简介：Mixedalcoholisofgreatpromiseasoctaneimproverinautomotivefuel,andhopefultoreplacetheMTBEtoreducetheenvironmentalpollution,Inthisfield,alkali-promtedmolybdenum-basedcatalystshavebeengivenspecialinterestbecauseoftheirexcellentsulfur-toleranceforsynthesisofmixedalcoholfromCO+H2,Itwasreportedthatthecoblatisafavorablepromoterforenhancingalcoholproduction,especiallyforimprovingtheselectivityforC2+alcohol[1-3],moreover,stronginteractionbetweenConandMoisinfavorofmixedalcoholsynthesis[4].Recently,weprparedakindofK-Co-Moultrafineparticlesbysol-gelmethodanditshowsmuchsmallerparticlesizebuthigheractivtyandselectivitytowardalcoholformationthantheonepreparedbyconventionalmethod[5],TheaimofthepresentworkistoresearchthemicostructuresoftheMoandCospeciesintheK-Co-Mosamplespreparedbydifferentmethod.
简介：Thetitlecomplex[NH_3CH_2CH(NH_2)CH_3]_2[M(Ⅵ)O_2(OC_6H_4O)_2](M=Mo_(0.6)W_(0.4))wassynthesizedviaasimplesolution-phasechemicalroute.ThedeterminationofsinglecrystalX-raydiffractionrevealedthatthetitlecompoundiscrystallizedinamonoclinicsystemwithP2(1)/nspacegroup,a=1.0913(10)nm,b=1.0442(10)nm,c=1.8842(19)nm,α=90°,β=96.530(17)°,γ=90°,Z=4,andV=2.133(4)nm3.Themononuclearanionicunit[M(Ⅵ)O2(OC6H4O)2]2-displayschiralpseudo-octahedral[MO_6]coordinationgeometryandislinkedbychiralcationsviahydrogenbondandπ…πstackinginteraction.Thetransmissionelectronmicroscopyimagesshowthatthetitlecomplexiscomprisedofnano-particleswithdiametersrangingfrom20to50nm.TheNMRstudyshowsthe1Hdownfieldchemicalshiftsof[NH_3CHaHbCH(NH_2)CH_3]+cationsinthetitlecomplexwhenitismixedwithadenosine-triphosphate(ATP),andthechemicalshiftdifferencebetweenHaandHbisincreasedgreatly,andmostofthecatecholateligandsdissociatefromthecentralmetalatoms.TheDNAcleavageactivityexperimentrevealsthatDNAcleavagepromotedbythetitlecomplexislowerthanthatbyNa_2MoO_4whichpossessesantitumorpro-perty,buthigherthanthatbyNa_2WO_4.
简介：Aneffectivedispersion-strengtheningphaseinAl-8Fe-2Mo-2Zr-2Nd-0.7Ti-1.6SialloywasidentifiedtobeanagedprecipitatephasewithpossiblechemicalstoichiometryofAl20（Ti,Mo）2Ndandfcccrystalstructurewithao=1.455nm.ThestructurewasdeterminedtobeFm3mspacegroup.
简介：以环己酮、乙二醇为原料,自制的锑铁复合固体超强酸S2O8^2-/Sb2O3/Fe2O3作催化剂,合成了环己酮乙二醇缩酮。通过分析环己酮与乙二醇的摩尔比、催化剂的量、反应时间和带水剂的用量对环己酮乙二醇缩酮的产率的单因素影响,选出合成环己酮乙二醇缩酮的单因素最优方案。同时,以环己酮与乙二醇的摩尔比、催化剂的量、带水剂的用量和反应时间为因素,设计了L9（34）正交表进行实验,得出的正交试验最佳方案为A2B1C2D2,即环己酮与乙二醇的摩尔比为1.0：1.7,催化剂的量为1.0g,带水剂用量为8mL,反应时间为1.5h。在该方案下,环己酮乙二醇缩酮的产率可以达到83.69%。
简介：Inthepresentpaper,novelsidewallmaterialsforaluminumreductioncellwerepreparedinairusingmagnesiaandmagnetiteasstartingmaterials.ThesinteringbehaviorsofthespecimenswereinvestigatedbymeansofX-raydiffraction(XRD)andscanningelectronmicroscope(SEM).AndcorrosiontestsinaNa_3AlF_6-AlF_3-K_3AlF_6bathwereconductedtoevaluatetheelectrolytecorrosionresistance.TheresultsshowthattheFe_3O_4phaseistransformedintoFe_2O_3athightemperatures,whichinturnreactswiththeMgOaddedtoformMgFe_2O_4spinel.AndwithincreasingtheMgOcontentfrom0to30mass%,densificationofthespecimensdecreasesmainlyduetolargervolumeexpansionresultingfromformationofmoreMgFe_2O_4.ThecorrosiontestsshowthatcorrosionlayersareproducedinalltheMgOaddedspecimens.However,forspecimenscontainingMgFe_2O_4phaseonly,Mg(Al,Fe)_2O_4compositespinellayersarealsogenerated,whichremarkablyimprovethecorrosionresistanceofthespecimens.
简介：Lid-drivenmixedconvectionhasbeengivenimmenseimportanceduetoitswiderangeofapplications.AT-shapedcavityisintroducedandpertinentparameterscontrollingmixedconvectionphenomenonareanalyzedinthispaper.Water-Al2O3nanofluidisconsideredinsidethecavitytoaugmentheattransferrate.Galerkinweightedresidualmethodoffiniteelementanalysisisappliedforthenumericalsimulations.Numericalsolutionisobtainedfordifferentsolidvolumefractionsofnanofluid(?=0-0.15),Grashofnumbers(Gr=0.1?5000)andReynoldsnumbers(Re=0.31?1000)inlaminarflowregime.Specialattentionisgivenontheanalysisofflowatthepuremixedconvectionregime.ItisfoundthatGrashof,ReynoldsandRichardsonnumbersalongwithsolidvolumefractionofnanofluidhavesignificanteffectonheattransfercharacteristicsinsidethecavity.ResultsarepresentedusingstreamlineandisothermcontoursalongwithrelatedvariationofaverageNusseltnumbersoftheheatedwallandaveragefluidtemperatureinsidethecavity.
简介：采用固相法制备La2O3与Sb2O3掺杂的钛酸锶钡陶瓷，研究其介电性能及相变特性。通过X射线衍射法分析体系微观结构并利用扫描电镜观察其表面微观形貌。（La,Sb）共掺杂的钛酸锶钡陶瓷具有典型的钙钛矿结构，且随着Sb2O3掺杂量的增多其平均粒径显著减小。La3＋离子以及Sb3＋离子均占据钙钛矿晶格的A位。La2O3与Sb2O3添加量的改变显著影响钛酸锶钡基陶瓷的介电常数以及介电损耗。La2O3改性的钛酸锶钡陶瓷其四方-立方相变为二级相变，且居里温度随着La2O3掺杂量的增多向低温方向移动。（La,Sb）共掺杂的钛酸锶钡陶瓷则体现为弥散相变，随着Sb2O3含量的增大而偏离居里－外斯定律越显著。由于Sb3＋离子对晶格原位离子的取代使得（La,Sb）共掺杂的钛酸锶钡陶瓷的介电常数最大值下的温度亦随着Sb2O3含量的增大而降低。
简介：ThecapacitytocaptureCO2wasdeterminedinseveralstoichiometriccompositionsintheLi2O–Bi2O3system.Thecompounds（Li7BiO6,Li5BiO5,Li3BiO4andLiBiO2phases）weresynthesizedviasolid-statereactionandcharacterizedbyX-raydiffraction,scanningelectronmicroscopyandN2adsorptiontechniques.Thesampleswereheat-treatedattemperaturesfrom40to750°CundertheCO2atmospheretoevaluatethecarbonateformation,whichisindicativeofthecapacityofCO2capture.Moreover,Li7BiO6showsanexcellentCO2capturecapacityof7.1mmol/g,whichisconsiderablyhigherthanthoseofotherpreviouslyreportedceramics.Li7BiO6isabletoreactwithCO2from240°Ctoapproximately660°CshowingahighkineticreactionevenatCO2partialpressurevaluesaslowas0.05.
简介：TiO2@ZrO2@Y2O3:有coremultishell结构的Eu3+合成粒子通过layer-by-layer(LBL)的联合被综合自己组装方法和一个solgel过程。获得的样品与扫描电子被描绘显微镜学(SEM)，传播电子显微镜学(TEM)，X光检查光电子光谱学(XPS)，X光检查衍射(XRD)，和荧光spectrophotometry。结果证明合成粒子有coremultishell结构，球形的形态学，和狭窄的尺寸分布。TiO2核心上的ZrO2层的存在能有效地阻止在TiO2核心和Y2O3壳之间的反应；为在在TiO2@ZrO2@Y2O3的TiO2核心和Y2O3壳之间的反应的温度:Eucoremultishell黄磷能被300提高
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![Crystal Structure, Nano-particle Morphology and Interaction with ATP of [ NH<b style='color:red'>3</b> CH<b style='color:red'>2</b> CH（ NH<b style='color:red'>2</b> ） CH<b style='color:red'>3</b> ]<b style='color:red'>2</b> [ M（ Ⅵ ） <b style='color:red'>O</b><b style='color:red'>2</b> （ OC6 H4 <b style='color:red'>O</b>）<b style='color:red'>2</b> ] （M = <b style='color:red'>Mo</b>0. 6 W0. 4 ） and Its Activity to Promote DNA Cleavage](/image/thesis2 "Crystal Structure, Nano-particle Morphology and Interaction with ATP of [ NH<b style='color:red'>3</b> CH<b style='color:red'>2</b> CH（ NH<b style='color:red'>2</b> ） CH<b style='color:red'>3</b> ]<b style='color:red'>2</b> [ M（ Ⅵ ） <b style='color:red'>O</b><b style='color:red'>2</b> （ OC6 H4 <b style='color:red'>O</b>）<b style='color:red'>2</b> ] （M = <b style='color:red'>Mo</b>0. 6 W0. 4 ） and Its Activity to Promote DNA Cleavage")
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![<b style='color:red'>K</b>8[ZnMg（H<b style='color:red'>2</b><b style='color:red'>O</b>）W11<b style='color:red'>O</b>39]·15H<b style='color:red'>2</b><b style='color:red'>O</b>的合成、表征及化学热扩渗](/image/thesis10 "<b style='color:red'>K</b>8[ZnMg（H<b style='color:red'>2</b><b style='color:red'>O</b>）W11<b style='color:red'>O</b>39]·15H<b style='color:red'>2</b><b style='color:red'>O</b>的合成、表征及化学热扩渗")
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