简介:Tostudytheelectromagnetic(EM)backscattercharacteristicsoffreakwavesatmoderateincidenceangles,weestablishanEMbackscatteringmodelforfreakwavesin(1+1)-dimensionaldeepwater.ThenonlinearinteractionbetweenfreakwavesandBraggshortwavesisconsideredtobethebasichydrodynamicspectramodulationmechanisminthemodel.NumericalresultssuggestthattheEMbackscatteringintensitiesoffreakwavesarelessthanthosefromthebackgroundseasurfaceatmoderateincidenceangles.Thenormalisedradarcrosssections(NRCSs)fromfreakwavesarehighlypolarisationdependent,evenatlowincidenceangles,whichisdifferentfromthesituationfornormalseawaves;moreover,theNRCSoffreakwavesismorepolarisationdependentthanthebackgroundseasurface.NRCSdiscrepanciesbetweenfreakwavesandthebackgroundseasurfacewithusinghorizontaltransmittinghorizomtal(HH)polarisationarelargerthanthoseusingverticaltransmittingvertical(VV)polarisation,atmoderateincidentangles.NRCSdiscrepanciesbetweenfreakwavesandbackgroundseasurfacedecreaseswiththeincreaseofincidenceangle,inbothHHandVVpolarisationradars.Asanapplication,inthesynthetic-apertureradar(SAR)imagingoffreakwaves,wesuggestthatfreakwavesshouldhaveextremelylowbackscatterNRCSsforthefreakwavefacetwiththestrongestslope.Comparedwiththebackgroundseasurface,thefreakwavesshouldbedarkerinHHpolarisationechoimagesthaninVVechoimages,inSARimages.FreakwavescanbemoreeasilydetectedfromthebackgroundseasurfaceinHHpolarisationimagesthaninVVpolarisationimages.Thepossibilityofdetectionoffreakwavesatlowincidenceanglesismuchhigherthanathighincidenceangles.
简介:Wehavesuccessfullysynthesized1-(2′-Phenyl)cycloproply1-2,3-epoxypropan-1-ol3,whichwillbeappliedtothekineticsstudyofoxiranylcarbinylradical.
简介:SINGULARITYANDQUADRATUREREGULARITYOF(0,1,...,m-2,m)─INTERPOLATIONONTHEZEROSOF(1-x)Pn-1αβ(x)ShiYingguang(史应光)(ComputingCe...
简介:ThesplittingofpotentialenergylevelsforgroundstateX2ΠgofOx2(x=+1,1)underspin–orbitcoupling(SOC)hasbeencalculatedbyusingthespin–orbit(SO)multi-configurationquasi-degenerateperturbationtheory(SO-MCQDPT).TheirMurrell–Sorbie(M–S)potentialfunctionsaregained,andthenthespectroscopicconstantsforelectronicstates2Π1/2and2Π3/2arederivedfromtheM–Sfunction.TheverticalexcitationenergiesforOx2(x=+1,1)areν[O+12(2Π3/2→X2Π1/2)]=195.652cm1,andν[O12(2Π1/2→X2Π3/2)]=182.568cm1,respectively.Allthespectroscopicdataforelectronicstates2Π1/2and2Π3/2aregivenforthefirsttime.
简介:Treatmentof4-amino-3-(1-aryl-5-methyl-1,2,3-triazol-4-yl)-5-mercapto-1,2,4-triazoles/2-amino-5-(1-aryl-5-methyl-1,2,3-triazole-4-yl)-1,3,4-thiadiazoleswithbenzaldehyde,acetoneandω-bromoacetophenonewastestedandcompared.ThetitlecompoundsSchiffbases,amides,imidazolo[2,1-b]-1,3,4-thiadiazolesand7H-s-triazolo[3,4-b]-1,3,4-thiadiazineshavebeenconfirmedbyelementalanalyses,^1HNMR,IRandMSspectra.AllthecompoundshavealsobeenscreenedfortheirantibacterialactivitiesagainstB.subtilis,S.aureusandE.coli.
简介:在微波辐射条件下,以2-氨基-5-苯并呋喃基-1,3,4-噻二唑和N.取代三氯乙酰苯胺为原料,在固体氢氧化钠作用下,“一锅法”高产率合成了10种N-(5-苯并呋喃基-1,3,4-噻二唑-2-基)-NL芳基脲,并通过IR、^1HNMR和元素分析表征了目标产物的结构.
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简介:Abosonicconstruction(withcentralchargec=2)ofLiealgebrasW1+∞andW1+∞(glN),aswellasthedecompositionsintoirreduciblemodulesaredescribed.AndforW1+∞,whenrestrictedtoitsVirasorosubalgebraVir,abosonicconstructionandthesamedecompositionforVirareobtained.
简介:ThespectrumoftheΣ(1193)excitedstates,Σ,withisospinI=1andstrangenessS=??1isoneofthemostimportantissuesinhadronicphysics.TheΣresonancesaremostlyproducedandstudiedinK-inducedreactions.ManyΣresonancesarenowcatalogedbytheParticleDataGroup[1].However,ourknowledgeoftheseresonancesisstillverypoor.Intheenergyregionbelow2GeV,onlyafewofthemarewellestablished,suchastheΣ(1385)ofspin-parityJP=3=2+,Σ(1670)ofJp=3=2??andΣ(1775)ofJp=5=2??.Theothersarenotwellestablishedandsomeofthemareevenoflargeuncertaintiesontheirexistence.Thus,thestudyoftheΣresonancewiththeavailableexperimentaldataisnecessary.
简介:Thepolymerizationof1-octeneinitiatedbymethylalumoxane(MAO)-activatedNi(Ⅱ)-based-α-diiminecomplexes[(2,6-i-Pr)_2C_6H_3-DAB(An)]NiBr_2wasinvestigated.Usingthiscatalyst,poly(1-octene)swithmolecularweightbetween100×10~3and400×10~3andpolydispersity(M_w/M_n)between1.3and1.5weresynthesizedsuccessfullybyvaryingreactiontimeatroomtemperature.Thepoly(1-octene)swereamorphouspolymersandcouldbewellsolubleintetrahydrofuran(THF).Afterfractionalprecipitation,poly(1-octene)swithnarrowmolecularweightdistributions(M_w/M_n≤1.12)wereobtained.Theirweight-averagemolecularweightsweremeasuredbygelpermeationchromatography(GPC)inconjunctionwithonlinemodelBI-MwAmultianglelaserlightscattering(MALLS),andtheirintrinsicviscositiesweremeasuredbyMaron'ssingle-pointmethod.ThekandavaluesinMark-Houwinkequation[η]=KM~αinTHFat40℃were0.089mL/gand0.61respectively.