简介:Thelimestone-gypsumfluegasdesulfurization(FGD)processhasbecomethemostwidespreadprocessintheworldforsulfurremoval.Theswirl-et-absorbingwetlimestone-gypsumsinteringFGDtechnologywasdevelopedforsinteringfluegasdesulfurization,andthisprocessproducesvolumesofwastewaterwithvariouscontaminantsthatrequirestreatmentbeforedisposalorreuse.Inthisstudy,thewastewaterqualityfromthreedifferentsinteringFGDsystemsatBaosteelGroupwasinvestigatedandcomparedwithwastewaterfrompowerplantFGD.AtreatmentprocesswasproposedwhichissuitableforsinteringFGDwastewater.Aftertreatmentwithaneutralization,coagulationandsedimentationprocess,heavymetalsinthesinteringFGDwastewaterwerereducedtoalevelmeetingtherelevantemissionstandards,butthepHandammoniaconcentrationweretoohigh,andafurthertreatmentprocesswasneeded.DuetocertainsimilaritiesandcomplementaritiesbetweensinteringFGDwastewaterandcokingwastewater,itisentirelyfeasibletomixthepretreatedsinteringFGDwastewaterintoabiologicalcokingwastewatertreatmentsystem.ThisstudyindicatesthatitisentirelyfeasibletomixpretreatedsinteringFGDwastewaterintothebiologicaltreatmentsystemsusedforcokingwastewaterfromtheironandsteelindustries.
简介:Thesurfacetreatmenttechnologycanimprovethecorrosionresistanceofsteelsheetsandincreasethevalueofsteelapplication.ThesurfacetreatedsteelsheetsinBaosteelincludezincgalvanizedsteelsheets,singalvanizedsteelsheets,chromiumgalvanizedsteelsheets,andcolourcoatingsteelsheetswiththeapplicationintheareafromconstructiontoautomobiles,appliance,package,etc.Thedevelopment,applicationandmanufacturingtechniqueoftheseproductshavebecomethecorecompetitionpowerofBaosteel.ThearticlereviewsthedevelopmentsofsurfacetreatedsteelsheetsandsurfacetreatmenttechnologiesinBaosteelin10years,especiallyhotdipgalvanizedhighstrengthsteelproductsusedinvehicles.ThearticlealsolooksforwardintofurtherdevelopmentsofsurfacetreatmentsteelproductsandtechnologiesinBaosteel,whichwillfocuson:①thenewproductsofhotdipgalvanizedadvancedhighstrengthsteels;②moreenvironmentalfriendlyproductsorfunctionalcoatingproducts;③thedevelopmentofsurfacetreatmenttechnologiestomeettherequirementofhighersurfacequalityinthemarcket;④newtypeofsurfacetreatmentandcoatingtechnologies.
简介:Thisstudysummarizessomeseriousdisharmoniousproblemsthatubiquitouslyexistinthecastingresiduerecyclingofsteelplants,suchaslargelandoccupation,lowoperationalefficiency,hiddenhazards,hugeresourceandenergyconsumption,seriousenvironmentalpollutionandsoon.Itanalyzesthenecessityoftheon-lineinnovationandrecyclingbasedonthepresentsituationofBaosteel.ItstatestheinnovationofthenewgridtechnologyandtheachievementsofitsintegratedapplicationatBaosteel.ItalsosummarizesandelaboratessomegreentechnologyfeaturesofthetreatmentandtheutilizationoftheBaosteelcastingresidueandthenewgridtechnology,suchassafety,energy-savingandenvironmentalprotection.Inaddition,itlaysouttheprospectsforthedevelopmentandapplicationofthetechnology.
简介:ThisstudyresearchestheeffectsoftherefiningtreatmentonthemicrostructureandthemechanicalpropertiesofH13mandrelsteelandcomparestheseeffectswiththoseoftheconventionaltreatment.Theresultsindicatethatbothcarbideparticlesandgrainswererefined,carbideparticleswereuniformlydistributedbytherefiningtreatment,andtherefore,thestrengthandtoughnessofH13mandrelsteelwereimproved.Rapidcoolingafterthesolutiontreatmentmayinhibitintra-granularprecipitationofcarbideparticles,whichisfavorabletoenhancingtoughness.Consequently,high-performanceH13mandrelsteelcanbeproducedbyproperrefiningtreatment.
简介:Theeffectofannealingtreatmentonthemicrostructuresandmechanicalpropertiesofcold-sprayedNicoatingwasinvestigatedbyconductingmicro-hardnessandtensiletestsandusinganormalopticalmicroscope(OM),ascanningelectronmicroscope(SEM),atransmissionelectronmicroscope(TEM)andanelectronprobeX-raymicroanalyzer(EPMA).Theresultsshowthatfollowingtheincreaseoftheannealingtemperature,themicro-hardnessofcold-sprayedNicoatingdecreasesandtheelongationafterfractureincreases,whilethetensilestrengthincreasesbeforedecreasing.Thetensiledeformationandfracturebehaviorchangefromatypicalbrittlefracturetoahybridbrittleandductilefracture,thentoatypicalductilefailure.Itisfoundthatwhenannealedatanelevatedtemperature(e.g.900℃),thegrainstendtogrowabnormallywiththeoxidesspheroidizingandthedefectsagglomeratingattheinterfaces,causingthetensilestrengthreductionofthecold-sprayednickelcoating.Itisalsopointedoutthatthetensilestrengthofthecold-sprayedNicoatingcanbesignificantlyimprovedbytheappropriateannealingprocedures,buttheelongationafterfracturecannotbeclearlyincreasedbecauseitisdifficulttoeliminatethemaindefectsinthecoatingbythefollowingheattreatments.
简介:Surfacenanocrystallization(SNC)hasprovedtobeaneffectiveapproachtoimprovetheoverallpropertiesofbulkmetallicmaterials.Recently,anewsurfacenanocrystallizationtechnique,i.e.,surfacemechanicalgrindingtreatment(SMGT),wasdeveloped.Inthiswork,agradientnano-microstructurewasachievedinthesurfacelayeroftheAISI52100steelbyusingSMGT.Weobtainedaminimumgrainsizeofabout7nminthetopsurfacelayer.Thetotalthicknessofthedeformedlayerisover200micrometer.Meanwhilethesurfaceroughnessisratherlow.Ferritegrainsweredeformedtodifferentextentsvaryingwithdepthfromthetopsurface.Gradientgrainsizeswereformedfromtopsurfacetodeepmatrixwhichofferedagreatopportunitytostudytherefinementprocessoftheferritegrains.Itisfoundthatdislocationactivitiesplayadominantroleintheprocess.Attheinitiatestage,dislocationsaccumulatedandinteractedtoformdensedislocationwallsandcells.Increasingstrainandstrainrateinducedmoredislocationwallsincells,formingfinercells.Thisprocedurecontinueduntilnanograinsformedatthetopmostsurface.Theexistenceofcementiteparticlesinferritematrixgreatlyfacilitatestheferriterefinementprocess.Boundariesbetweenferritesandcementitesofferedmanydislocationsourceswhichacceleratethepropagationofdislocations.Dislocationwallswereblockedbycementiteswhichcertainlyleadtofinerdislocationcells.Theexistenceofcementitesmakesiteasiertogeneratefreshdislocationwallsinsub-microngrains.Astraingradientwasformedfromacementiteparticletosurroundingferritegrains.Thisstraingradientgivesrisetomoregeometricnecessarydislocations.Asferritegrainsizedecreasedlessthanthatofcementiteparticles,fragmentationoccurredincementites.Hardsecondphasewasusuallyconsideredasbrittle.Inthiswork,evidencesofdeformation(tracesofdislocationactivities)incementitesweredistinct.Sincethestressconcentrationinthephaseboundary(espec
简介:Themorphologyandtheevolutionofδ-ferriteexistinginB410Dslabs,hot-rolledplates,annealedplatesandquenchedplateswerestudiedthroughmetallographicobservation.Resultsshowthatδ-ferriteformsduringthesolidificationprocessandthatiteasilygrowsandincreasesinquantityduringhightemperatureannealing.Band-shapedδ-ferriteinhotrolledplatesisdifficulttobeeliminatedbyconventionalheattreatmentandhardtorecrystallize.
简介:Basedonthecharacteristicsofpicklingwastewaterinthecold-rollingproductionofstainlesssteel,anewprocessingroute,featuringsourcesludgereduction,wastewatertwo-stagetreatment,heavymetal-containedsludgeandcalciumsaltsludgeseparatingrecovery,wasproposed.Asshownbytheresearchresults,afterthetwo-stageprocesstreatment,theeffluentwatercansteadilyreachtheemissionstandards,thesludgeyieldcanbedecreasedbymorethan8%;withintheheavymetal-containedsludge,therecoveryratesofFe,CrandNicaneitherreachorsurpass95%,andthetotalcontentofFandScandroptoaround3%.Therefore,thesludgeinthefrontpartcanbeusedasferricdust.Inthecalciumsaltsludge,therecoveryrateofFcaneitherreachorsurpass85%,andthetotalcontentsofFe,CrandNicanfallbelow0.5%.Sothesludgeintherearpartcanbeusedasfluorgypsumorfluorite.Meanwhile,theresultsoftheanalysisonheavymetalsleachingtoxicityandmorphologicdistributionindicatethatthetwokindsofsectionalizedsludgearenotclassifiedashazardouswastes,whichhaveastablebehaviorandbetterutilizationvaluescomparedwiththeformermixed-sludge.
简介:微观结构和当演员组Mg-4.0Sm-1.0Ca合金的机械性质在由热挤出组成的thermomechanical处理期间被调查,滚动,并且在473K变老。Mg41Sm5阶段包含Ca和像针的Mg2在Mg矩阵形成的Ca阶段,和平均谷物尺寸和延伸是4.2m并且27%,分别地在热挤出以后,它在韧性暗示了增加。在滚动以后,另外,谷物尺寸进一步被精制,并且张力的力量增加了到293MPa。一新猛抛Mg3Sm在山峰Mg-4.0Sm-1.0Ca合金被发现,这合金显示了最好的机械性质,与83HV的山峰坚硬和313MPa的最终的张力的力量;这些性质被归因于谷物精炼加强,加强的稳固的答案,变硬的工作,并且降水加强。
简介:Surface-treatedMmNi3.55Co0.75Mn0.4Al0.3alloyasnegativeelectrodematerialofnickel-metalhydridebatterywasemployedtoimprovethehigh-ratedischargeability.SurfacetreatmentwasrealizedbydippingandstirringthealloyintoaHClaqueoussolutionwithvariousconcentrationsatroomtemperature.ThemicrostructureofthealloybeforeandaftersurfacetreatmentwasanalyzedbyX-raydiffraction(XRD)andscanningelectronmicroscopy(SEM).Theelectrochemicalpropertiesbeforeandaftersurfacetreatmentwerecompared,andthealloytreatedin0.025mol/LHClsolutionshowedtheoptimalhigh-ratedischargeability.
简介:TheeffectofrapidsolidificationonstructureandelectrochemicalperformanceoftheLaNi4.5Co0.25Al0.25hydrogenstoragealloywasinvestigatedbyX-raypowderdiffractionandasimulatedbatterytest,includingmaximumcapacity,cyclingstability,self-discharge,andhigh-ratedischargeability(HRD).Allthemelt-spunalloysweresingle-phasewiththeCaCu5-typestructure(spacegroupP6/mmm).Incomparisontotheas-castalloy,therapidlyquenchedalloysmanifestedanimprovedhomogeneityofcompositionandexpandedlatticeparameters.Theelectrochemicalmeasurementsshowedthattheactivationproperty,cyclingstabilityandself-dischargeofthealloyelectrodeswerealsoimprovedfortherapidsolidifiedalloys.TheHRDoftheas-castalloywasbetterthanthoseofalltherapidlysolidifiedalloys.Asthequenchingrateincreased,theHRDandexchangecurrentdensityfirstdecreasedandthenincreased.
简介:Thetransformationinducedplasticity(TRIP)steelseffectoccursbecauseofthemartensitictransformationofretainedausteniteduringplasticdeformation,anditprovidesthesteelwithexcellentstrengthandductility.Whileweldingremainsavitalpartofautobodymanufacturing,theweldabilityofTRIPsteelsisproblematic,andthispreventsitsadoptionformanyapplicationsintheautomotiveindustry.Thispresentworkstudiestheeffectsofweldingandpost-weldheattreatmentonthemicrostructureof...
简介:AhighalloyedVanadis4(V4)steelwasproducedbysprayformingprocessinBaosteel,andthemicrostructureoftheas-sprayedsteelanditsevolutionduringhotrollingandannealingprocesseswerecharacterized.Itwasfoundthattheas-sprayedV4steelhasahomogeneousandfinescalemicrostructurewithuniformdispersionofcarbides.Thehotrollingtemperatureisthekeyfactorincontrollingtheevolutionoftype,morphologyanddistributionofcarbides,aswellasthematrixmicrostructureoftheas-rolledsteels.Theoptimizedprocessingparametersfortheas-sprayedV4steelarerollingat1050℃andthenannealingat900℃.Themicrostructuralevolutionmechanismsduringhotrollingandannealingaredeterminedaccordingtothemicrostructuralanalyasisofthematerialatdifferentstages.