学科分类
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50 个结果
  • 简介:PtRu/SnO2/Ccatalystwaspreparedinapolyolprocess,followedbyreductiontreatmentandalkalineetching.X-raydiffraction,transmissionelectronmicroscopewithenergydispersivespectrometerandXrayphotoelectronspectroscopywereusedtocharacterizethemorphology,structureandcompositionofthecatalysts.COandmethanolelectro-oxidationactivitiesofthecatalystswereevaluatedbyCOstrippingvoltammetry,cyclicvoltammetryandchronoamperometrymeasurements.ReductiontreatmentofthepreparedPtRuSnO2/CcatalystinapolyolprocessinducedtheenrichmentofSnonthesurface,inhibitingmethanoldissolutionandCOadsorptiononPt.AlkalineetchingremovedSnorSnOxandthusexposedPtRuonthesurface,resultinginenhancedactivitiesforCOandmethanolelectro-oxidationduetothesynergyeffectsofPtRuonthesurfaceandSnspeciesbeneath.

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  • 简介:Thefirstorderdifferentialmatrixequationsofthehostshellandconstrainedlayerforasandwichrotationalshellarederivedbasedonthethinshelltheory.Employingthelayerwiseprincipleandfirstordersheardeformationtheory,onlyconsideringtheshearingdeformationoftheviscoelasticlayer,theintegratedfirstorderdifferentialmatrixequationofapassiveconstrainedlayerdampingrotationalshellisestablishedbycombiningwiththenormalequilibriumequationoftheviscoelasticlayer.Ahighlyprecisetransfermatrixmethodisdevelopedbyextendedhomogeneouscapacityprecisionintegrationtechnology.Thenumericalresultsshowthatpresentmethodisaccurateandeffective.

  • 标签: 旋转壳 矩阵法分析 阻尼特性 阻尼振动 一阶剪切变形理论 传递
  • 简介:由Wittmann和Lotz等的isotactic聚丙烯(iPP)的三个领域的概念的介绍。是在在结晶化行为和作为结果的性质上理解melt结构的影响的重要进展。为了进一步理解melt的物理性质,组织,在在三个领域的热处理以后的iPP的水晶的结构系统地被调查。在在不同领域对待以后,它被发现那水晶形态学包括spherulitic的尺寸和birefringence,光线、正切的lamellae的比例,等等,有显然不同的特征。我们的学习表明在域II的原子核局部地订的链和导致的存储器效果创作不能在退火下面被擦掉处理当在域III的原子核水晶碎片创作时,它将在退火下面聚集进程。基于我们的结果,高度图解的图被建议在三个不同领域说明melt结构的可能的物理特征。

  • 标签: 等规聚丙烯 结晶行为 形态演化 治疗 熔体结构 物理性质
  • 简介:Differentoxygenandnitrogencontainingfunctionalgroupswerecreatedonthesurfaceofthemultiwalledcarbonnanotubes.Themulti-walledcarbonnanotubesweretreatedinultrasonicbathwithsulfuricornitricacid.Furthermorethesurfacetexturewasmodifiedbyincreaseoftheroughness.Inparticularaftertreatmentwiththeoxidizingnitricacid,incomparisontotheH_2SO_4orultra-sonictreatedsamples,cratersandedgesaredominatingthesurfacestructures.Manganeseoxidewasdepositedonthemultiwalledcarbonnanotubesbyprecipitationmechanism.Variousmanganeseoxidesareformedduringthedepositionprocess.Thesampleswerecharacterizedbyelementalanalysis,microscopy,thermalanalysis,Ramanspectroscopy,andbythezetapotentialaswellasX-raydiffractionmeasurements.Itwasshownthatthedepositedmanganeseoxidesarestabilizedratherbysurfacetextureofthemulti-walledcarbonnanotubesthanbycreatedfunctionalgroups.

  • 标签: 多壁碳纳米管 预处理程序 催化剂载体 氧化锰 X射线衍射测量 含氮官能团
  • 简介:纸由使用biomagnetic液体动力学(BFD)的原则通过一个多孔的中等题目处理biomagnetic液体流动的一个基本问题的理论调查到一个磁场。学习与液体的磁化与温度变化的一种状况相关。液体被认为非牛顿,其流动被一个二年级的方程管理粘弹性的液体。隧道的墙被假定可拉长,在表面速度与从坐标的起源的纵的距离成正比的地方。这个问题首先被归结为解决包含七个参数的联合非线性的微分方程的一个系统。把血看作biomagnetic液体并且使用现在的分析,被尝试由开发一个合适的数字方法并且由设计一个适当有限差别计划计算血流动的一些参数。计算结果在图形的形式被介绍,并且从而,一些理论预言在一个磁场的行动下面处于一个过高热的状态关于血的hemodynamical流动被做。结果清楚地显示磁性的偶极子的存在忍受潜力以便在电磁的过高热的治疗学的过程期间在动脉影响血流动的特征到重要程度。学习将吸引临床医生,结果将在由电磁的过高热的方法的癌症病人的治疗是谁有用的注意。

  • 标签: biomagnetic 液体 拉长墙 多孔的媒介 电磁的过高热
  • 简介:Toimprovetheinitialcoulombicefficiencyandbulkdensityoforderedmesoporouscarbons,activeFe2O3nanoparticleswereintroducedintotubularmesoporechannelsofCMK-5carbon,whichpossesseshighspecificsurfacearea(>1700m2g-1)andlargeporevolume(>1.8cm3g-1).FineFe2O3nanoparticleswithsizesintherangeof57nmwerehighlyandhomogenouslyencapsulatedintoCMK-5matrixthroughammonia-treatmentandsubsequentpyrolysismethod.TheFe2O3loadingwascarefullytailoredanddesignedtowarrantahighFe2O3contentandadequatebufferspaceforimprovingtheelectrochemicalperformance.Inparticular,suchFe2O3andmesoporouscarboncompositewith47wt%loadingexhibitsaconsiderablystablecycleperformance(683mAhg-1after100cycles,99%capacityretentionagainstthatofthesecondcycle)aswellasgoodratecapability.Thefabricationstrategycaneffectivelysolvethedrawbackofsinglematerial,andachieveahigh-performancelithiumelectrodematerial.

  • 标签: 碳纤维复合材料 FE203 锂离子电池 有序介孔 纳米粒子 氨处理
  • 简介:TheAlkalineThermalTreatment(ATT)ofbiomassisoneofthefewbiomassconversionprocessesthathasapotentialforBECCS(bio-energywithcarboncaptureandstorage).Combiningin-situcarboncapturewithcreatesacarbon-neutralprocessthathasthepotentialtobecarbon-negative.Thisstudyhasshownthattheconversionofcellulosetosuppressedcanbeachievedthroughthereformingofgaseousintermediatesinafixedbedof10%Ni/ZrO2.Reformingoccursatlowtemperatures≤773K,whichcouldallowforimprovedsustainability.

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