Combined Use of Co-immobilized Lysozyme and Lipase and Chemical Inhibitors in Circulating Cooling Water System

(整期优先)网络出版时间:2018-04-14
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Inordertoimprovethestabilityandcorrosioninhibitionperformanceofbioenzyme,lipaseandlsozymewereco-immobilizedonthemesoporousmolecularsieveMCM-41bytheadsorptionmethod.Thentheimmobilizedenzymeswerecombinedwithaminotrimethylenephosphonicacidandpolyasparticacidtopreventcorrosioncausedbycirculatingcoolingwater.Theweight-lossmethodandelectrochemicaltechniqueswereusedtoevaluatetheperformanceofcompositeinhibitors.Theco-immobilizedlysozymeandlipaseachievedgoodinhibitioneffects.Aftertheywerecombinedwithaminotrimethylenephosphonicacidandpolyasparticacid,thecorrosioninhibitionpropertieswerefurtherimproved.Theinhibitionefficiencywaspromotedto94.4%.Duringthecorrosioninhibitionprocess,theimmobilizedenzymesplayedanimportantrole.Theadditionofcorrosioninhibitorcouldinhibittheanodicdissolutionandcathodichydrogenevolutionprocessofcarbonsteelatthesametime.Theadsorptionofco-immobilizedlysozymeandlipasecompositeinhibitoronthesteelsurfacewasajointactioninvolvingphysicaladsorptionandchemicaladsorption.