简介:合成了氰根桥联配合物Co[Fe(CN)5NO].5H2O,使用元素分析、热重分析、红外光谱、XRD对配合物进行了表征。红外光谱显示金属离子通过氰根桥联即FeII-CN-NiII传递磁相互作用,是属于桥式氰根配体的CN伸缩振动,而粉末XRD衍射图表明此化合物为面心立方体结构(FCC),空间群为Fm3m(225),晶格常数a=10.2856。通过对该配合物的直流变温磁化率和交流磁化率测定表明金属离子通过氰根传递弱反铁磁作用,根据Curie-Weiss定律,拟合数据获得居里常数C=1.55cm3·K/mol,顺磁居里温度θ=-1.87K。
简介:Thestructuralproperties,mechanicalbehavior,andelectronicstructureofthenewlydevelopeddiamondlikeBC5(d-BC5)wasinvestigatedusingdensityfunctionaltheory(DFT)calculations.Theresultsindicatethatd-BC5hasgreatbulkmodulusof393GPa,largeshearmodulusof398GPa,andhighhardnessof62Pa,andthussupportthefactthatd-BC5isanultra-incompressibleandsuperhardmaterial.Remarkably,thesuperhardd-BC5exhibitsmetallicfeatures.Furthermore,thetrendthatthemechanicalbehaviorfallswiththeincreaseofboroncontentwasrevealed.Thecombinationofhugestiffness,highhardness,andgoodmetallicitymakesseriesofdiamondlikeBCx(d-BCx)validforwiderapplicationsincomparisonwithpurediamond.
简介:DarkMatterParticleExplorer(DAMPE)isapowerfulspacetelescopeforhighenergycosmicraysdetectionsuchas-ray,electronandheavyions.ThemainmotivationofDAMPEistofindtheevidenceofdarkmatterexistence,andthesatelliteisscheduledforlaunchingbeforetheendof2015.ThePlasticScintillatorDetector(PSD),whichisoneofthekeycomponentsoftheDAMPEsystem,hastwomajorfunctionalities:distinguishphotonsfromchargedparticlesbyanti-coincidenceandmeasurethechargeofheavyions.ThePSDisdesignedandfabricatedbytheinstituteofmodernphysics,CAS.Itconsistsof82plasticscintillatorstrips,eachofwhichisreadoutbyPMTatbothends,andadouble-dynodereadoutschemeforPMTisutilizedinordertocoverthelargedynamicrange(fromHtoCa).
简介:Asimplemethodisappliedtocalculatingtheisotopeshifts(ISs)on5S1/2→4D3/2,5/2transitionsof87,88Sr+.FirstwehavecalculatedtheISsoflowertransitionsonaseriesofalkali-likesystemssuchasB2+,Ca+andBa+,whichareinagreementwithotherworks.ThentheISson5S1/2→4D3/2,5/2transitionsof87,88Sr+,whichareusefultostudytheSr+opticalfrequencystandard,areevaluated.
简介:Vanadiumalloys(V-Cr-Tiseries)areimportantcandidatematerialsforblanketcomponentsoffusionreactorsduetotheirlowactivationandhighstrengthatelevatedtemperatures.Low-temperatureirradiationembrittlementdeterminestheoperationtemperaturelimitofVanadiumalloysfortheapplicationtostructuralmaterialsoffusionreactorsirradiationresponseofvanadiumalloysneedstobeclarifiedfortheirapplication.Inthepresentstudy,specimensoftwoalloys(V-4Cr-4TiandV-5Cr-5Ti)wereirradiatedwithenergeticHeionsandheavyionstounderstandhardeningofthealloysduetoheliumaccumulationandcascadedamageproduction.