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500 个结果
  • 简介:The2-C,methylenegroupof1-aroyl-1,2-dihydro-3H-naphtho[2,1-b]pyran-3-ones(2)havebeenshowedtopossessasuperiorreactivitytowardsmanyoforganicreagents.Thena-phthopyrones(2)condensedwitharomaticaldehydestogivethe2-arylidinederivatives(3).Bromin-ationof2gave1,2-dibromo(4)or5-bromo(5)derivativesdependingonthereactionconditions.Thebasecatalyzedadditionorcycloadditionofnaphthopyrones(2)to4-methoxybenzalacetophenonegavetheexpectedMichaeladduct(6)orthecyclicadducts(7-9)dependingonthetypeofcatalyticbaseandreactionconditions.Structuresoftheproductshavebeenestablishedbyelementalanalyses,IRand~1HNMRspectroscopicmethods.

  • 标签: PYRAN REACTIVITY aldehydes aromatic bromo catalyzed
  • 简介:Withthehelpofanextendedmappingapproach,anewtypeofvariableseparationexcitationwiththreearbitraryfunctionsofthe(2+1)-dimensionaldispersivelong-waterwavesystem(DLW)isderived.Basedonthederivedvariableseparationexcitation,abundantnon-propagatingsolitonssuchasdromion,ring,peakon,andcompactonetc.arerevealedbyselectingappropriatefunctionsinthispaper.

  • 标签: 映射展开逼近 局部激发 DLW系统 水波色散 非线性物理模型
  • 简介:Inthispaperwestudytheaverageσ-Kwidthandtheaverageσ-linearwidthoftheunitballofl1x(R)inl2α(R).Theexactvaluesofthesewidthsarecalculatedandanoptimalsubspacewiththeoptimallinearopera-tor(fortheσ-linearwidth)areidentified.

  • 标签: exact inequality opera subspace AVERAGE R)IN
  • 简介:Usingafurthermodifiedextendedtanh-functionmethod,richnewfamiliesoftheexactsolutionsforthe(2+1)-dimensionalBroer-Kaup(BK)system,comprisingthenon-travelingwaveandcoefficientfunctions'soliton-likesolutions,singularsoliton-likesolutions,periodicformsolutions,areobtained.

  • 标签: 双曲正切函数 修正展开法 BK系统 精确解 周期孤波
  • 简介:STUDYONTHEREARRANGEMENTREACTIONOF5-AMINO--AMINOCARBONYL-1,,ANDITSANALOGUES¥RongJianLU;HuaZhengYANG;BaoYingQIAN;HaiYanDENG(N...

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  • 简介:TwonewintercalationcompoundsFe0.90PS3(phen)0.41(1)(phenstandsfor1,10-phenanthrolineincludingapartof1,10-phenanthrolineH+)andFe0.83PS3(bipy)0.34(2)(bipystandsfor2,2’-bipyridineH+)weresynthesizedbythereactionofthelayeredFePS,with1,10-phenanthrolineor2,2’-bipyridineinthepresenceofaniliniumchloride.Theywerecharacterizedbyelementalanalyses,powderX-raydiffraction(XRD),infraredspectroscopy.Thelatticespacingoftheintercalatewasexpandedby0.90nmforFe0.90PS3(phen)0.41and0.57nmforFe0.83PS3(bipy)0.34withrespecttothepristineFePS3,indicatingthattheringplaneoftheguestsisperpendiculartothelayerofthehost.TheUV-visabsorptionspectraofthefiltrateinpreparationoftheintercalatesindicatethat1,10-phenanthrolineor2,2’-bipyridinealsoactsasacomplexingagenttoremoveintralamellarFe2+ionsintothesolutionduringintercalation.Themagneticpropertiesof1and2werestudied.

  • 标签: INTERCALATION FePS3 1 10-PHENANTHROLINE 2 2’-bipyridine
  • 简介:SYNTHESISOF3-ARYL-H,4H)ACRIDONESANDTHEIRDERIVATIVES¥RongYIN;GuangFanHAN;YuTianLI(DepartmentofMedicalLaboratory,JilinMediea...

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  • 简介:用特殊Painleve-Baecklund转变以及扩大印射的途径和线性重叠定理,我们获得的可变分离答案的新家庭(2+1)维的概括Broer-Kaup(GBK)系统。基于导出的准确答案,我们揭示局部性的刺激的一些新奇进化行为,即分裂和熔化现象在(2+1)维的GBK系统。

  • 标签: GBK系统 变量分离解 局部激发 裂变 聚变
  • 简介:Polymer-supportedRCpCpTiCl2(Cp=η^5-C5H4;RCp=η^5-RC5H4)havebeenpreparedandreducedbyi-C3H7MgBrinsitu,thenusedincatalyticisomerizationof1,5-hexadiene.Theisomerizationof1,5-hexadieneleadstoamixtureofcyclicandlinearproducts.Theratioofcyclictolinearproductdependsonthenatureofthesupporterandthesubstituentonthecyclopentadienylring.Theformercontributesthemost,forexample,silicasupportedCp2TiCl2gavecyclic-linearratioof99/1,whileforpolymer-supportedCp2TiCl2species,linearcompoundsarethemajorproductsandtheratioofcyclictolinearproductchangeswithdifferentRgroupsonthecyclopentadienylring.

  • 标签: 制备 异构化作用 聚合物-支撑烷基环戊二烯基环戊二烯基二氯化钛 1 5-己二烯
  • 简介:Ageneralmappingdeformationmethodispresentedandappliedtoa(2+1)-dimensionalBoussinesqsystem.Manynewtypesofexplicitandexacttravellingwavesolutions,whichcontainsolitarywavesolutions,periodicwavesolutions,JacobianandWeierstrassdoublyperiodicwavesolutions,andotherexactexcitationslikepolynomialsolutions,exponentialsolutions,andrationalsolutions,etc.,areobtainedbyasimplealgebraictransformationrelationbetweenthe(2+1)-dimensionalBoussinesqequationandageneralizedcubicnonlinearKlein-Gordonequation.

  • 标签: 三维Boussinesq方程 行波解 广义图分形理论 周期波解 孤波解 数学物理方法
  • 简介:WedescribetheestablishingprocessfortheBoson-FermionalgebraofOSP(1,2)startingfromthefundamentalWigneroperatorsofOSP(1,2),andstudyitsstructuréfeatureandrepresentationtheory.WealsogivetheBoson-FermionrepresentationofOSP(1,2),whichisaninfinitedimensionalandgradestarrepresentation

  • 标签: ALGEBRA operators infinite starting establishing ADJOINT
  • 简介:Thetreatmentandresourcereuseof1,2,4-acidproducingwastewaterbyself-mademacroporousadsorptionresinND,A-107wasstudiedinthispaper.Optimumadsorptionanddesorptionprocessparameterswereacquiredbysystematicallystudy.ThepolymericresinNDA-107indicatedgoodadsorption&desorptionof1,2,4-acidinthewastewater.Theremovalefficiencyof1,2,4-acid,CODerisabout78%,72%respectively.Itisevidentthatthisadsorptionprocessisanefficienttreatmentmethodfor1,2,4-acidproducingwastewater.Atthesametime,theaccumulationandresourcereuseofl,2,4-acidcanberealizedinthisprocess.

  • 标签: 资源再利用 废水处理 1 2 4-产酸废水 大孔聚合物吸附剂
  • 简介:RecentexperimentalresultsofHL-1MtokamakandprogressofHL-2Aprojectarepresented.Strongfishboneinstabilitywasobservedduringoff-axisECRH.ThisisfirstobservationofthefishboneinstabilitypurelydrivenbyenergeticelectronsproducedbyECRH.TheMBIwasfirstproposedanddemonstratedonHL-1M.RecentlynewresultsofMBIexperimentwereobtainedbyincreasingthepressureofgas.Astair-shapedensityincrementwasobtainedwithhigh-pressuremulti-pulseMBIjustlikethedensityevolutionbehaviorduringthemultipelletinjection.Itisshown

  • 标签: HL-1M HL-2A 实验数据 托卡马克装置 等离子体物理学
  • 简介:本文给出任意有限维全微分方程的判定定理与求通解的一种方法。定理的条件是充要的。判断与求通解是同步进行的,方法简单,运用方便。解决了高维全微分方程的判断与求通解的困难。

  • 标签: 全微分方程 M_ndx_n=0 判定定理 有限维 求通 变元
  • 简介:3-(2-Hydroxyphenyl)-6-(4-nitrophenyl)-7H-1,2,4-triazolo[3,4-b][1,3,4]thiadiazine,C16H11N5O3S,waspreparedbythecyclizationof3-(2-hydroxyphenyl)-4-amino-5-mercapto-1,2,4-triazolewith2-bromo-4-nitroacetophenone.Thecompoundwascharacterizedbymeansofelementalanalysis,IR,1HNMR,13CNMR,massspectrometry,andX-raydiffraction.ThecompoundcrystallizesinamonoclinicsystemwithspacegroupCc,a=2.1853(4)nm,b=2.1192(5)nm,c=1.3526(3)nm,β=95.21(2)°,V=6.238(2)nm3,Dcalcd.=1.505Mg/m3,Z=16,F(000)=2916,R1=0.0501,wR2=0.0427.Acomparisonbetweenthecrystalstructuresof1,2,4-triazolo[3,4-b][1,3,4]thiadiazineand1,2,4-triazolo[3,4-b][1,3,4]thiadiazolewasmadeinthestructuralview.Atwo-dimensionalnetworkisformedbyhydrogenbondsandπ-πstackinginteractions.

  • 标签: 晶体结构 [1 3 4]噻二嗪 制备 光谱表征 Π-Π相互作用
  • 简介:热行为,机制和在一个规划温度的模式的标题混合物的发热的第一阶段的分解反应的运动参数借助于DSC,TG-DTG和红外被调查了。反应机制被建议。在微分形式,明显的激活精力(Ea)和这反应的pre指数的因素(A)的实验运动模型功能是(1-)?1.119,211.3kj/mol和1020.2s?1分别地。混合物的热爆炸的批评温度是202.2爠慥瑣潩?㈠低??湡敧漠??????????????鈿酌顛鱎?????疞????陴?陴?T

  • 标签: DECOMPOSITION GLYCOLURIL KINETICS mechanism