简介：有drag系数修正的Eulerian小粒的多相的模型基于精力最小化多尺度(扩展内存管理程序)模型被用来规模传播模仿半工业使流体化的床(CFB)。三维(3D)，完整环的CFB的时间依赖者模拟表明跨sectionally的轴的侧面平均稳固的体积部分，和稳固的轴的速度的光线的侧面，稳固的体积部分在对试验性的数据的合理同意。基于这个协议，从还没完成的实验导出的数据库在CFB循环附近与如此的模拟，和液体政体图和压力平衡被填满因此被导出。这个工作在CFB上介绍一个综合观点并且为CFB建模展开一个新鲜范例，它能被期望帮助解决在争论长却为实验难的某些期。

简介：Intheunderwater-shockenvironment,cavitationoccursnearthestructuralsurface.Thedynamicresponseoffluid-structureinteractionsisinfluencedseriouslybythecavitationeffects.Itisalsothedifficultyinthefieldofunderwaterexplosion.Withthetraditionalboundaryelementmethodandthefiniteelementmethod(FEM),itisdifficulttosolvethenonlinearproblemwithcavitationeffectssubjectedtotheunderwaterexplosion.Tosolvethisproblem,undertheconsiderationofthecavitationeffectsandfluidcompressibility,withfluidvisciditybeingneglected,a3Dnumericalmodeloftransientnonlinearfluid-structureinteractionsubjectedtotheunderwaterexplosionisbuilt.Thefluidspectralelementmethod(SEM)andtheFEMareadoptedtosolvethismodel.AftercomparisonwiththeFEM,itisshownthattheSEMismoreprecisethantheFEM,andtheSEMresultsareingoodcoincidencewithbenchmarkresultsandexperimentresults.Basedonthis,combinedwithABAQUS,thetransientfluid-structureinteractionmechanismofthe3Dsubmergedsphericalshellandshipstiffenedplatessubjectedtotheunderwaterexplosionisdiscussed,andthecavitationregionanditsinfluenceonthestructuraldynamicresponsesarepresented.Thepaperaimsatprovidingreferencesforrelevantresearchontransientfluid-structureinteractionofshipstructuressubjectedtotheunderwaterexplosion.

简介：Thebubblesriseupandburstatthefreesurfaceisacomplextwo-phaseprocess.AfreeenergylatticeBoltzmannmethod(LBM)modelisadoptedinthispapertostudythisphenomenon.Theinterfacecapturingtechnique[Zhengetal.,2006]isusedtodealwiththehighdensityratioproblem.TheLaplacelawandtheair-waterinterfacecapturingabilityarevalidatedforthemultiphasemodel.Theinteractionbetweenthesinglebubbleormultiplebubblesandthefreesurfacearestudiedbythemultiphasemodel.Theforceactingonthebubbleandtheevolutionofthefreesurfaceisstudied.Meanwhile,effectoftheinitialdistancebetweentwoadjacentbubblesoninteractioneffectsofmultiplebubblesisinvestigatedaswell.

简介：有从30～80nm的尺寸的Fe3O4nanoparticles被湿milling铁粉末在一家行星的球工厂综合。阶段作文和同样综合的产品的形态学被X光检查衍射(XRD)测量，扫描电子显微镜学(SEM)和传播电子显微镜学(TEM)。NanosizedFe3O4粒子被湿milling准备金属性的铁粉末(?200网孔，99%)在与不锈钢装备的一家行星的球工厂，使用的小瓶与50:1并且以300rpm的旋转速度的ball-to-powder团比率在提取的水下面熨球。在这个方法的铁球的使用在Fe3O4formation起了一个关键作用。现在的技术简单，这个过程是容易的执行。

简介：Inthisstudy,factorsaffectingthecrystalstructureofflame-synthesizedY2O3:Euparticleswereinves-tigated,especiallytheparticlesizeeffectanditsinteractionwithEudopingconcentration.PolydisperseY2O3:Eu(sizerange200nmto3m)powdersampleswithEudopingconcentrationsfrom2.5mol%to25mol%weregeneratedineitherH2/airorH2/O2substrate-freeflames.ThecrystalstructureofthepowdersampleswasdeterminedbypowderX-raydiffraction(XRD),whichwascomplementedbypho-toluminescence(PL)measurements.Singleparticlecrystalstructurewasdeterminedbysingleparticleselectedareaelectrondiffraction(SAED),andforthefirsttime,byelectronbackscatterdiffraction(EBSD).H2/airflamesresultedincubicphaseY2O3:Euparticleswithhollowmorphologyandirregularshapes.ParticlesfromH2/O2flameshaddenseandsphericalmorphology;sampleswithlowerEudopingconcen-trationshadmixedcubic/monoclinicphases;sampleswiththehighestEudopingconcentrationswerephase-puremonoclinic.ForsamplesgeneratedfromH2/O2flames,aparticlesizeeffectanditsinteractionwithEudopingconcentrationwerefound:particlessmallerthanacriticaldiameterhadthemonoclinicphase,andthiscriticaldiameterincreasedwithincreasingEudopingconcentration.Thesefindingssug-gestthattheformationofmonoclinicY2O3:Euisinevitablewhenextremelyhotsubstrate-freeflamesareused,becausetypicalflame-synthesizedY2O3:Euparticlesizesarewellbelowthecriticaldiameter.However,itmaybepossibletogenerateparticleswithdense,sphericalmorphologyandthedesiredcubicstructurebyusingamoderatelyhighflametemperaturethatenablesfastsinteringwithoutmeltingtheparticles.

简介：Anewanalyticalmodelwasdevelopedtopredictthegravitywavedrag(GWD)inducedbyanisolated3-dimensionalmountain,overwhichastratified,non-rotatingnon-Boussinesqshearedflowisimpinged.Themodelisconfinedtosmallamplitudemotionandassumestheambientvelocityvaryingslowlywithheight.ThemodifiedTaylor-GoldsteinequationwithvariablecoefficientsissolvedwithaWentzel-Kramers-Brillouin(WKB)approximation,formallyvalidathighRichardsonnumbers.WiththisWKBsolution,genericformulaeofsecondorderaccuracy,fortheGWDandsurfacepressureperturbation(bothforhydrostaticandnon-hydrostaticflow)arepresented,enablingarigoroustreatmentontheeffectsbyverticalvariationsinwindprofiles.Inanidealtesttothecircularbell-shapedmountain,itwasfoundthatwhenthewindislinearlysheared,thattheGWDdecreasesastheRichardsonnumberdecreases.However,theGWDforaforwardshearedwind(windincreaseswithheight)decreasesalwaysfasterthanthatforthebackwardshearedwind(winddeceaseswithheight).Thisdifferenceisevidentwheneverthemodelishydrostaticornot.

简介：Inthepresentpaper,amultifluidmodeloftwo-phaseflowswithpulverized-coalcombustion,basedonacontinuum-trajectorymodelwithreactingparticlephase,isdevelopedandemployedtosimulatethe3-Dturbulenttwo-phaseflowsandcombustioninanewtypeofpulverized-coalcombustorwithoneprimary-airjetplacedalongthewallofthecombustor.Theresultsshowthat:(1)thiscontinuum-trajectorymodelwithreactingparticlephasecanbeusedinpracticalengineeringtoqualitativelypredicttheflamestability,concentrationsofgasspecies,possibilitiesofslagformationandsootdeposition,etc.;(2)largerecirculationzonescanbecreatedinthecombustor,whichisfavorabletotheignitionandflamestabilization.

简介：这研究向动人的表面为三维的麦克斯韦液体集中于热和集体流动的Cattaneo-Christov理论。有可变热电导率的不可压缩的laminar流动被考虑。流动产生由于表的双向拉长。热和集体运输的联合现象被说明。热和集体散开的Cattaneo-Christov模型被用来开发精力和集体种类的表情。在集体种类方程的一阶的化学反应术语被考虑。边界层假设导致管理数学模型。homotopic模拟被采用设想无尺寸的流动方程的结果。速度，温度，和集中的图显示出不同产生参数的效果。一个数字基准被介绍设想计算结果的会聚的价值。结果证明集中和温度地为热和集体散开的Cattaneo-Christov理论被腐烂。

简介：Perovskite-typeLa1-xCexMnO3（x=0-10%）catalystswerepreparedbyflamespraypyrolysisandtheiractivitiesduringthecatalyticoxidationofbenzenewereexaminedoverthetemperaturerangeof100-450℃.ThestructuralpropertiesandreducibilityofthesematerialswerealsocharacterizedbyX-raydiffraction（XRD）,N2adsorption/desorption,H2temperature-programmedreduction（H2-TPR）andX-rayphotoelectronspectroscopy（XPS）.TheincorporationofCewasfoundtoimprovethebenzeneoxidationactivity,andtheperovskiteinwhichxwas0.1exhibitedthehighestactivity.Phasecompositionandsurfaceelementalanalysesindicatedthatnon-stoichiometriccompoundswerepresent.TheincorporationofCehadanegligibleeffectonthespecificsurfaceareaoftheperovskitesandhencethisfactorhaslittleimpactonthecatalyticactivity.IntroductionofCe44+resultedinmodificationofthechemicalstatesofbothB-siteionsandoxygenspeciesandfacilitatedthereducibilityoftheperovskite.ThesurfaceMn4+/Mn3+ratiowasincreasedasaresultofCe4+substitution,whileadecreaseinthesurface-adsorbedO/latticeO(Oads/Olatt)ratiowasobserved.Therelationshipbetweenthesurfaceelementalratiosandcatalyticactivitywasestablishedtoallowabetterunderstandingoftheprocessbywhichbenzeneisoxidizedoverperovskites.

简介：Nanostructuredtransitionmetaloxidesarepromisingalternativeanodesforlithiumionbatteries.Li-ionstorageperformanceisexpectedtoimproveifhighpackingdensityenergyparticlesareavailable.Herein,Mn2O3microsphereswithaca.18μmdiameterandatappeddensityof1.33g/cm3weresynthesizedbyafacilesolvothermal-thermalcoversionroute.SphericalMnCO3precursorswereobtainedthroughsolvothermaltreatmentandtheydecomposedandconvertedintoMn2O3microspheresatanannealingtemperatureof700C.TheMn2O3microspheresconsistedofMn2O3nanoparticleswithanaverage40nmdiameter.TheseporousMn2O3microspheresallowgoodelectrolytepenetrationandprovideanionbufferreservoirtoensureaconstantelectrolytesupply.TheMn2O3microsphereshavereversiblecapacitiesof590and320mAh/gat50and400mA/g,respectively.Wethusreportanefficientrouteforthefabricationofenergyparticlesforadvancedenergystorage.

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简介：Anewefficientmeshlessmethodbasedontheelement-freeGalerkinmethodisproposedtoanalyzethestaticdeformationofthinandthickplatestructuresinthispaper.Usingthenew3Dshell-likekinematicsinanalogytothesolid-shellconceptofthefiniteelementmethod,discretizationiscarriedoutbythenodeslocatedontheupperandlowersurfacesofthestructures.Theapproximationofallunknownfieldvariablesiscarriedoutbyusingthemovingleastsquares(MLS)approximationschemeinthein-planedirections,whilethelinearinterpolationisappliedthroughthethicknessdirection.Thus,differentboundaryconditionsaredefinedonlyusingdisplacementsandpenaltymethodisusedtoenforcetheessentialboundaryconditions.TheconstrainedGalerkinweakform,whichincorporatesonlydisplacementdegreesoffreedom(d.o.f.s),isderived.Amodified3Dconstitutiverelationshipisadoptedinordertoavoidoreliminatesomeself-lockingeffects.Thenumericefficiencyoftheproposedmeshlessformulationisillustratedbythenumericexamples.

简介：通过分析1维和2维线性插值可以推导出任意斜角直线坐标系下n维线性插值的一般计算公式以及有唯一解的条件,这一结论能够应用于三维温度场计算。可以将n维插值问题归结如下：已知n＋1维空间中的n＋1个点的坐标以及第n＋2个点的n个坐标分量xn＋2,1,xn＋2,2,,xn＋2,n,求解该点的第n＋1个坐标分量xn＋2,n＋1。根据线性插值定义,第n＋2个点位于前n＋1个点所确定的n维超平面上。根据这一条件列写方程、求解方程可得到插值xn＋2,n＋1。n维插值问题有唯一解的条件是已知的n＋1个点在n维空间中构成的多面体的体积不为0。推导过程在斜角直线坐标系中完成,因而结论具有较大普适性。

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简介：hard-core/soft-shell钙碳酸盐(CaCO3)的合成/poly(甲基methacrylate)(PMMA)混合结构化的nanoparticles(<100nm)由把分裂成原子的微乳液聚合，过程被报导。聚合物链通过acoupling代理人的使用被抛锚到nano-CaCO3的表面上，triethoxyvinylsilane(TEVS)。铵persulfate(APS)，钠dodecyl硫酸盐(SDS)和n-pentanol分别地被用作开始者，表面活化剂和cosurfactant。coreshell乳胶粒子的聚合机制被讨论。由PMMA的nano-CaCO3的封装用一台传播电子显微镜(TEM)被证实。coreshell粒子的grafting百分比被thermogravimetric分析(TGA)调查。nano-CaCO3/PMMAcoreshell粒子被Fourier变换描绘红外线(FTIR)光谱学和微分扫描热量测定(DSC)。FTIR结果在nano-CaCO3粒子和PMMA的接口揭示了一个强壮的相互作用的存在，它成功地暗示聚合物链是grafted到通过联合代理人的连接的nano-CaCO3粒子的表面上。另外，TGA和DSC结果与纯nano-PMMA的相比显示了coreshell材料的热稳定性的改进。nano-CaCO3/PMMA粒子被混合进聚丙烯(PP)矩阵由融化处理。它能也用扫描PMMA锁住的电子显微镜学(SEM)被观察grafted在聚合物矩阵(PP矩阵)防碍到CaCO3nanoparticles上CaCO3的聚集并且因此与PP矩阵改进CaCO3nanoparticles的相容性。

简介：AlaminarpremixedPropane/Airflamewithafuelequivalenceratioof2.1wasemployedforanalysisofsootparticles.Zeroth-orderIognormaldistributions(ZOLD)wereusedintheanalysisofexperimentaldistributionphenomenaatdifferentresidencetimesduringsootformationintheflame.Rayleigh'stheoryandMie'sscatteringtheorywerecombinedwithagglomerateanalysisusingscatteringandextinctiondatatodeterminethefollowingsootcharacteristics:agglomerateparameters,volumetricfractions,massflowratesandsurfacegrowthrate.Sootdensitymeasurementswerecarriedouttodeterminedensityvariationsatdifferentstagesofgrowth.Themeasuredresultsshowthatmetricfractionandmassflowrateindicatethatthesurfacegrowthrateofsootparticlesexceedstheoxidationratesintheflamestudied.Thedataobtainedinthisworkwouldbeusedtostudysootoxidationrateunderflamingcondition.

简介：PureAl2O3-2SiO2powderswerepreparedbysol-gelandcoprecipitationmethods,andtheiralkaliactivationreactivitieswerecompared.Thealkali-activationreactivityofthepowderpreparedbythesol-gelmethodwashigherthanthatofthepowderpreparedbythecoprecipitationmethod.Thepowderswereinvestigatedby27AIand29Simagic-anglespinningnuclearmagneticresonancespectroscopy（MASNMR）tounderstandtherelationshipbetweentheirstructureandalkali-activationreactivity.The27AlMASNMRdatashowedthatthefive-coordinateAIcontentofthepowderpreparedbythesol-gelmethodwashigherthanthatofthepowderpreparedbycoprecipitation.Thehighercontentoffive-coordinateAlcorrespondedtohigheralkali-activationreactivity.The29SiMASNMRdatashowedthatforthepowderpreparedbythesol-gelmethod,siliconwasreplacedbyaluminumatsecondarycoordinationsitesofthecentralSiatomsduringcalcination.However,forthepowderpreparedbysingle-batchcoprecipitation,themainchangewasfromalowdegreeofpolycondensationtoahighdegreeofpolycondensation.