Study on the stannous halides promoted addition of 1,1,1-trichloro-2,2,2-trifluoroethane to aldehydes and the chemical transformation thereof

(整期优先)网络出版时间:1994-02-12
/ 1
Promotedbystannoussalts,1,1,1-trichloro-2,2,2-trifluoroethanereactsreadilywithaliphatic,aromatic,andα,β-unsaturatedaldehydesgivingthecorrespondingalcoholsbearingaCF3CCl2-moietyingoodtoexcellentyields.ThesealcoholsarefartheroxidizedbyJonesreagentgivingthecorrespondingketonesinhighyields.