简介：Asidechainliquidcrystallinecopolysiloxane,whichwouldshowelectro-opticeffectsasknownfromlowmassliquidcrystal,wassynthesizedbyhydrosilylationreaction,andthetwohomologousmonomerswithdifferentlengthspacerscontainingSchiff’sbasemesogenwith—NO2terminatedgroupweregraftedtoapolysiloxanemainchain.Residualmonomerincrudeproductiseffectiveinreinforcingtheresponsetoanelectricfieldoverthatofpurepolymericliquidcrystal.
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![SYNTHESIS OF POLY{（p—PHENYLENEVINYLENE）—alt—p,m—[<b style='color:red'>2</b>—PHENYL—5—（p—PHENYLENEVINYLENE）—1,3,4—OXADIAZOLYL]} WITH DEFINED CONJUGATION LENGTH AND IMPROMVED SOLUBILITY](/image/thesis1 "SYNTHESIS OF POLY{（p—PHENYLENEVINYLENE）—alt—p,m—[<b style='color:red'>2</b>—PHENYL—5—（p—PHENYLENEVINYLENE）—1,3,4—OXADIAZOLYL]} WITH DEFINED CONJUGATION LENGTH AND IMPROMVED SOLUBILITY")