简介:Anewtypeoffiberopticglucosebiosensorbasedonfluorescencequenchinghasbeendesignedanditspropertieshavebeenstudied.Glucosecanbeoxidizedbyoxygenwhenglucoseoxidaseareusedasthecatalyst,therefore,theconcentrationofglucosecanbemeasuredbydetectingtheconsumptionofoxygen.Forthedetectionofoxygenconcentration,theruthenium(Ⅱ)complex,Ru(bpy)3Cl2,wereusedasthefluorescenceindicatoranditsfluorescencelifetimeweredetectedbylock-intechnology.Thedetectingrangeofthesensoris50-500mg/dlanditsresponsetimeis30seconds,showingthatthiskindofsensorsispossibletobeusedinclinicaldiagnosisanddetection.
简介:Usingmoleculardynamics(MD)methodscombiningwithtwo-stepradiationheatingmodel,themechanismsofablationandthethermodynamicstatesatNisurfaceunderfemtosecondlaserirradiationareinvestigated.Simulationresultsshowthatthemainmechanismsofablationareevaporationandtensilestressesgeneratedinsidethetarget.Thevelocityofstresswaveispredictedtobenearlyequaltosoundvelocity.Theratesofablationatdifferentfluencesobtainedfromsimulationsareingoodagreementwithexperimentaldata.Superheatingphenomenonisalsodiscovered.
简介:Alightpurplishredsapphireisheattreatedinanairtightcrucible.Thesamplechangeslittleincolorafterreceivingheattreatmentat1100°C,butturnstolightblueandblueafterbeingtreatedat1200°Cand1300°C,respectively.Beforeheating,theUV-VISabsorptionspectraofthesamplearedominatedbythe551nmbroadabsorptionbandcontributedbythed-electrontransition~4A_2→~4T_2ofCr~(3+).Afterheating,theUV-VISabsorptionspectraaredominatedbythe563nmbroadabsorptionbandcontributedbytheintervalencechargetransferofFe~(2+)-Ti~(4+).ThexrayphotoelectronspectroscopytestrevealsthattheFe~(2+)andTi~(4+)ioncontentsincreasewithincreasingtemperature.ThesapphirechangingfromlightpurplishredtoblueintheheatingprocessisowingtothefactthattheFe~(2+)andTi~(4+)contentsgrowandtheintervalencechargetransferofFe~(2+)-Ti~(4+)selectivelyabsorbsUV-VISlight.
简介:Mitoxantrone,aclinicallyusefulantitumourantibioticforleukaemiaandbreastcancer,hasreceivedmoreattentions.Inthispaper,theinteractionbetweenmitoxantroneandcalfthymusDNAisinvestigatedbyRamanandfluorescencespectroscopies,andthebindingsiteofmitoxantronetocalfthymusDNAisexplored.TheresultsshowedthatmitoxantroneinteractswithcalfthymusDNAbasesbytheintercalationofanthracyclineintothebasepairplaneofadenine(A)andthymine(T),anditresultsinthedisruptionofthehydrogenbondsbetweencalfthymusDNAbases,andthusthecalfthymusDNAdouble-strandcanbedisruptedintotheB-formDNAdouble-strandsegments.
简介:Nitridatedβ-Ga_2O_3(100)substratewasinvestigatedasthesubstrateforGaNepitaxialgrowth.Theeffectsofnitridationtemperatureandsurfaceroughnessofβ-Ga_2O_3wafersontheformationofGaNwerestudied.Itwasfoundthatthemostoptimizednitridationtemperaturewas900°C,andhexagonalGaNwithpreferredorientationwasproducedonthewell-polishedwafer.Thenitridationmechanismwasalsodiscussed.
简介:Thenonlinearswitchingcharacteristicsoffusedfiberdirectionalcouplerswerestudiedexperimentally.Byusingfemtosecondlaserpulseswithpulsewidthof100fsandwavelengthofabout1550nmfromasystemofTi:sapphirelaserandopticalparametricamplifier(OPA),thenonlinearswitchingpropertiesofanullcoupleranda100%couplerweremeasured.Theexperimentalresultswerecoincidentwiththesimulationsbasedonnonlinearpropagationequationsinfiberbyusingsuper-modetheory.Nonlinearlossinfiberwasalsomeasuredtogettheinjectedpoweratthecoupler.Afterdeductingthenonlinearlossandinputefficiency,thenonlinearswitchingcriticalpeakpowersfora100%andanullfusedcouplerswerecalculatedtobe9410and9440W,respectively.ThenonlinearlossparameterPNinanexpressionofαNL=αP/PNwasobtainedtobePN=0.23W.
简介:Thefeasibilityoffenestrationoperationinmiddleearbonewithpulsedinfraredlaserisevaluated.HealthymaleNewZealandrabbitsinvivoareusedintheexperiment.Middleearmastoidboneofanimalmodeliscompletelyexposedwithconventionalmethods,andthenapulsedCO2laser(10.6μm)andanEr:YAGlaser(2.94μm)areusedtoperformthefenestrationoperation.Diamonddrillisalsousedasacontrolgroup.Thetotaloperationtimeandlightirradiationtimearerecordedandtheopeningefficiencyisassessed.Themorphologicalchangesandthermaldamagearoundtheopeningwindowonthemiddleearboneareexamined.Itisshownthatbothlasersystemsaresuitableforthefenestrationoperationinmiddleearbone,andthisno-touchtechniquehasalotofbenefitscomparedwithtraditionalmethods.Thebleedingduringoperationhasanimportanteffectonoperationtimeandthermalinjuryandneedstobecontrolledefficientlyinfurtherstudy.更多还原
简介:Amaster-slaveconfigurationusedtocontrolthenonlinearbehaviorsarisinginaverticalcavitysurfaceemittinglaser(VCSEL)withstrongexternalopticalfeedbackisestablished.Intermsofbifurcationdiagram,timeandfrequencydomain,theinfluenceofthecontinuousopticalinjectionfromthemasterVCSELonthenonlinearcharacteristicsoftheslaveisinvestigatedtheoretically.Forrelativelyweakinjection,theslavestillkeepsitsintrinsicnonlinearstate.Withincreasingtheinjectionstrength,thesenonlinearbehaviorsevolvetoperiodicfluctuation,andatlastarereplacedbythesteady-state(e.g.thecriticalinjectionparameterforsteady-stateis1.2whenexternalcavity'sreflectivityandlengthare4%and4cm,respectively).Duringthisevolutionthebifurcation-contractionphenomenaarealsoobserved.
简介:InordertoimprovetheopticalpropertiesoftheⅢ-Ⅴlaserdiodes(LDs)bymeansofH_2Splasmapassiva-tiontechnology,H_2SplasmapassivationtreatmentisperformedontheGaAs(110)surface.Theoptimumpassivationconditionsobtainedare60-Wradiofrequency(RF)powerand20-minduration.Sothelasercavitysurfacesaretreatedundertheoptimumpassivationconditions.Consequently,comparedwithun-passivatedlaserswithonlyAR/HR-coatings,thecatastrophicopticaldamage(COD)thresholdvalueofthepassivatedlasersbyH_2Splasmatreatmentisincreasedby33%,whichisalmostthesameasthatof(NH_4)_2S_xtreatment.Andthelife-testexperimenthasdemonstratedthatthispassivationmethodismorestablethan(NH_4)_2S_xsolutionwet-passivatedtreatment.
简介:为了定量研究光线光路中辐射能量的传输变化数理表达形式,实现用相对简单有效的光学内辐射传输替代复杂困难的系统全光路外辐射传输的技术过程,建立了光学系统内外辐射传递关系模型。模型结合辐射源的辐射模型和辐射能量在系统内部传输模型,利用微分光线追迹计算的方法,对携带辐射能量的光线传播路径进行分析研究。微分光线光学计算的方法对每一光学元件发射的辐射通量传输过程进行定量分析研究。光学系统的每个被分析的光学元件都被看作朗伯辐射源。而位于它后面的所有光学元件组成新的光学系统。待分析的光学元件发射的辐射通量经过后面的光学系统最终到达探测器面。据此理论分析,设计了光学系统内外辐射传输的理论模型和模型实现的算法程序。根据实验测量数据,应用于构建的模型,计算的最大相对误差为8.2%,平均相对误差为5.1%,对于红外光学系统的实际测量实验,可以满足测量的要求。
简介:Anovelno-guidelightpentype3D-coordinatemeasurementsystemwiththreesetsofpositionsensitivedevices(PSDs)torealizeintersectionconvergeinagingisintroduced.Itiscalledasthelightpentypemeasurementsystem,becausethemeasuringheadisshapedasapenwithseverallightsourcesonit.Thestructuredesign,measurementprincipleandexperimentalresultsarepresented.Thetheoreticalanalysisandexperimentalresultsprovethatthissystemhasadvancedfeaturesofsimplestructure,highautomation,andhighaccuracy,andcanbeusedinthemeasurementfieldsofmechanicalmanufacture,robot,auto,aviationandmedicineeffectively.
简介:OpticalmethodsandMTTmethodareusedtocharacterizetheantiproliferationeffectofantitumordrug9-aminoacridine(9AA)withandwithoutsilvernanoparticles.IntracellularsurfaceenhancedRamanscattering(SERS)spectraandfluorescentspectraof9AAindicatetheformof9AAadsorbedonthesurfaceofsilvernanoparticles.AlthoughbothsilvernanoparticlesandantitumordrugcaninhibitthegrowthofHelacells,silvernanoparticlescanslowdowntheantiproliferationeffectonHelacellsatlowconcentrationofantitumordrugs.Ourexperimentalresultssuggestthatsilvernanoparticlesmayserveasslow-releasedrugcarriers,whichisimportantinantitumordrugdelivery.
简介:Usingamicrowavegenerator,chlorinedilutedbyheliumwasdissociatedtochlorineatomsthatsubse-quentlyreactedwithhydrogenazidetoproducetheexcitedstatesofNCl(a1△).Meanwhile,moleculariodinewithcarriergasofheliumreactedwithatomicchlorinetoproduceatomiciodinewhichthenwaspumpedtoexcitedstateofI(2P1/2)byanenergytransferreactionfromNCl(a1△).Inthispaper,thechangesofNCl(a1△)andNCl(bi∑)emissionintensityispresentedwhenI2/HeisintroducedintothestreamofCl/Cl2/He/HN3/NCl(a1△)/NCl(b1∑).ThedependencesofatomiciodineI(2P1/2)onflowratesofgaseswerealsoinvestigated.TheoptimumparametersforI(2P1/2)productionaregiven.