简介:Thecarbon-13spin-spinrelaxationtimesoffluorine-containingionomersaremeasuredandmotionalcorrelationtimesτ_oandτ_darecalculatedbyusingVJGMmodel.Theresultsshowthatthemotionsofpolymermainchaininionomersbecomemoredifficultwithincreasingofionizationdegreeandcontentsoffunctionalgroup,anddependonthefinestructuresandstabilityofionicmicrodomains.
简介:Dithia-monoaza18-Crown-6anditsimmobilizationproduct,silica-bound1,7-dithia-4-aza-10,13,16-trioxa-cyclooctadecaneviaaspacerofthreecarbonatoms,anditsplatinumcomplexhavebeensynthesized.Itisfoundthattheplatinumcomplexisanefficienthydrosilylationcatalystforolefins.TheXPSdataoftheplatinumcomplexarereported.