简介:Intermediate Mass Fragment Emission in Ar+Ag CollisionsIntermediateMassFragmentEmissioninAr+AgCollisions¥WuEnjiu;ZhengJiwen;W...
简介:TheannealingbehaviorofAgnanoparticlesinsilicawithandwithoutdefectswasinvestigatedinthisstudy.SilicasampleswithandwithoutArionpre-irradiationwereimplantedwithAgionsandthenannealedattemperaturefrom300to850℃.UV-VISspectroscopyandTEMwereusedtocharacterizetheopticalabsorbancepropertyandsizedistributionofAgnanoparticles,respectively.OpticalabsorbanceresultsshowthattheabsorbanceintensityofSPR(SurfacePlasmonResonance,SPR)peakfromAgnanoparticlesinthesamplewithpre-irradiationisstrongerthaninthesamplewithoutpre-irradiation,whichindicatesthatthedefectsproducedbypre-irradiationpromptthenucleationofAgnanoparticles.Duringannealing,theSPRpeakshiftstoshortwavelengthdirection,asshowninFig.1.
简介:ThispaperinvestigatesthesolidificationbehaviouroftheAg—Cueutecticalloymeltundercooledupto100K.ItisrevealedthatlamellareutecticsgrowinadendriticformintheAg-Cueutecticmeltwithundercoolingequaltoorgreaterthan76K.Asundercoolingincreases,theremeltedfractionoftheprimaryeutecticsduringrecalescencerises.Thesevereremeltingandthesubsequentripeningoftheprimaryeutecticdendritesleadtotheformationofanomalouseutectics.
简介:Mercaptopropyltrimethoxysilane(MPTS)bearingmercaptogroupswasusedtoformself-assemblymonolayers(SAMs)onglasssubstratesbysolutionextraction.SEM,XRDandrubbingtestanalysisillustratedthattheAgfilmontheSAMs-modifiedglasswasmoredurablethanthatonthecommonly-modifiedglassandthatthecrystallinityofAgfilmontheSAMs-modifiedglasswasidenticalwiththoseoftheAgfilmonthecommonly-modifiedglassandpureAg.
简介:Afacilemethodforthesynthesisofsilver-silica(Ag-SiO2)Janusparticleswithfunctionalitiessuitablefortextileapplicationsisreported.SilicananoparticlespreparedbytheStobermethodwerefunctionalizedwithepoxy,amine,andthiolgroups,whichwereconfirmedbyFouriertransforminfraredanalysis.ThefunctionalizedsilicananoparticleswereusedtoproducePickeringemulsions,andtheexposedsurfacewasusedfortheattachmentofsilvernanoparticles(AgNPs)viathelow-temperaturechemicalreductionmethod.ThemorphologyandstructureoftheAg-SiO2Janusparticleswerecharacterizedbyscanningelectronmicroscopy,scanningtransmissionelectronmicroscopy,high-resolutiontransmissionelectronmicroscopy,energy-dispersiveX-rayanalysis,andUV-visspectroscopy.Becauseoftheirspecificfunctionalities,theseAg-SiO2Janusparticlesareproposedforapplicationsontextilesubstrates,astheycanovercomeseveraldrawbacksofdirectapplicationofAgNPsontextiles,suchasleaching,agglomeration,andinstabilityduringstorage.
简介:Inordertodeepentheunderstandingoftherelationshipbetweenfundamentalproperties(including:microstructureandcomposition)andphotocatalyticperformance,fourbismuthatecompounds,including:LiBiO3,NaBiO3,KBiO3,andAgBiO3,areregardedasresearchexamplesinthepresentwork,becausetheyhaveparticularcrystalstructuresandsimilarcompositions.Usingdensityfunctionaltheorycalculations,theirstructural,electronic,andopticalpropertiesareinvestigatedandcomparedsystematically.Firstofall,thecalculatedresultsofcrystalstructuresandopticalpropertiesareinagreementwithavailablepublishedexperimentaldata.Basedonthecalculatedresults,itisfoundthatthetunneledorlayeredmicro-structuralpropertiesleadtothestrongerinteractionbetweenbismuthandoxygen,andtheweakerinteractionbetweenalkaline-earthmetaland[BiO6]octahedron,resultinginthefeatureofmulti-bandgapsinthecasesofLiBiO3,NaBiO3,andKBiO3.ThisconclusionissupportedbythecaseofAgBiO3,inwhichthefeatureofmulti-bandgapsdisappears,duetothestrongerinteractionbetweenthenoblemetaland[BiO6]octahedron.Thesepropertieshavesignificantadvantagesinthephotocatalyticperformance:absorbinglowenergyphotons,rapidlytransferringenergycarriers.Furthermore,thefeaturesofelectronicstructuresofbismuthatecompoundsarewellreflectedbytheabsorptionspectra,whichcouldbeconfirmedbyexperimentalmeasurementsinpractice.Combinedwiththecalculatedresults,itcouldbeconsideredthatthecrystalstructuresandcompositionsofthephotocatalystdeterminetheelectronicstructuresandopticalproperties,andsubsequentlydeterminethecorrespondingphotocatalyticperformance.Thus,anovelBi-basedphotocatalystdrivenbyvisible-lightcouldbedesignedbyutilizingspecificcompositionstoformfavorableelectronicstructuresorspecificmicro-structurestoformabeneficialchannelforenergycarriers.
简介:这篇文章介绍一条灵巧的途径给聚苯乙烯/银(PS/Ag)的准备不对称的混合粒子。在这个方法,polystyrene/polyglycidylmethacrylate(PS/PGMA)Janus粒子经由dichloromethane(DCM)的蒸发从PS/PGMA/DCM-in水乳剂微滴触发的内部阶段分离被综合。然后,Janus粒子是aminated并且顺序获得PS/PGMA-NH2和PS/PGMA-COOH粒子的carboxylated。在由与amine/carboxyl协调的functionalizedPS/PGMA粒子的PGMA半球的表面上自我装配的Ag+。有Ag的7.29wt%的PS/Ag不对称的混合粒子被Ag+的减小获得。扫描电子显微镜学,精力散的X光检查光谱学和传播电子显微镜学结果证实Ag在聚合物粒子的表面上是不均匀地分布式的。
简介:COandformaldehyde(HCHO)oxidationreactionswereinvestigatedovermesoporousAg/Co3O4catalystspreparedbyone-pot(OP)andimpregnation(IM)methods.Itwasfoundthattheone-potmethodwassuperiortotheimpregnationmethodforsynthesizingAg/Co3O4catalystswithhighactivityforbothreactions.ItwasalsofoundthatthecatalyticbehaviorofmesoporousCo3O4andAg/Co3O4catalystsforthebothreactionswasdifferent.AndtheadditionofsilveronmesoporousCo3O4didnotalwaysenhancethecatalyticactivityoffinalcatalystforCOoxidationatroomtemperature(20C),butcouldsignificantlyimprovethecatalyticactivityoffinalcatalystforHCHOoxidationatlowtemperature(90C).Thehighsurfacearea,uniformporestructureandtheprettygooddispersiondegreeofthesilverparticleshouldberesponsiblefortheexcellentlow-temperatureCOoxidationactivity.However,forHCHOoxidation,theadditionofsilverplayedanimportantroleintheactivityenhancement.AndthesilverparticlesizeandthereducibilityofCo3O4shouldbeindispensableforthehighactivityofHCHOoxidationatlowtemperature.
简介:研制出以固态AgCl-KCl-聚乙烯醇-琼脂混合物为导电凝胶的全固态Ag/AgCl参比电极(AllState-ReferencrElectrode,简写为ASRE)。将ASRE与pH玻璃电极组成电极组,直接电位法测定pH2.00-12.00磷酸盐缓冲溶液的pH值,与以饱和甘汞电极为参比电极(SCE)的测定结果比较,相对误差为-0.8%-+0.8%;与氯离子选择电极组合测定1.00×10^(-1)-1.00×10^(-4)mol/LNaCl的电池电动势ΔE,-lgc(Cl-)与ΔE呈良好的线性关系,斜率为-49.3,与以双盐桥SCE为参比电极时的斜率(-49.9)基本一致,表明ASRE能够代替双盐桥SCE运用于Cl-浓度的测定。在10-80℃范围内,以KNO_3溶液(1.000mol/L)为模型,测定ASRE相对于SCE的ΔE,ΔE与T呈线性关系,温度系数为0.123mV/℃。ASRE有望代替传统参比电极,应用于离线或在线电化学测定中。