简介:Howtocontrolmeltcompositionisthekeyforgettinghighqualityalloymelt.Thepapermadethefollowingefforts:(1)TheactivitycoefficientsinTi-15-3melthavebeencalculated.(2)Takingadvantageoftheactivitycoefficients,theevaporationlossesofcomponentsinTi-15-3meltduringISMprocesshavebeenstudied.Thecalculatedresultsshowthatthereisacriticalvacuumdegree(about1.33Pa)duringmeltingprocess.
简介:LowcarbonsteelswithBandPadditionswereremeltedbyelectromagneticlevitationandsolidifiedinavacuumdroptube.Thedropletvolumesweresettobe2mm×2mm×2mm(TM)and5mm×5mm×5mm(FM),respectively.Themicrostructureofrapidlysolidifiedsteeldroplets(cooledinsiliconoil)withPandbothBandPadditionwasobserved.ThemicrostructuresofB-bearingdropletsamplesweremoreuniformthanthoseofB-freeones,forbothTMandFMsamples.Thedistributionof℃andPalongthediameterofeachsamplewasdetected.Thewell-distributionof℃andPwasdetectedinB-bearingdropletsamples.SoitcouldbededucedthatBwasalsowelldistributedinthesteels.ItwasBatomsthatpromotedthewell-distributionof℃andP,whichfurtherimprovedtheuniformityofmicrostructureundertheconditionofrapidsolidification.Themicro-hardnessofBbearingsampleswashigherthanthatofB-freesamples,andthehardeningmechanismwasdiscussedindetail.
简介:AmodelhasbeendevelopedtodescribethemicrostructureevolutionintheatomizeddropletsofCu-Fealloyduringcoolingthroughthemetastablemiscibilitygap.CalculationshavebeenperformedforCu85Fe15alloytoinvestigatetheprocessofliquid-liquidphasetransformation.Thenumericalresultsindicatethattheminorityphasedropletsarenucleatedinatemperatureregionaroundthepeakofthesupersaturation.TheaverageradiusoftheFe-richdropletsdecreasesandthenumberdensityoftheminorityphasedropletsincreaseswithdecreasingtheatomizeddropletsize.Thesimulatedresultswerecomparedwiththeexperimentalones.Thekineticprocessoftheliquid-liquidphasetransformationwasdiscussedindetail.
简介:Microstructureandsubsequentphasetransformationsonheatingofthemelt-spunNd85Al15alloyhavebeenstudiedbyX-raydiffraction,transmissionelectronmicroscopyanddifferentialscanningcalorimetry.Themelt-spunNd85Al15alloyshowstwo-stagetransformationprocessesasfollows:amorphous+72nmsupersaturatedbcc-Nd(Al)solidsolution→7nmomega-likephase→AlNd3+hexagonalNd.Theactivationenergiesforthefirstandsecondtransformationwerefoundtobe100kJ/moland188kJ/mol,respectively.Theformationmechanismofnanoscaleomega-likephaseisdiscussed.
简介:PositronannihilationbehaviorshavebeenstudiedinthesinglephaseNd2Fe14BmagnetandthenanocompositeNd2Fe14B/α-Femagnet,preparedbymeltspinning.Theresultsshowedthatthenumberofvacancy-clusteratgrainboundariesincreaseswithincreasingannealingtemperatureforthebothtypesofmagnets.Theincreaseofthiskindofdefectcanimprovethecoercivityof
简介:MoleculardynamicssimulationusingauniversalforcefieldhasbeenemployedtodeterminethediffusioncoefficientsofO2andNa2SO4vaporintoB2O3andSiCfrom700Kto1273K,respectively.Einsteindiffusionwasobservedina250~300pssimulation.ThediffusioncoefficientfortheO2rangefromabout9.279×10-9cm2/sforB2O3to2.275×10-10cm2/sforSiCataloadingof32moleculespersimulationbox,thatfortheNa2SO4vaporrangefromabout9.888×10-7cm2/sforB2O3to1.837×10-10cm2/sforSiCataloadingof8moleculespersimulationbox.EnvironmentpropertiesofC/SiCcompositewillbeincreasedviatheB2O3preventingthediffusionofO2andNa2SO4vaporintothepyrolyticinterphaseandcarbonfibers.
简介:Anas-castmagnesiumalloywithhighAlcontentMg15Alwassubjectedtoequal-channelangularpressing(ECAP)throughadiewithanangleofφ=90?at553KfollowingrouteBc.Itisfoundthatthenetworkβ-Mg17Al12phasesintheas-castMg15Alalloyarebrokenintosmallblocksanddisperseduniformlywithincreasingnumbersofpressingpasses.Moreover,manynano-sizedMg17Al12particlesprecipitateintheultra-fineα-Mgmatrix.Thegrainsareobviouslyrefined.However,thegrainstructureisinhomogeneousindifferentareasofthealloy.Theaveragesizeoftheprimaryphaseα-Mgisreducedtoabout1μmwhilegrainsofaround0.1-0.2μmareobtainedinsometwo-phaseareas.WithadditionalECAPpasses(upto8),coarseningofthegrainsoccursbydynamicrecovery.RoomtemperaturetensiletestsshowthatthemechanicalpropertiesofMg15Alalloysaremarkedlyimprovedafter4ECAPpasses.Theultimatetensilestrengthandelongationtofailureincreasefrom150MPato269.3MPaandfrom0.05%to7.4%,respectively.Comparedwiththatafter4passes,theelongationtofailureofthealloyincreasesbutthestrengthofthealloyslightlydecreasesafter8ECAPpasses.FracturemorphologyoftheECAP-processedalloyexhibitsdimple-likefracturecharacteristicswhiletheas-castalloyshowsquasi-cleavagefractures.
简介:有alloying原子X=C,B,N,O和空缺的镁和它的合金的概括叠的差错(GSF)精力和表面精力用第一原则的方法被调查了。叠的差错精力上的alloying原子和空缺的占优势的减少效果在slip飞机附近在第一层从他们的位置被结果,这被发现。叠的差错精力是将近与纯镁一样当alloying原子和空缺被放在时第二,第三,第4,第5和第6层。O强烈减少Mg的GSF精力,这被显示出。alloying原子C,B和N增加表面精力,但是O和空缺减少Mg的表面精力。Mg和Mg合金的韧性被使用在表面精力和不稳定的叠差错精力之间的比率基于瑞斯标准讨论了。
简介:ExperimentswerecarriedouttostudytheinfluenceofsurfaceconditiononexpulsionduringthespotweldingofAZ31BMgalloy.AgeneralelectricalcontactresistancetheoryforconductiveroughsurfacesandtherelationbetweenmaximumtemperatureTminthecontactandvoltage-dropVacrossinterfaceoftwosurfaceswereemployedtounderstandthereasonofexpulsioninMgalloyspotwelding.Themainreasonofexpulsionisthatthehighelectricalcontactresistanceinducedbylargeroughnessofthesurfaceandoxidefilmcoveredonthesurfaceleadstolocalmeltingofmetalintheinterfaceoftwosurfaces,andliquidmetalofthelocalareaejectedfromthespecimenunderelectrodeforceformsexpulsion.