简介:采用2步水热法合成了LaPO4∶Eu3+-Fe3O4复合材料.在LaPO4∶Eu3+-Fe3O4复合材料中,LaPO4∶Eu3+为单斜晶相,呈纳米棒状,纳米棒的直径和长度分别为20-100nm和0.2-1μm;Fe3O4为正交晶相、呈20-30nm的颗粒状,Fe3O4粒子紧紧附着在LaPO4∶Eu3+纳米棒的表面;样品的磁性和发光性质研究表明所合成的LaPO4∶Eu3+—Fe3O4复合材料既具有发光性质又具有磁性.
简介:InthispaperweusedMOF-5andCu3(BTC)2toseparateCO2/CH4andCH4/N2mixturesunderdynamicconditions.Bothmaterialsweresynthesizedandpelletized,thusallowingforameaningfulcharacterizationinviewofprocessscale-up.ThematerialswerecharacterizedbyX-raydiffraction(XRD)andscanningelectronmicroscopy(SEM).Byperformingbreakthroughexperiments,wefoundthatCu3(BTC)2separatedCO2/CH4slightlybetterthanMOF-5.BecausethecrystalstructureofCu3(BTC)2includesunsaturatedaccessiblemetalsitesformedviadehydration,itpredominantlyinteractedwithCO2moleculesandmoreeasilycapturedthem.Conversely,MOF-5withasuitableporesizeseparatedCH4/N2moreefficientlyinourbreakthroughtest.
简介:Inthisreport,wepresentasimulatedresultontheion-massindependenceoftheguidedtransmission,whichisinagreementwiththepreviousexperimentalresults[1].Inordertosearchtheinuenceoftheionmassonguidedtransmission,variousspeciesofionsusedasprojectilesinsimulations.Fig.1showsthetransmissionfractionsforNe7+,Ar7+,Kr7+,andXe7+ions.Thesedatawereacquiredfortiltangleof2inenergyof7keV.Itisseenthatallofionfractionsgraduallyrisesafteratimedelay,andnallyreachstable.
简介:Morelocalizedenergydepositionisabletobeproducedinantiproton-nucleuscollisionsincomparisonwithheavy-ioncollisionsduetoannihilationreactions.Searchingforthecoldquark-gluonplasma(QGP)withantiprotonbeamshasbeenconsideredasahottopicbothinexperimentsandinthereticalcalculationsoverthepastseveraldecades.Strangenessproductionandhypernucleusformationinantiproton-inducednuclearreactionsareimportanceinexploringthehyperon(antihyperon)-nucleon(HN)potentialandtheantinucleon-nucleoninteraction,whichhavebeenhottopicsintheforthcomingexperimentsatPANDAinGermany.
简介:MoleculardynamicssimulationsareperformedtostudythegrowthmechanismofCH4-CO2mixedhydrateinxCO2=75%,xCO2=50%,andxCO2=25%systemsatT=250K,255Kand260K,respectively.OursimulationresultsshowthatthegrowthrateofCH4-CO2mixedhydrateincreasesastheCO2concentrationintheinitialsolutionphaseincreasesandthetemperaturedecreases.Viahydrateformation,thecompositionofCO2inhydratephaseishigherthanthatininitialsolutionphaseandtheencagingcapacityofCO2inhydratesincreaseswiththedecreaseintemperature.ByanalysisofthecageoccupancyratioofCH4moleculesandCO2moleculesinlargecagestosmallcages,wefindthatCO2moleculesarepreferablyencagedintothelargecagesofthehydratecrystalascomparedwithCH4molecules.Interestingly,CH4moleculesandCO2moleculesfrequentlyreplacewitheachotherinsomeparticularcagesitesadjacenttohydrate/solutioninterfaceduringthecrystalgrowthprocess.Thesetwospeciesofguestmoleculeseventuallyacttostabilizethenewlyformedhydrates,withCO2moleculesoccupyinglargecagesandCH4moleculesoccupyingsmallcagesinhydrate.
简介:Highenergyprotonbeamhasthelongpenetrationlengthinsolidmatteranditcouldproducetheradiographsandindicatethetomographyandmaterialpropertiesinsideofthespecimen.Consideringtheexpensivecoststoconstructahighenergyprotonaccelerator,theothercandidateofhighenergyelectronbeambecomesmoreacceptable[1??3].Duetothehighspatialandtemperalresolutionofhighenergyelectronbeam.Itisapowertooltodiagnosetheinnerstructurechangeduringthehighenergydensitymatterproductionandtheinertialconfinementfusionprocess.Inordertostudythedensityresolutionofthehighenergyelectronbeamradiography,astep-targetwasdesignedandproduced.ThestructureandthetargetpicturesareshowninFig.1andtheSitargetswithdifferentslot-widthwereproducedbyusingthemicroetchtechnics.
简介:TemperatureisoneofthekeythermodynamicparametersofHEDmatter.Asapopulartechnique,thepyrometerofnarrow-bandlterstogetherwithphotodiodes(namelymulti-channelpyrometer)hasbeenapplied.However,thepyrometercanonlymeasureone-positiontemperatureinsingleshot[1;2].Actually,itisveryimportanttoknowtemperatureevolutionofmultiplepositionsinsingleshot,especiallyforthetargetinducedbyheavyionbeam,wherealargevolumeofHEDmattercanbegenerated.Consequently,afastnew-typepyrometerhasbeendesigned.
简介:Thiscontributionreportsethylenepolymerizationbehavioroftitaniumcomplexesincorporatingbis(phenoxyimine)ligands.Sixphenoxy-imineTi(IV)complexes{6-R1-2-[CH=N(2,6-difluoro-3,5-diR2-4-R3Ph)]C6H3O}2TiCl2(1:R1=H,R2=H,R3=H;2:R1=H,R2=H,R3=4-vinylphenyl;3:R1=CH3,R2=H,R3=H;4:R1=CH3,R2=H,R3=4-vinylphenyl;5:R1=CH3,R2=F,R3=H;6:R1=CH3,R2=F,R3=4-vinylphenyl)havebeensynthesizedandevaluatedforethylenepolymerizationusingdriedMAO(simplifiedasDMAO)ascocatalyst.AnobviouscatalyticheterogeneityofCat2(Complex2/DMAO)towardsethylenepolymerizationwasobserved,whichwasillustratedbydecreasedactivity,multimodalmolecularweightdistributionandpartiallyimprovedparticlemorphologycomparingwithCat1.Moreover,Cat3exhibits'living'characteristicsintheprocessundercertainconditions(25°C,lessthan20min).Otherwise,themoderatetohighethylenepolymerizationactivityofca.105-106gPE/(molTi·h)andhighmolecularweight(Mw=105-106)ofpolyethylenecanbeobtainedbychangingtheskeletonstructureofthesecomplexes.
简介:Grapheneistwodimensionalmaterialswhichismadeofhoneycombedcarbonatoms.Itattractsextensiveinterestsforitswonderfulcharacteristicsthatmakethegrapheneapotentialcandidateinfieldsofmicroelectronicsproduction,moleculedetection,desalinationandDNAsequencing.Highlychargedion(HCI)hashugepotentialenergyforpeelingoffelectrons.Wheninteractingwithsolidsurface,theHCIdistortedthesolidlatticeviapotentialdepositionandthenthenanostructureswereformedonthesolidsurface.TheHCIwasexpectedasatoolforsurfacemodification.Inthiswork,HOPGandgraphemewereirradiatedwithXeq+andArq+ions.ThetypicalRamanspectraofgrapheneandHOPGirradiatedwithhighlychargedionswereshowninFig.1.TheDpeakappearedat1335cm??1onthespectraofgrapheneirradiatedwithhighlychargedions.TheintensityofDpeakincreasedwithfluence.TheratioofintensityofDpeaktothatofGpeakvariedwithfluenceinFig.2.Theratioroselinearlywiththesquarerootoffluencewhenfluencewaslow.Theratiosaturatedwhentheirradiationfluencewashigh.Thecriticalfluencedependedonthechargestateofion.Thehigherchargestateitwas,thelowercriticalfluenceitwouldbe.
简介:Duetolowactivationcharacteristics,desirablehigh-temperaturestrength,goodresistancetoradiationdamageandusablefabricationproperties,vanadium(V)alloysareattractivecandidatestructuralmaterialsforfusionreactors[1].Irradiationinducedhardening/embrittlementatlowtemperatureisamajorproblemforthematerialsapplicationinfusionreactor[2].Inthisstudy,H/Heionswithvariousenergieswereusedtoirradiateapurevanadium(V)andaValloy(V-4Ti)toobtainadamageplateaufromsamplesurfacetothedepthof1.5m,asshowninFig.1[3].Thedetailsofirradiationparameters(energies,fluences)forHandHeionsareshowninTable1.NanoindentationwasperformedtoinvestigatethehardeningbehaviorofV-4TialloyandpureVunderirradiation.
简介:Thenanomaterialsoftenexhibitveryinterestingelectrical,optical,magnetic,andchemicalproperties,whichcannotbeachievedbytheirbulkcounterparts[1-7].Thedevelopmentofuniformnanometersizedparticleshasbeenintensivelypursuedbecauseoftheirtechnologicalandfundamentalscientificimportance[8-15].Itissignificantthatnanostructuredmaterialscanbecontrollablyassembledintotherequiredgeometryontosubstrates,becomingthebasisofthenextgenerationofcomponentsanddevices[16-31].Thedevelopmentofnewmethodsandstrategiesfororganizingthenanoparticlebasicbuildingblocksintothedesiredstructuresisrequired.Superlatticesmadefromthesebuildingblocksgiveustheopportunitytostudynotonlythepropertiesoftheindividualbuildingblocks,butalsocollectiveeffects.Thesuperparamagneticironoxidenanocrystals(NCs)havebeenusedinthefieldsofbio-medicine,ferrofluids,refrigerationsystem,catalysis,particularlyinmagneticresonanceimaging,tissueengineering,anddrugdeliveryapplications[32-42].
简介:Graphitic碳氮化物(g-C3有向在可见轻照耀下面的4-nitrophenol的降级的高photocatalytic活动的N4)被蚀刻的HCl准备由氨中立化列在后面。准备样品的结构,形态学,表面区域,和photocatalytic性质被学习。在处理以后,g-C3N4从几测微计减少了到几百纳米,和g-C3N4从11.5 增加了;m2/g到115 ;m2/g。同时,g-C3N4显著地在可见的光下面向4-nitrophenol的降级在处理以后被改进照耀。小粒子g-C3N4是5.7次体积g-C3为水处理和环境补习为未来应用使它成为有希望的可见轻光催化剂的N4,。
简介:Highlychargedions(HCIs)carryingamountofpotentialenergywillproducesomenewphysicalphenomenabecausethepotentialenergywillbedepositedintoaverysmallvolumewithinaveryshorttime.WewouldapplythecalorimetricmethodtostudytheenergydepositionofHCIs[1;2].Hereinweintroducethenewsetupforcalorimetricmeasurementforthepotentialenergydepositionofhighlychargedionsat320kVHighlyChargedIonsPhysicsExperimentalPlatform.Thesetupwasconstructedby3parts:theDewar,theelectricaltemperaturecontrollerandthemainpart.ThediamondtargetwasconnectedtotheLN2cooledheatsinkby4copperwiresandaPlatinumtemperaturesensorwasgluedtotherearsideofthetarget.AsshowninFig.1.