学科分类
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92 个结果
  • 简介:Accordingtothegoodchargetransportingpropertyofperovskite,wedesignandsimulateap–i–n-typeall-perovskitesolarcellbyusingone-dimensionaldevicesimulator.Theperovskitechargetransportinglayersandtheperovskiteabsorberconstitutetheall-perovskitecell.Bymodulatingthecellparameters,suchaslayerthicknessvalues,dopingconcentrationsandenergybandsofn-,i-,andp-typeperovskitelayers,theall-perovskitesolarcellobtainsahighpowerconversionefficiencyof25.84%.Thebandmatchedcellshowsappreciablyimprovedperformancewithwidenabsorptionspectrumandloweredrecombinationrate,soweobtainahighJ_(sc)of32.47mA/cm~2.Thesmallseriesresistanceoftheall-perovskitesolarcellalsobenefitsthehighJ_(sc).Thesimulationprovidesanovelthoughtofdesigningperovskitesolarcellswithsimpleproducingprocess,lowproductioncostandhighefficientstructuretosolvetheenergyproblem.

  • 标签: 高效太阳能电池 钙钛矿型 仿真设计 n型 模拟器设计 P型
  • 简介:TheexistenceanduniquenessofastrongperiodicsolutionoftheevolutionsystemdescribinggeophysicalflowinboundeddomainsofRN(N=3,4)areprovenifexternalforcesareperiodicintimeandsufficientlysmall.

  • 标签: 存在性 唯一性 强周期解 有界域 发展系统
  • 简介:介绍了阻变存储器及其I-V特性的测试分析方法。通过测量三明治结构的阻变存储器的I-V特性,采用多种拟合方法,与导电机制原理对比,可以判断器件的导电机制,便于深入分析阻变机理。

  • 标签: 电致阻变 I-V特性 导电机制
  • 简介:Copolymerizationofstyrene(St)andisoprene(IP)wascarriedoutwithacatalystsystemcomposeaofanhydrouslanthanidechloridehexamethylphosphoramidecomplex(LnCl3·HMPA)andaluminumorganiccompound(AOC).Amongthecatalystsexamined,catalystNdCl3·HMPA/AI(i-Bu)3showedahighactivityinthecopolymerizationundercertainconditionsgivingcopolymers(5%—15%Stcontent)withhighcis-1,4microstructureinIPunits(>95%).TheeffectsofHMPA/Ndmolarratio,Al/Ndmolarratio,monomer/Ndmolarratio,Stfeedratio,andthereactiontimeoncopolymerizationwereexaminedwiththiscatalyticsystem.Theobtainedcopolymerswerecharacterizedby^1Hand^13CNMRspectroscopiesandgel-permeationchromatography(GPC).

  • 标签: 异戊二烯 苯乙烯 氯化镧 共聚反应 六甲基磷酰胺 铝有机化合物
  • 简介:Inliterature,nonlineartravelingwavesinelasticcircularrodshaveonlybeenstudiedbasedonsinglepartialdifferentialequation(pde)models,andhereweconsidersuchaproblembyusingamoreaccuratecoupled-pdemodel.WederivetheHamiltonianfromthemodelequationsforthelongfinite-amplitudewaveapproximation,analyzehowthenumberofsingularpointsofthesystemchangeswiththeparameters,andstudythefeaturesofthesesingularpointsqualitatively.Variousphysicallyacceptablenonlineartravelingwavesarealsodiscussed,andcorrespondingexamplesaregiven.Inparticular,wefindthatcertainwaves,whichcannotbecourltedbythesingle-equationmodel,canarise.

  • 标签: 非线性波动 独立性 周期性 超弹性棒 张力能量方程
  • 简介:近年来,国内企业界在CI设计的开发和导入过程中,形成了一系列令人瞩目的示范效应。这引起了理论界、设计界对CI作业过程中的管理问题的重视。本文着重探讨在CI作业过程中,引入计划-控制-计划管理循环的模式和具体方法。

  • 标签: 管理循环 名牌策划 品牌管理 企业形象设计
  • 简介:AseriesofRbxCs1-xAg4I5(x=0-1)thinfilmsweregrownbyvacuumevaporationonNaCIcrystalsubstratesat350K.Theabsorptionspectraofthesefilmsweremeasuredat80Kinthewavelengthrangefrom240nmto400nm.ItisshownthatsuperionicconductorthinfilmsofquaternarycompoundRb0.5Cs0.5Ag4I5andternarycompoundRbAg415canbeobtainedatx=0.5-0.6andx=0.7-1,respectively.Atx=0.65,thecombinedcompoundfilmofthemixtureof30mol%RbAg4I5and70mol%Rb0.5Cs0.5Ag4I5ispresented.Then,basedonthespectralpositionsoftheA1andA2peaks,wedeterminedthattheRb0.5Cs0.5Ag4I5excitoncouplingenergyRexis0.21eV,theforbiddenzonewidthEgis3.82eVandtheexcitonradiusaexis0.70hm.Furthermore,theionicconductivitiesofsuperionicconductorthinfilmsofRbAg4I5andRb0.5Cs0.5Ag4I5andtheirmixturefilmareinvestigated,respectively,inthetemperaturerange303K-393K.

  • 标签: 吸收光谱 离子传导性 超离子导体薄膜 真空演化
  • 简介:Inthisarticleweconsideratwo-levelfiniteelementGalerkinmethodusingmixedfiniteelementsforthetwo-dimensionalnonstationaryincompressibleNavier-Stokesequations.ThemethodyieldsaH^1-optimalvelocityapproximationandaL^2-optimalpressureapproximation.Thetwo-levelfiniteelementGalerkinmethodinvolvessolvingonesmall,nonlinearNavier-StokesproblemonthecoarsemeshwithmeshsizeH,onelinearStokesproblemonthefinemeshwithmeshsizeh<

  • 标签: 有限元GALERKIN法 NAVIER-STOKES方程 空间离散化 偏微分方程 误差估计
  • 简介:Inthispaper,normalincidenceverticalp-i-nphotodetectorsonagermanium-on-insulator(GOI)platformweredemonstrated.Theverticalp-i-nstructurewasrealizedbyion-implantingboronandarsenicatthebottomandtopoftheGelayer,respectively,duringtheGOIfabrication.Abruptdopingprofileswereverifiedinthetransferredhigh-qualityGelayer.Thephotodetectorsexhibitadarkcurrentdensityof~47mA∕cm~2at-1Vandanopticalresponsivityof0.39A/Wat1550nm,whichareimprovedcomparedwithstate-of-the-artdemonstratedGOIphotodetectors.Aninternalquantumefficiencyof~97%indicatesexcellentcarriercollectionefficiencyofthedevice.Thephotodetectorswithmesadiameterof60μmexhibita3dBbandwidthof~1GHz,whichagreeswellwiththeoreticalcalculations.Thebandwidthisexpectedtoimproveto~32GHzwithmesadiameterof10μm.ThisworkcouldbesimilarlyextendedtoGOIplatformswithotherintermediatelayersandpotentiallyenrichthefunctionaldiversityofGOIfornear-infraredsensingandcommunicationintegratedwithGeCMOSandmid-infraredphotonics.

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  • 简介:Forthequadraticsystem:x=-y+δx+lx^2+ny^21y=x(1+ax-y)undercondtions-1<1<0,n+l-1>0theauthordrawsinthe(a,b)parameterplanetheglobalbifurcationdiagramoftrajectoriesaroundO(0,0).Noticethatwhenna^2+1<0thesystemhasonesaddleN(0,1/n)andthreeantisaddles.

  • 标签: 极限周期 分歧曲线 二次微分系统 反鞍点
  • 简介:以2-醛基吡啶和1,2-二(对氨基苯氧基)乙烷进行缩合得到Schiff碱配体L,然后与AgSbF6进行配位反应,得到了席夫碱配合物[Ag(L)SbF6]n,用元素分析、FT-IR和X-射线单晶衍射进行了表征.结果表明,配合物属于单斜晶系,P21/n空间群,每个Ag(I)的配位环境均为扭曲四面体,每个配体L通过其两端的2个N原子同2个金属离子配位桥联形成一维螺旋链结构.

  • 标签: 席夫碱 Ag(Ⅰ)配合物 晶体结构
  • 简介:Shortpeptidesbasedonthetripeptides,Leu-Arg-ProandLeu-Lys-Pro,weresynthesizedbymicrowaveassistedsolid-phasesynthesismethod,inordertomakeasearchforpotentialinhibitorsforangiotensinI-convertingenzyme(ACE)withminimumsideeffectsinthetreatmentofhypertension.OnepeptidewiththesequenceLeu-Arg-Pro-Phe-PheshowsthestrongestinhibitiontowardsACEwithanIC50valueof0.26μmol/Linvitro.Thestudyofstructure-activityrelationshipshowsthattheintroductionofabulkygroupintotheN-terminalofthisseriesofinhibitorsmayenlargesterichindrance,resultinginthepoorinhibitoryactivitytowardsACE.TheinhibitoryactivitydecreasedinturnwhenL-Pro,D-ProorAc6cwasattheC-terminalrespectively.ThebindinginteractionbetweeneachoftheseinhibitorsandtesticularACE(tACE)wasperformedbymoleculardocking.TheresultssuggestthatLeu-Arg-Pro-Phe-PhemainlyoccupiedtheS1subsiteoftACE,andmadecontactwithtACEviasevenH-bonds.ItappearedthatthesiteonthepeptidethatboundwithtACEwasinfluencedbytheconfigurationoftheaminoacid,LorD-form,attheC-terminalofthepeptide.

  • 标签: 血管紧张素转换酶抑制剂 固相合成 微波辅助 分子对接 生物评价 ACE抑制活性
  • 简介:Theadsorptionoflowconcentrationoffreeacidbyregenerablechitinisfollowedbyelectricconductancedetermination.Theeffectofacidconcentratioin,contentoffunctioinalaminogroups,andionicstrengthonadsorptionwasdiscussed.Experimentalresultsindicatethattheactivecentreofregenerablechitinisthefreeaminogroupsonistsurface,andthattherateofadsorptionoffreeacidwasfoundtobeaffectedbytwofactors:theinteractionbetweentheadsorbentandtheadsorbateinsolutionandthatbetweentheadsorbatemoleculesorionsinsolution.

  • 标签: 吸附剂 吸附物 相互作用
  • 简介:通过理论分析和PIC数值模拟,研究了阳极腔区结构对无箔二极管I-Ⅴ特性的影响,得到了束流强度和结构影响因子的变化规律.研究发现,当阴阳极间距大于0时,无箔二极管的结构影响因子随着阳极腔区半径的增大而减小并逐渐趋于稳定,且对于较小的阴极外半径、较大的漂移管半径、较大的阴阳极间距,达到稳定后的结构影响因子越小,并给出了结构影响因子的可调节范围.在TPG700脉冲驱动源上开展了初步实验研究,对实验中的回流电子束进行数值模拟分析并去除其影响以后,实验结果很好地符合了理论分析结论.

  • 标签: 无箔二极管 强流电子束 I-V特性 结构影响因子
  • 简介:本文考虑的是备货型商品的生产与优化管理。商品的生产过程是随机可控的。需求过程是一个根据销售价格高低来控制的随机过程。本文主要研究是这样一个系统的利润函数。

  • 标签: 备货型商品 泊松生产 利润函数
  • 简介:Photonics-basedradarwithaphotonicde-chirpreceiverhastheadvantagesofbroadbandoperationandreal-timesignalprocessing,butitsuffersfrominterferencefromimagefrequenciesandotherundesiredfrequency-mixingcomponents,duetosingle-channelreal-valuedphotonicfrequencymixing.Inthispaper,weproposeaphotonicsbasedradarwithaphotonicfrequency-doublingtransmitterandabalancedin-phaseandquadrature(I/Q)de-chirpreceiver.Thisradartransmitsbroadbandlinearlyfrequency-modulatedsignalsgeneratedbyphotonicfrequencydoublingandperformsI/Qde-chirpingoftheradarechoesbasedonabalancedphotonicI/Qfrequencymixer,whichisrealizedbyapplyinga90°opticalhybridfollowedbybalancedphotodetectors.Theproposedradarhasahighrangeresolutionbecauseofthelargeoperationbandwidthandachievesinterference-freedetectionbysuppressingtheimagefrequenciesandotherundesiredfrequency-mixingcomponents.Intheexperiment,aphotonics-basedK-bandradarwithabandwidthof8GHzisdemonstrated.ThebalancedI/Qde-chirpingreceiverachievesanimage-rejectionratioofover30dBandsuccessfullyeliminatestheinterferenceduetothebasebandenvelopeandthefrequencymixingbetweenradarechoesofdifferenttargets.Inaddition,thedesireddechirpedsignalpowerisalsoenhancedwithbalanceddetection.Basedontheestablishedphotonics-basedradar,inversesyntheticapertureradarimagingisalsoimplemented,throughwhichtheadvantagesoftheproposedradarareverified.

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  • 简介:Amechanismisproposedfornucleatepoolboilingheattransferalongwithageneralmodelforbothpureliquidsandbinarymixtrues.Acombinedphysicalmodelofbubblegrowthisalsoproposedalongwithacorrespondingbubblegrowthmodelforpureliquidsonsmoothtubes.Usingthegeneralmodelandthebubblegrowthmodelforpureliquids,ananalyticaslmodelfornucleatepoolboilingheattransferofpureliquidsonsmoothtubesisdeveloped.

  • 标签: 热传导 沸腾液体 光滑管
  • 简介:ACupro-8-thioquinolinecoordinationpolymer,[Cu^I(C9H6NS)]n,wassynthesizedbymethano-thermalreactionofCuCland8,8′-dithiodiquinoline(dtdq)inamolarratioof2:1at160℃for7d.X-Raysinglecrystalstructuredeterminationrevealedtheformationofaone-dimensionalstructurebelongingtomonocliniccrystalsystem,spacegroupP21/cwithcellparametersa=0.8043(1)nm,b=1.8949(3)nm,c=1.1048(1)nm,β=110.109(4)°,V=1.5810(4)nm^3andZ=4,Thecrystalwasfoundtobestableuptoapproximately300℃bythermalanalysisandhaveanenergygap(Eg)of2.0eVexhibitedbyUV-Vis-NIRreflectancespectrum.

  • 标签: n 8-硫代喹啉 铜(Ⅰ) 核磁共振 紫外光谱 配位聚合物