简介:Multi-nucleontransferreactionplaysanimportantroleinthesynthesisofnewnuclides[1].Inthereactionsof20Ne+209Bi,someshort-livednucleiproducedbytransferring26nucleonswerediscovered.Theexperimentof20Ne+209Biwasperformedatgas-filledrecoilseparatorinLanzhou[2].A400g/cm2thick209Bitargetwasbombardedwith20NebeamdeliveredbyacceleratorHIRFL.
简介:Inthiswork,a2Dcovalenttriazine-basedframeworkwaspreparedbyusing1,3-dicyanobenzo[c]thiophene(DCBT)asmonomertoeffectivelycaptureCO2.TheresultingCTF-DCBTwascharacterizedbyFT-IR,XPS,PXRD,elementalanalysis,SEM,TEM,andN2adsorption-desorption.TheresultsindicatethatCTF-DCBTispartiallycrystallineandhasultramicropore(6.5A?)aswellashighheteroatomcontents(11.24wt%and12.61wt%forNandS,respectively).Inaddition,theBETsurfaceareaandtotalporevolumeofCTF-DCBTare500m2/gand0.26cm3/g,respectively.CTF-DCBTpossessesexcellentthermalstability(450°C)andchemicalstabilitytowardsboilingwater,4MHCl,and1MNaOH.TheCO2adsorptioncapacityofCTF-DCBTis37.8cm3/gat1barand25°C.Aftersixadsorption-desorptioncycles,thereisnoobviouslossofCO2uptakeobserved.Duetotheultramicroporeandhighheteroatomcontents,CTF-DCBThashighisostericheatsofadsorptionforCO2andhighselectivitiesofCO2overN2andCH4.At25°C,theCO2/N2andCO2/CH4selectivitiesare112.5and10.3,respectively,whicharehigherthanthoseofmostPOFs.BreakthroughcurvesindicatethatCTF-DCBTcouldeffectivelyseparateCO2/N2andCO2/CH4mixtures.
简介:PtRu/SnO2/Ccatalystwaspreparedinapolyolprocess,followedbyreductiontreatmentandalkalineetching.X-raydiffraction,transmissionelectronmicroscopewithenergydispersivespectrometerandXrayphotoelectronspectroscopywereusedtocharacterizethemorphology,structureandcompositionofthecatalysts.COandmethanolelectro-oxidationactivitiesofthecatalystswereevaluatedbyCOstrippingvoltammetry,cyclicvoltammetryandchronoamperometrymeasurements.ReductiontreatmentofthepreparedPtRuSnO2/CcatalystinapolyolprocessinducedtheenrichmentofSnonthesurface,inhibitingmethanoldissolutionandCOadsorptiononPt.AlkalineetchingremovedSnorSnOxandthusexposedPtRuonthesurface,resultinginenhancedactivitiesforCOandmethanolelectro-oxidationduetothesynergyeffectsofPtRuonthesurfaceandSnspeciesbeneath.
简介:CO2conversionviaphotocatalysisisapotentialsolutiontoaddressglobalwarmingandenergyshortage.PhotocatalysiscandirectlyutilizetheinexhaustiblesunlightasanenergysourcetocatalyzethereductionofCO2tousefulsolarfuelssuchasCO,CH4,CH3OH,andC2H5OH.Amongstudiedformulations,CubasedphotocatalystsarethemostattractiveforCO2conversionbecausetheCu-basedphotocatalystsarelow-costandabundancecomparingnoblemetal-basedcatalysts.Inthisliteraturereview,acomprehensivesummaryofrecentprogressonCu-basedphotocatalystsforCO2conversion,whichincludesmetalliccopper,copperalloynanoparticles(NPs),copperoxides,andcoppersulfidesphotocatalysts,canbefound.Thisreviewalsoincludedadetaileddiscussiononthecorrelationsofmorphology,structure,andperformanceforeachtypeofCu-basedcatalysts.Thereactionmechanismsandpossiblepathwaysforproductionsofvarioussolarfuelswereanalyzed,whichprovideinsightintothenatureofpotentialactivesitesforthecatalysts.Finally,thecurrentchallengesandperspectivefutureresearchdirectionswereoutlined,holdingpromisetoadvanceCu-basedphotocatalystsforCO2conversionwithmuch-enhancedenergyconversionefficiencyandproductionrates.
简介:Nuclearmassmeasurementsprovidevaluableinformationonthenuclearbindingenergywhichreflectsthesummedresultofallinteractionsamongitsconstituentprotonsandneutrons.Thesystematicandaccurateknowledgeofnuclearmasseshavewideapplicationinmanyareasofsubatomicphysicsrangingfromnuclearstructureandastrophysicstothefundamentalinteractionsandsymmetriesdependingontheachievedmassprecision[1].
简介:WediscussthenonlinearSchrdingerequationwithvariablecoefficientsin2Dgraded-indexwaveguideswithdifferentdistributedtransversediffractionsandobtainexactbrightanddarksolitonsolutions.Basedonthesesolutions,wemainlyinvestigatethedynamicalbehaviorsofsolitonsinthreedifferentdiffractiondecreasingwaveguideswiththehyperbolic,GaussianandLogarithmicprofiles.Resultsindicatethatforthesameparameters,theamplitudeofbrightsolitonsintheLogarithmicprofileandtheamplitudeofdarksolitonsintheGaussianprofilearebiggestrespectively,andtheamplitudeinthehyperbolicprofileissmallest,whilethewidthofsolitonshastheoppositecase.
简介:RecentexperimentalresultsofHL-1MtokamakandprogressofHL-2Aprojectarepresented.Strongfishboneinstabilitywasobservedduringoff-axisECRH.ThisisfirstobservationofthefishboneinstabilitypurelydrivenbyenergeticelectronsproducedbyECRH.TheMBIwasfirstproposedanddemonstratedonHL-1M.RecentlynewresultsofMBIexperimentwereobtainedbyincreasingthepressureofgas.Astair-shapedensityincrementwasobtainedwithhigh-pressuremulti-pulseMBIjustlikethedensityevolutionbehaviorduringthemultipelletinjection.Itisshown
简介:Themaingoalofdivertorphysicsistodeterminetheedgeplasmatemperature,density,powerdispersal,powerasymmetrybetweeninwardtargetandoutwardone,thecontrolabilityofimpurityandneutralparticles.Aboveparameterswillchangewithplasmadensityorheatingpower.Theycanbedividedinto3regimes:linearregime,highrecyclingoneanddetachedone.
简介:Theneutron-richisotopeswithN40below68Ni,inmanywaysbehavesimilartothe“islandofinversion”nucleiwithN20.Wereportonthemeasurementsofexcitedstatesof63;65;67Mnviain-beam-rayspectroscopy.TheexperimentwasperformedattheRadioactiveIsotopeBeamFactory,RIKEN.Analysisofdatafor63;65;67MnobtainedintheSEASTARcampaignhasbeendone.Afewtransitionshavebeenidentifiedineachofthemprovidingachancetostudythesystematicstructureevolutionofn-richMnisotopesnearN40.
简介:Recently,bismuthsulfide(Bi2S3)hasattractedmuchattentioninthethermoelectriccommunityowingtoitsabundance,lowcost,andadvancedproperties.However,itspoorelectricaltransportpropertieshavepreventedBi2S3devicesfromrealizinghighthermoelectricperformance.Inthiswork,ourmotivationistodecreasethelargeelectricalresistivity,whichisrecognizedastheoriginofthelowZTvalueinundopedBi2S3.Wecombinedmeltingandsparkplasmasintering(SPS)inacontinuousfabricationprocesstoproduceBi2S3–xSex(x=0,0.09,0.15,0.21)andBi2S2.85–ySe0.15Cly(y=0.0015,0.0045,0.0075,0.015,0.03)samples.OurresultsshowthatSealloyingatSsitescannarrowthebandgapandactivateintrinsicelectronconduction,leadingtoahighpowerfactorof~2.0μW·cm–1·K–2atroomtemperatureinBi2S2.85S0.15,about100timeshigherthanthatofundopedBi2S3.Moreover,ourfurtherintroductionofClatomsintotheSsitesresultedinasecond-stageoptimizationofcarrierconcentrationandsimultaneouslyreducedthelatticethermalconductivity,whichcontributedtoahighZTvalueof~0.6at723KforBi2S2.835Se0.15Cl0.015.OurresultsindicatethathighthermoelectricperformancecouldberealizedinBi2S3withearth-abundantandlow-costelements.
简介:ThispaperconstructstheinteractionpotentialoftheSH(X2Π)radicalbyusingthecoupled-clustersinglesdoubles-approximate-triplestheorycombiningthecorrelation-consistentquintuplebasissetaugmentedwiththediffusefunctions,aug-cc-pV5Z,inthevalencerange.Employingthepotential,itaccuratelydeterminesthespectroscopicparameters.ThepresentDe,Re,ωe,ωeχe,αeandBevaluesareof3.7767eV,0.13424nm,2699.846cm?1,47.7055cm-1,0.2639cm-1and9.4414cm-1,respectively,whichareinexcellentagreementwiththoseobtainedfromthemeasurements.Atotalof19vibrationalstateshasbeenfoundwhenJ=0bysolvingtheradialSchrdingerequationofnuclearmotion.Thecompletevibrationallevels,classicalturningpoints,initialrotationandcentrifugaldistortionconstantswhenJ=0arereportedforthefirsttime,whichareingoodaccordwiththeexperimentalresults.Thetotalandvariouspartial-wavecrosssectionsarecomputedfortheelasticcollisionsofsulfurandhydrogenintheirgroundstatesatlowtemperatureswhentwoatomsapproacheachotheralongtheSH(X2Π)potentialenergycurve.Overtheimpactenergyrangefrom1.0×10-11to1.0×10-4a.u.,eightshaperesonanceshavebeenfoundinthetotalelasticcrosssections.Foreachshaperesonance,theresonantenergyisaccuratelycalculated.Carefulinvestigationshavepointedoutthattheseresonancesresultfromthel=0,1,2,3,4,6,7,8partial-wavecontributions.
简介:Multilayerblackphosphorus(BP)nanoplateletsofdifferentthicknesseswerepreparedbytheliquidphaseexfoliationmethodanddepositedontoyttriumaluminumgarnetsubstratestoformsaturableabsorbers(SAs).Thesewerecharacterizedwithrespecttotheirthickness-dependentsaturableabsorptionpropertiesat3μm.TheBP-SAswereemployedinapassivelyQ-switchedEr:Lu2O3laserat2.84μm.ByusingBPexfoliatedindifferentsolvents,stablepulsesasshortas359nsweregeneratedatanaverageoutputpowerofupto755mW.Therepetitionrateintheexperimentwas107kHz,correspondingtoapulseenergyof7.1μJ.TheseresultsprovethatBP-SAshaveagreatpotentialforopticalmodulationinthemid-infraredrange.
简介:Sn-dopedTiO_2nanoparticleswithhighsurfaceareaof125.7m~2·g~(-1)aresynthesizedviaasimpleone-stephydrothermaimethodandexploredasthecathodecatalystsupportforprotonexchangemembranefuelcells.ThesynthesizedsupportmaterialsarestudiedbyX-raydiffractionanalysis,energydispersiveX-rayspectroscopyandtransmissionelectronmicroscopy.Itisfoundthattheconductivityhasbeengreatlyimprovedbytheadditionof30mol%SnandPtnanoparticlesarewelldispersedonTi_(0.7)Sn_(0.3)O_2supportwithanaveragesizeof2.44run.ElectrochemicalstudiesshowthattheTi_(0.7)Sn_(0.3)O_2nanoparticleshaveexcellentelectrochemicalstabilityunderahighpotentialcomparedtoVulcanXC-72.Theas-synthesizedPt/Ti_(0.7)Sn_(0.3)O_2exhibitshighandstableelectrocatalyticactivityfortheoxygenreductionreaction.ThePt/Ti_(0.7)Sn_(0.3)O_2catalystreservesmostofitselectrochemicallyactivesurfacearea(ECA),anditshalfwavepotentialdifferenceis11mV,whichislowerthanthatofPt/XC-72(36mV)under10hpotentialholdat1.4Vvs.NHE.Inaddition,theECAdegradationofPt/Ti_(0.7)Sn_(0.3)O_2is1.9timeslowerthancommercialPt/XC-72under500potentialcyclesbetween0.6Vand1.2Vvs.NHE.Therefore,theassynthesizedPt/Ti_(0.7)Sn_(0.3)O_2canbeconsideredasapromisingalternativecathode,catalystforprotonexchangemembranefuelcells.
简介:Todemonstratetheviabilityofsteady-statetokamakoperationinahighperformanceregime,whichisoneofthekeyphysicsissuesforaviableeconomicfusionreactor,thequasi-stationaryreversedshear(RS)modeofoperationintheHL-2AtokamakhavebeenmodeledwiththeTRANSPcode.InordertosustaintheRSoperationtowardssteady-state,off-axiscurrentdrivewithlowerhybrid(LH)waveat2.45GHzisusedtocontrolthecurrentprofile.
简介:AnapplicatiopnoftheopticalpyrometerisstudiedformeasuringmonochromaticemissivitiesofcementclinkerwithvariousFe2O3contnet.Theidsaofusing“brightnesstemperature”isintroducedintotheeimssivitymeasurement.Inthismethod,thereisnoneedformeasuringanactualtemperatureofsamplesurfaces,onlywithdeterminingbothbrightnesstemperaturesofasampleandablackbodycantherequiredemissivitybeevaluatedaccordingtoWien'sradiationlaw.Inpractice,thecementclinkerisregardedasagreybody,themonochromaticemissivityisapproximatelyequaltothetotalemissivity,soasingle-colouropticalpyrometerisappliedforthispurpose,Testmeasurementsarecarriedouton10kindsofcementclinkers,Experimentaldataaretreatedbytheleastsquaremethod.Asaresult,theemissivityvariationwithtemperatureatacertainFe2O3contentisquitewellrepresentedbyεn=a+bT.Furthermore,thisworkfirstreportedthattheeimissivitiesofcementclinkerchangeconsierablywithFe2O3contents.Inmultiplecementproductionthisconclusionisveryimportant.
简介:Ithasbeenproposedthatfusionreactionsbetweenneutron-richlightnuclei,forexample24C,24Oand28Ne,maycontributetoachievingtheignitiontemperatureforexplosivecarbonburningprocessduringsuperbusrsts[1,2].Studiesoffusionreactionsinvolvingneutron-richnucleiarebeyondordinaryexperimentaltechniques,sincetheintensityofradioactivebeambecomelowforthesemeasurements[3].TheactivetargettechniqueusingTPC(TimeProjectionChamber),withpropertiesofmulti-sampling,highefficiencyandlowbackground,isasuitablesolutiontotheproblem.