学科分类
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65 个结果
  • 简介:UsingthedensityfunctionaltheoryandthenonequilibriumGreen’sfunctionmethod,westudiedthefinite-biasquantumtransportinaCr/graphene/Crmagnetotunneljunction(MTJ)constructedbyasinglegraphenelayersandwichedbetweentwosemi-infiniteCr(111)electrodes.Wefoundthatthetunnelingmagnetoresistance(TMR)ratiointhisMTJreached108%,whichisclosetothatofaperfectspinfilter.Underanexternalpositivebias,wefoundthattheTMRratioremainedconstantat65%,incontrasttoMgO-basedMTJs,theTMRratiosofwhichdecreasewithincreasingbias.TheseresultsindicatethattheCr/graphene/CrMTJisapromisingcandidateforspintronicsapplications.

  • 标签: 隧道磁阻 石墨 磁电阻 自旋电子学 格林函数方法
  • 简介:ConstructingareasonablereactionkineticmodelforCr-containingwasteincinerationisofhighsignificancetostudytheeffectofvariousfactors,suchastemperature,Cl,onitshexavalentchromiumcompounds.Inthispaper,aprimaryCr/H/Air/ClreactionkineticmodelisbuiltandstudiedbyGaussian03codewithquantumchemistrytheory.Numericalresultsshowthattherearetwooverallreactionsinthemodel,eachofthetwooverallreactionsconsistsoftheirrespectivetwoelementaryreactions.Sothetwooverallreactionsshouldbeomittedfromthemodel.Instead,thefourelementaryreactionsshouldbeaddedintheCr/H/Air/Clreactionkineticmodel.Theactivationenergiesofthefourelementaryreactionsarealsocalculated.

  • 标签: 动力学模型 高氯 空气 小时 反应活化能 CR
  • 简介:Tounderstandtheelectronicandmagneticproperties,wehavestudiedCr-dopedzinc-blendeAINsystemindetailbyapplyingafirst-principleplanewavepseudopotentialmethodbasedonthedensityfunctionaltheorywithinthelocalspindensityapproximation.Theanalysesofthebandstructures,densityofstates,exchangeinteractions,andmagneticmomentsshowthatAl_(1-x)Cr_xNalloysmayexhibitahalf-metallicferromagnetismcharacter,thatCrinthediluteddopinglimitformsnear-midgapdeeplevels,andthatthetotalmagnetizationofthecellis3μ_BperCratom,whichdoesnotchangewithGrconcentration.Moreover,wehavesucceededinpredictingthatAl_(1-x)Cr_xNalloysinx=0.0625hasaveryhighCurietemperature,andfindthatferromagneticexchangeinteractionbetweenmagneticdopantsisshort-ranged.

  • 标签: 氮化铝 铬掺杂 密度泛函理论 电子结构 磁性
  • 简介:我们报导自我开始的femtosecondCr:forsterite激光由1064-nmYb抽了的高度有效、高的力量做了纤维激光。五啁啾镜子被用来补偿intra洞组延期分散,并且锁模式被一个半导体开始可饱和的吸收器镜子(SESAM)。在7.9W的泵力量下面,有760mW的平均力量的稳定的femtosecond激光脉搏被获得,产出12.3%的泵力量斜坡效率。测量脉搏持续时间并且光谱带宽(FWHM)是46fs和45nm;重复率是82MHz。[从作者抽象]

  • 标签: 铬:镁橄榄石激光器 光纤激光器 光泵 激光技术
  • 简介:Vanadiumalloys(V-Cr-Tiseries)areimportantcandidatematerialsforblanketcomponentsoffusionreactorsduetotheirlowactivationandhighstrengthatelevatedtemperatures.Low-temperatureirradiationembrittlementdeterminestheoperationtemperaturelimitofVanadiumalloysfortheapplicationtostructuralmaterialsoffusionreactorsirradiationresponseofvanadiumalloysneedstobeclarifiedfortheirapplication.Inthepresentstudy,specimensoftwoalloys(V-4Cr-4TiandV-5Cr-5Ti)wereirradiatedwithenergeticHeionsandheavyionstounderstandhardeningofthealloysduetoheliumaccumulationandcascadedamageproduction.

  • 标签:
  • 简介:Co(II)-salenwasencapsulatedinMIL-100(Cr)metalorganicframeworkby"shipinabottle"tosynthesizeanewelectrocatalyst,Cosalen@MIL-100(Cr).ThematerialwascharacterizedbyXRD,FT-IR,UV-VisandN2-adsorption.TheCosalen@MIL-100(Cr)modifiedglassycarbonelectrodeexhibitsawell-definedreductionpeakatthepotentialof–0.21Vtowardtheoxygenreductionreaction(ORR)bycyclicvoltammetry(CV)inpH=6.84phosphatebuffer.Almost400mVpositiveshiftofpotentialatCosalen@MIL-100(Cr)modifiedelectrodeforORRcomparedwiththatatbareglassycarbon,indicatesthatCosalen@MIL-100(Cr)possessesexcellentelectrocatalyticactivity.ThetransferrednumberofelectronsforORRwasdeterminedbychronocoulometry.TheresultsuggeststhattheintroductionofCo(II)-salencomplexintoMOFincreasestheelectrocatalyticactivityviaafour-electronreductionpathway.Furthermore,thiselectrocatalystexhibitsgoodstabilityandreproducibility.

  • 标签: 电催化还原 封装 电催化活性 玻碳电极 氧气 金属有机骨架
  • 简介:WeconstructaclassofintegrablegeneralizationofTodamechanicswithlong-rangeinteractions.ThesesystemsareassociatedwiththeloopalgebrasL(Cr)andL(Dr)inthesensethattheirLaxmatricescanberealizedintermsofthec=0representationsoftheaffineLiealgebrasCr(1)andDr(1)andtheinteractionspatterninvolvedbearsthetypicalcharactersofthecorrespondingrootsystems.WepresenttheequationsofmotionandtheHamiltonianstructure.Thesegeneralizedsystemscanbeidentifiedunambiguouslybyspecifyingtheunderlyingloopalgebratogetherwithanorderedpairofintegers(n,m).Itturnsoutthatdifferentsystemsassociatedwiththesameunderlyingloopalgebrabutwithdifferentpairsofintegers(n1,m1)and(n2,m2)withn2<n1andm2<m1canberelatedbyanestedHamiltonianreductionprocedure.Forallnontrivialgeneralizations,theextracoordinatesbesidesthestandardTodavariablesarePoissonnon-commute,andwheneithernorm≥3,thePoissonstructurefortheextracoordinatevariablesbecomessomeLiealgebra(i.e.theextravariablesappearlinearlyontheright-handsideofthePoissonbrackets).Inthequantumcase,suchgeneralizationswillbecomesystemswithnoncommutativevariableswithoutspoilingtheintegrability.

  • 标签: 广义Toda力学 多体系统 泊松括号 非线性偏微分方程
  • 简介:Wereportedabifunctionalmaterial,Cr-salenimplantedconjugatedmicroporouspolymer(Cr-CMP),whichisabletocaptureexcellentCO2amountsandhasaremarkablecatalyticactivitytowardsthecycloadditionreactionofCO2toepoxidesformingcycliccarbonatesatmildconditionswithoutadditionalsolvents.ThisheterogeneousCr-CMPcatalysthasasuperiorcatalyticactivitytoitsrelatedhomogeneouscatalystandcanbereusedmorethantentimeswithoutasignificantdecreaseincatalyticactivity.

  • 标签: carbon dioxide EPOXIDES cyclic CARBONATE polymer
  • 简介:实现了X型腔全固态端面泵浦Cr:LiSAF激光器的高效率输出和宽谱调谐。斜效率最高为33.3%,在吸收泵浦功率为650mW时,输出功率最高达160mW。在谐振腔内插入双折射滤光片(BF)调谐,调谐范围达787.952nm。测量了激光器的光谱、光束质量等,分析了激光器效率和调谐范围的限制因素。研究表明,X型腔全固态端面泵浦的Cr:LiSAF激光器可以实现高效的近红外宽谱调谐输出。

  • 标签: 固体激光器 近红外 调谐激光器 Cr:LiSAF激光
  • 简介:Therearemoreandmorecountriestoakeanefforttothestudiesofvanadiumalloyforfusionapplication.NIFSinJapanhasrecentlydevelopedan80kgheatV4Cr4Tialloy(NIFS-heat2)aftertheproductionofa500kgscaleV4Cr4TiinU.S.severalyearsago.PropertyevaluationofthealloyhasbeenputintoaninternationalcollaborationprogramunderthecoordinationofIEA(InternationalEnergyAgency).SWIPhasjoinedthecollabrationonthehydrogenembrittlementresistanceevaluationofthealloyt.

  • 标签: 钒合金 氢脆变 阻抗 NIFS
  • 简介:钨基合金由于具有高密度、高强度及高冲击韧性等优异性能而得到广泛应用。它在军事工业中主要用作穿甲弹、动能弹和导弹弹头。我单位对高密度钨基合金材料的研究已有多年历史,重点研究了添加Co,Mn,Cr等元素对钨基合金性能的影响,并研制出一系列密度和力学性能的钨基合金。

  • 标签: 钨基合金 机械性能 真空热处理
  • 简介:OnaccountoftheexcellentmechanicalpropertiesofCrNfilmsuchasgoodwearandcorrosionresistance,andoxidizationatamuchhighertemperature,CrNfilmhasbeendemonstratedasoneofthebestcoatingsforenlargingthebearingatpresent.However,steelworkinglifespanatpresentt.However,withthemoreincreasinglyaggressiveoftheworkingenvironmentofmechanicalcomponents,especiallyforbearingsteel,newcoatingtechnologieswithamorebetterpropertiesofthetreatedpartssuchaswearandcorrosionresistancearerequired.

  • 标签: 复合涂层 离子束辅助沉积 轴承钢 耐磨性实验
  • 简介:采用环境氢脆技术及现代材料微观分析技术,研究了Fe-35Ni-15Cr实验合金在室温至900℃的力学性能及热充氢后在室温及750℃的力学性能,分析了温度对材料微观组织的影响,为优化其化学成分、热处理工艺等提供技术依据。

  • 标签: 力学性能 微观组织 合金 温度 现代材料 热处理工艺
  • 简介:我们从intra洞表明红轻femtosecond激光脉搏的产生加倍频率的Cr4+:forsterite激光。75mW的平均产量力量被在激光洞插入500-m-thickBBO晶体与55fs的脉搏宽度在647nm的中央波长获得。第二泛音脉搏的光谱的带宽是9nm,相应于0.355的一个时间带宽产品。

  • 标签: 镁橄榄石激光器 飞秒脉冲 腔内倍频 红光 时间带宽积 飞秒激光脉冲