites.Presentstudyrevealsthatthesolid-solutionstructureformedbysubstitutionbetweenCa2+andZn2+ionshassignificanteffectontheluminescencepropertiesofsinglephaseCa1-xZnxTiO3:0.002Pr3+phosphors.

简介：Whitelight-emittingYVO_4：1mol.%Dy~（3＋）,xmol.%Eu~（3＋）phosphorpowderswithordermorphologyandwellcrystallizationwerehydrothermallysynthesizedat180°C.Themicrostructure,white-lightemission,andlight-emittingmechanismofthepowderswerecarefullystudiedusingX-raydiffractometry,scanningelectronmicroscopyandphotoluminescencespectra.TheexcitationandemissionspectraofthephosphorpowdersindicatedthecoexistenceofefficientenergytransferfromEu~（3＋）toDy~（3＋）andinefficientenergytransferfromDy~（3＋）toEu~（3＋）besidestheenergytransferfromVO_4~（3–）toEu~（3＋）.IncreasingtheEu~（~（3＋））concentrationinitiallyenhancedandthenweakenedtheluminescentintensityofDy~（3＋）.Thewhite-lightemissionsofYVO_4：1mol.%Dy~（3＋）,xmol.%Eu~（3＋）phosphorpowderswerebothrelatedtotheenergytransferbetweenVO_4~（3–）andDy~（3＋）/Eu~（3＋）,aswellasbetweenEu~（3＋）andDy~（3＋）.TheinefficientenergytransferfromDy~（3＋）toEu~（3＋）wasfirstfound.