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简介:Anovelintermediatefluidvaporization(IFV)technologyforLNGre-gasificationprocesswithspiral-woundheatexchangingtubesisproposed.ThenewIFVprojectcombinestheadvantageofrunningtheshellandtubeheatexchangersathighpressurewiththeadvantageofcompactspaceofheatexchangers.Thermalanalysisonthetwoprocessesofforcedconvectionandvaporizationtypeheattransferinthespiralwoundtubesandvaporcondensation/re-boilingtypeofheattransferviaintermediatefluidinshellsideshowsthefeasibilityofthispromisingtechnology.
简介:Immisciblefluidflowisfrequentlyfoundinresourcerecoveryorsoilremediation.Theflowpatternintheporousmediaisaffectedbythewettabilityofporesurface.Inthisstudy,quartzsubstratesandmicrofluidicchipsaretreatedbysilicananoparticles(SNP)andtriethoxy(octyl)silane(TES)tofabricatethewater-wetandoil-wetsurfaces.Thewettabilityofthetreated-surfaceismeasuredintermofcontactangleforseveralcombinationsofsurroundingfluidandaliquiddroplet.Theeffectofthewettabilityonthefluidflowpatternisexploredbyinjectingoilandwateralternatelyintothesurface-treatedmicrofluidicchips.TheresultsrevealthattheSNP-coatedquartzsubstrateshowsstrongwater-wetpropertyandtheTEScoatingmakeswater-repellent/oil-wetsurfaces.Inaddition,itisfoundthatthemaximumandminimumoilandwatersaturationduringalternateinjectionofoilandwaterdependsonthesurfacewettabilityofthemicrofluidicchips.Thecharacteristicsofthepore-scalefluidflowpatternarealsodescribed.
简介:Anewsilicasolbinderwasobtainedbymixingtheacid-modifiedaluminiumsulfateandwaterglass.TheeffectofSiO2concentrationinsodiumsilicate,pHvalueandpolymerizationwasinvestigated.Thenewsilicasolbinder,whichpossessedabundantporevolumeandsuitableacidamount,wasanidealcomponentforpreparingcrackingcatalyst.Asaresult,thecorrespondingcatalystcomprisingthenewbindershowedexcellentperformance.Comparedwiththereferencesample,theliquefiedpetroleumgas(LPG)andpropyleneyieldobtainedoverthiscatalystincreasedby3.49and1.20percentagepoints,respectively.TheperfectporestructureandsuitableLewisacidamountofnewsilicasolwerethepossiblereasonleadingtoitsoutstandingperformance.
简介:Anovelporousbinderwasobtainedfromacid-treatedkaolin.Thisnewbinderpossessedabundantmeso/macropores,goodhydrothermalstabilityandheavymetalresistance.Thepreparedcatalystusingnewbinderfeaturedlowattritionindexandlargeporevolume.ThecatalystswerecontaminatedwithNi,V,andtestedinafixed-fluidizedbedreactorunit.Incomparisonwiththereferencesample,theoilconversionachievedbytheabove-mentionedcatalystincreasedby3.50percentagepoints,andheavyoilyielddecreasedby2.86percentagepoints,whilethetotalliquidyieldandlightoilyieldincreasedby2.82percentagepointsand0.79percentagepoints,respectively.Theperfectporestructure,goodhydrothermalstabilityandheavymetalresistantperformanceofnewbinderwerethepossiblecausesleadingtoitsoutstandingperformance.
简介:Thebasic-nitrogenaromaticcompoundsinfeedstocksandliquidproductsfromthemicro-reactorandsolublecomponentsofcokeobtainedduringfluidcatalyticcracking(FCC)processwereanalyzedbythemicro-electrosprayionization(ESI)9.4TFouriertransformioncyclotronresonancemassspectrometry(FT-ICRMS)withanaveragemassresolvingpowerof300000atamassrangeof100-1200.Theanalyticalresultsrevealedthatthecokergasoil(CGO)containedahigherabundanceofbasic-nitrogenaromaticcompoundswiththetypeof-5Nto-9Ncomparedwiththoseindeasphaltedoil(DAO)andmixedFCCfeedstock.Aftercatalyticcracking,theabundanceoflowlycondensedbasic-nitrogenaromaticcompoundswasmuchlessthanthoseofhighlycondensedaromaticsintheliquidproducts,withthecarbonnumbermainlyrangingfrom6to25andtheaveragecarbonnumberoftheside-chainsequatingto1-5.Onthecontrary,withrespecttothesolublecomponentsofcoke,theabundanceoflowlycondensedbasic-nitrogenaromaticcompoundswasmorethanthoseofhighlycondensedaromatics,andthecarbonnumberrangedfrom12to30,whichwasmuchsmallerthanthatofthemixedFCCfeedstockbutslightlylargerthanthatofthecrackedliquidproducts.TheseresultshaveprovidedsomefundamentalinformationonFCCprocess.