简介:采用铜(Ⅱ)盐和3,5-二氯水杨醛缩丝氨酸以及4,4′-联吡啶在乙醇水溶液中合成了具有二维层状的配位聚合物.通过元素分析、红外光谱对该配位聚合物进行了表征,并利用X射线单晶衍射仪对其结构进行了鉴定.晶体结构表明,该标题配合物属三斜方晶系,空间群C2/c,晶胞参数为a=2.711(3)nm,b=2.711(3)nm,c=4.977(5)nm;α=90.00°,β=90.00°,γ=120.00°,V=3.1678nm^3,Z=18,Dc=1.173g·cm^-3,F(000)=11448,μ=0.807mm-1,R1=0.0788,wR2=0.1872.
简介:Twotransmissioncurvedcrystalspectrometersaredesignedtomeasurethehardx-rayemissioninthelaserfusionexperimentofComptonradiographyofimplosiontargetonShenGuang-IIIlaserfacilityinChina.Cylindricallycurvedα-quartz(10–11)crystalswithcurvatureradiiof150and300mmareusedtocoverspectralrangesof10–56and17–100keV,respectively.Thedistancebetweenthecrystalandthex-raysourcecanbechangedoverabroaddistancefrom200to1500mm.Theopticaldesign,includingtheintegralreflectivityofthecurvedcrystal,thesensitivity,andthespectralresolutionofthespectrometers,isdiscussed.WealsoprovidemechanicdesigndetailsandexperimentalresultsusingaMoanodex-raysource.High-qualityspectrawereobtained.Weconfirmedthatthespectralresolutioncanbeimprovedbyincreasingtheworkingdistance,whichisthedistancebetweentherecordingmediumandtheRowlandcircle.
简介:Thecopolymerizationsofethylenewith10-undecen-1-olhavebeeninvestigatedusingvanadiumprecatalysts,bis(imino)pyrrolylvanadium(III)complexes1-3,2,5-C4H2N(CH=NR)2VCl2(THF)2[R=C6H5(1),2,6-iPr2C6H3(2),C6F5(3)],andtheiminopyrrolylandβ-diketiminateonesforcomparison.Thepolarmonomerwaspretreatedbydiethylaluminiumchloride(presentalsoasthecocatalyst)beforethecopolymerization.ThemonomerreactivityratioswereevaluatedusingtheFineman-Rossmethod.Theligandstructureconsiderablyinfluencedthecatalyticactivityandtolerancetowardsthepolarmonomer,thepolarmonomerincorporationandthemolecularweightsoftheresultantcopolymers.Thebis(imino)pyrrolylvanadiumcomplexesexhibitedpromisingcatalyticperformanceforthecopolymerization,andahighcatalyticactivityupto3.84kg/mmolv·hwithahighcomonomerincorporationof14.0mol%wasachievedbycomplex3undermildconditions.
简介:摘要随着我国经济的不断发展,我国网络自动化技术的发展也在逐步加快。在实际电网运营的过程中,广大自动化设备也会发挥着自身的额作用。目前,10kV的配电自动化设备在运行的过程中存在诸多问题,其分布的区域、网络节点和其他内容都会存在诸多困难。本文全面分析10kV配电自动化设备与一体化运维模式的运作方式。
简介:TheaveragepoweroffiberlasershasbeenscaleddeeplyintothekWregimeinthepastyears.However,stimulatedRamanscattering(SRS)isstillamajorfactorlimitingfurtherpowerscaling.Here,wehavedemonstratedforthefirsttime,tothebestofourknowledge,thesuppressionofSRSinahalf10kWtandempumpingfiberamplifierusingchirpedandtiltedfiberBragggratings(CTFBGs).Withspeciallyself-designedandmanufacturedCTFBGsinsertedbetweentheseedlaserandtheamplifierstage,amaximumSRSsuppressionratioof>15dBinspectrumisobservedwithnoreductioninlaserefficiency.WithoneCTFBG,theeffectiveoutputpowerisimprovedto3.9kWwithabeamqualityM2factorof~1.7from<3.5kWwithanM2factorof>2;withtwoCTFBGs,theeffectivelaserpowerreaches4.2kWwithanincreasingratioof20%andanM2factorof~1.8,andfurtherpowerimprovementislimitedbythepowerandperformanceofthe1018nmpumpsources.ThisworkprovidesaneffectiveSRSsuppressionmethodforhigh-powerall-fiberlasers,whichisusefulforfurtherpowerscalingofthesesystems.
简介:ThecompressionbehaviourofPd39Ni10Cu30P21bulkmetallicglassisivestigatedatroomtemperatureupto23.5GPausinginsituhighpressureenergydispersivex-raydiffractionwithasynchrotronradiationsource.Pressureinducedstrucuralrelaxationofthebulkmetallicglassisexhibitedwithinthepressurerange.Itisfoundthatbelowabout5GPa,theexistenceofexcessfreevolumecontributestorapidstructuralrelaxation,whichgivesrisetorapidvolumeticchange.Underhigherpressure,furtherrelaxationresultsinstructuralstiffness.
简介:摘要近年来,随着国民经济的持续快速发展,以及城市化进程的不断推进。国家电网建设取得了举世瞩目的成就。由于10kV配电网架空线路整体性能良好,各方面的工作也能取得良好的效果,成为我国许多城市国内主要的电力线覆盖率的一半以上。在我国,由于供电用户众多,供电中断对居民的社会生产和日常生活产生了很大的影响。因此,10kV配电网架空线路的维护都是现场工作。10kV配电网架空线路的现场维护虽然不会影响正常供电工作,但其运行难度大,容易受到外部因素的影响,也对运维人员的安全构成很大威胁。本文对10kV配电网架空线路维护工作中存在的一些问题进行了深入分析,并提出了相应的解决方案。为了帮助我国10kV配电网架空线路的现场维护工作体系得到完善。