简介:Accordingtothegoodchargetransportingpropertyofperovskite,wedesignandsimulateap–i–n-typeall-perovskitesolarcellbyusingone-dimensionaldevicesimulator.Theperovskitechargetransportinglayersandtheperovskiteabsorberconstitutetheall-perovskitecell.Bymodulatingthecellparameters,suchaslayerthicknessvalues,dopingconcentrationsandenergybandsofn-,i-,andp-typeperovskitelayers,theall-perovskitesolarcellobtainsahighpowerconversionefficiencyof25.84%.Thebandmatchedcellshowsappreciablyimprovedperformancewithwidenabsorptionspectrumandloweredrecombinationrate,soweobtainahighJ_(sc)of32.47mA/cm~2.Thesmallseriesresistanceoftheall-perovskitesolarcellalsobenefitsthehighJ_(sc).Thesimulationprovidesanovelthoughtofdesigningperovskitesolarcellswithsimpleproducingprocess,lowproductioncostandhighefficientstructuretosolvetheenergyproblem.
简介:Copolymerizationofstyrene(St)andisoprene(IP)wascarriedoutwithacatalystsystemcomposeaofanhydrouslanthanidechloridehexamethylphosphoramidecomplex(LnCl3·HMPA)andaluminumorganiccompound(AOC).Amongthecatalystsexamined,catalystNdCl3·HMPA/AI(i-Bu)3showedahighactivityinthecopolymerizationundercertainconditionsgivingcopolymers(5%—15%Stcontent)withhighcis-1,4microstructureinIPunits(>95%).TheeffectsofHMPA/Ndmolarratio,Al/Ndmolarratio,monomer/Ndmolarratio,Stfeedratio,andthereactiontimeoncopolymerizationwereexaminedwiththiscatalyticsystem.Theobtainedcopolymerswerecharacterizedby^1Hand^13CNMRspectroscopiesandgel-permeationchromatography(GPC).
简介:Inliterature,nonlineartravelingwavesinelasticcircularrodshaveonlybeenstudiedbasedonsinglepartialdifferentialequation(pde)models,andhereweconsidersuchaproblembyusingamoreaccuratecoupled-pdemodel.WederivetheHamiltonianfromthemodelequationsforthelongfinite-amplitudewaveapproximation,analyzehowthenumberofsingularpointsofthesystemchangeswiththeparameters,andstudythefeaturesofthesesingularpointsqualitatively.Variousphysicallyacceptablenonlineartravelingwavesarealsodiscussed,andcorrespondingexamplesaregiven.Inparticular,wefindthatcertainwaves,whichcannotbecourltedbythesingle-equationmodel,canarise.
简介:AseriesofRbxCs1-xAg4I5(x=0-1)thinfilmsweregrownbyvacuumevaporationonNaCIcrystalsubstratesat350K.Theabsorptionspectraofthesefilmsweremeasuredat80Kinthewavelengthrangefrom240nmto400nm.ItisshownthatsuperionicconductorthinfilmsofquaternarycompoundRb0.5Cs0.5Ag4I5andternarycompoundRbAg415canbeobtainedatx=0.5-0.6andx=0.7-1,respectively.Atx=0.65,thecombinedcompoundfilmofthemixtureof30mol%RbAg4I5and70mol%Rb0.5Cs0.5Ag4I5ispresented.Then,basedonthespectralpositionsoftheA1andA2peaks,wedeterminedthattheRb0.5Cs0.5Ag4I5excitoncouplingenergyRexis0.21eV,theforbiddenzonewidthEgis3.82eVandtheexcitonradiusaexis0.70hm.Furthermore,theionicconductivitiesofsuperionicconductorthinfilmsofRbAg4I5andRb0.5Cs0.5Ag4I5andtheirmixturefilmareinvestigated,respectively,inthetemperaturerange303K-393K.
简介:Inthisarticleweconsideratwo-levelfiniteelementGalerkinmethodusingmixedfiniteelementsforthetwo-dimensionalnonstationaryincompressibleNavier-Stokesequations.ThemethodyieldsaH^1-optimalvelocityapproximationandaL^2-optimalpressureapproximation.Thetwo-levelfiniteelementGalerkinmethodinvolvessolvingonesmall,nonlinearNavier-StokesproblemonthecoarsemeshwithmeshsizeH,onelinearStokesproblemonthefinemeshwithmeshsizeh<
简介:Inthispaper,normalincidenceverticalp-i-nphotodetectorsonagermanium-on-insulator(GOI)platformweredemonstrated.Theverticalp-i-nstructurewasrealizedbyion-implantingboronandarsenicatthebottomandtopoftheGelayer,respectively,duringtheGOIfabrication.Abruptdopingprofileswereverifiedinthetransferredhigh-qualityGelayer.Thephotodetectorsexhibitadarkcurrentdensityof~47mA∕cm~2at-1Vandanopticalresponsivityof0.39A/Wat1550nm,whichareimprovedcomparedwithstate-of-the-artdemonstratedGOIphotodetectors.Aninternalquantumefficiencyof~97%indicatesexcellentcarriercollectionefficiencyofthedevice.Thephotodetectorswithmesadiameterof60μmexhibita3dBbandwidthof~1GHz,whichagreeswellwiththeoreticalcalculations.Thebandwidthisexpectedtoimproveto~32GHzwithmesadiameterof10μm.ThisworkcouldbesimilarlyextendedtoGOIplatformswithotherintermediatelayersandpotentiallyenrichthefunctionaldiversityofGOIfornear-infraredsensingandcommunicationintegratedwithGeCMOSandmid-infraredphotonics.
简介:Shortpeptidesbasedonthetripeptides,Leu-Arg-ProandLeu-Lys-Pro,weresynthesizedbymicrowaveassistedsolid-phasesynthesismethod,inordertomakeasearchforpotentialinhibitorsforangiotensinI-convertingenzyme(ACE)withminimumsideeffectsinthetreatmentofhypertension.OnepeptidewiththesequenceLeu-Arg-Pro-Phe-PheshowsthestrongestinhibitiontowardsACEwithanIC50valueof0.26μmol/Linvitro.Thestudyofstructure-activityrelationshipshowsthattheintroductionofabulkygroupintotheN-terminalofthisseriesofinhibitorsmayenlargesterichindrance,resultinginthepoorinhibitoryactivitytowardsACE.TheinhibitoryactivitydecreasedinturnwhenL-Pro,D-ProorAc6cwasattheC-terminalrespectively.ThebindinginteractionbetweeneachoftheseinhibitorsandtesticularACE(tACE)wasperformedbymoleculardocking.TheresultssuggestthatLeu-Arg-Pro-Phe-PhemainlyoccupiedtheS1subsiteoftACE,andmadecontactwithtACEviasevenH-bonds.ItappearedthatthesiteonthepeptidethatboundwithtACEwasinfluencedbytheconfigurationoftheaminoacid,LorD-form,attheC-terminalofthepeptide.
简介:Theadsorptionoflowconcentrationoffreeacidbyregenerablechitinisfollowedbyelectricconductancedetermination.Theeffectofacidconcentratioin,contentoffunctioinalaminogroups,andionicstrengthonadsorptionwasdiscussed.Experimentalresultsindicatethattheactivecentreofregenerablechitinisthefreeaminogroupsonistsurface,andthattherateofadsorptionoffreeacidwasfoundtobeaffectedbytwofactors:theinteractionbetweentheadsorbentandtheadsorbateinsolutionandthatbetweentheadsorbatemoleculesorionsinsolution.
简介:Photonics-basedradarwithaphotonicde-chirpreceiverhastheadvantagesofbroadbandoperationandreal-timesignalprocessing,butitsuffersfrominterferencefromimagefrequenciesandotherundesiredfrequency-mixingcomponents,duetosingle-channelreal-valuedphotonicfrequencymixing.Inthispaper,weproposeaphotonicsbasedradarwithaphotonicfrequency-doublingtransmitterandabalancedin-phaseandquadrature(I/Q)de-chirpreceiver.Thisradartransmitsbroadbandlinearlyfrequency-modulatedsignalsgeneratedbyphotonicfrequencydoublingandperformsI/Qde-chirpingoftheradarechoesbasedonabalancedphotonicI/Qfrequencymixer,whichisrealizedbyapplyinga90°opticalhybridfollowedbybalancedphotodetectors.Theproposedradarhasahighrangeresolutionbecauseofthelargeoperationbandwidthandachievesinterference-freedetectionbysuppressingtheimagefrequenciesandotherundesiredfrequency-mixingcomponents.Intheexperiment,aphotonics-basedK-bandradarwithabandwidthof8GHzisdemonstrated.ThebalancedI/Qde-chirpingreceiverachievesanimage-rejectionratioofover30dBandsuccessfullyeliminatestheinterferenceduetothebasebandenvelopeandthefrequencymixingbetweenradarechoesofdifferenttargets.Inaddition,thedesireddechirpedsignalpowerisalsoenhancedwithbalanceddetection.Basedontheestablishedphotonics-basedradar,inversesyntheticapertureradarimagingisalsoimplemented,throughwhichtheadvantagesoftheproposedradarareverified.
简介:Amechanismisproposedfornucleatepoolboilingheattransferalongwithageneralmodelforbothpureliquidsandbinarymixtrues.Acombinedphysicalmodelofbubblegrowthisalsoproposedalongwithacorrespondingbubblegrowthmodelforpureliquidsonsmoothtubes.Usingthegeneralmodelandthebubblegrowthmodelforpureliquids,ananalyticaslmodelfornucleatepoolboilingheattransferofpureliquidsonsmoothtubesisdeveloped.
简介:ACupro-8-thioquinolinecoordinationpolymer,[Cu^I(C9H6NS)]n,wassynthesizedbymethano-thermalreactionofCuCland8,8′-dithiodiquinoline(dtdq)inamolarratioof2:1at160℃for7d.X-Raysinglecrystalstructuredeterminationrevealedtheformationofaone-dimensionalstructurebelongingtomonocliniccrystalsystem,spacegroupP21/cwithcellparametersa=0.8043(1)nm,b=1.8949(3)nm,c=1.1048(1)nm,β=110.109(4)°,V=1.5810(4)nm^3andZ=4,Thecrystalwasfoundtobestableuptoapproximately300℃bythermalanalysisandhaveanenergygap(Eg)of2.0eVexhibitedbyUV-Vis-NIRreflectancespectrum.