简介:6,9,11-Trihydroxy-6a,12a-dehydrorotenoid1(coccineoneB)wassynthesizedfrom2-hydroxybenzaldehyde2andphloroglucinol.
简介:Quasiclassicaltrajectorycalculation(QCT)isusedfrequentlyforstudyingcollisionalenergytransferbetweenhighlyvibrationallyexcitedmoleculesandbathgases.Inthispaper,theQCToftheenergytransferbetweenhighlyvibrationallyexcitedC6F6andN2,O2andgroundstateC6F6wereperformed.TheresultsindicatethathighlyvibrationallyexcitedC6F6transferredvibrationalenergytovibrationaldistributionofN2,O2andgroundstateC6F6,sotheyareV-Venergytransfer.EspeciallyitismainlyV-VresonanceenergytransferbetweenexcitedC6F6andgroundstateC6F6,excitedC6F6transfersmorevibrationalenergytogroundstateC6F6thantoN2andO2.ThevaluesofQCT,-〈△Evib〉ofexcitedC6F6aresmallerthanthoseofexperiments.
简介:TheimportanceoftheInternettomodernHighEnergyPhysicsCollaboratorsisclearlyimmense,andunderstandinghownewdevelopmentsinnetworktechnologyimpactnetworksiscriticaltothefuturedesignofexperiments.ThenextgenerationInternetProtocol(IPv6)isbeingdeployedontestbedsandproductionnetworksthroughouttheworld.Theprotocolhasbeendesignedtosolvetodaysinternetproblems,andmanyofthefeatureswillbecoreInternetservicesinthefuture.Inthistalkthefeaturesoftheprotocolwillbedescribed.DetailswillbegivenonthedeploymentatsitesimportanttoHighEnergyPhysicsResearchandthenetworkservicesoperatingatthesesites,InparticularIPv6deploymentontheU.S.EnergySciencesNetwork(ESnet)willbereviewed.TheconnectivityandperformancebetweenHighEnergyPhysicsLaboratories,UniversitiesandInstituteswillbediscussed.
简介:Wehaveinvestigatedthephysicalproperties,includingthemorphology,texture,adhesionandchemicalquality,ofhigh-frequencychemicalvapourdepositeddiamondcoatingsonWC-6%Cosubstrates,whichwerepre-treatedbyatwo-stepetchingmethod.TheresultsindicatethattheincreasingCocontentfrom0.12to3.05%withintheetchingdepthof5μmcausedamorphologytransformationfromprismdiamondtospheruliticdiamond,andatexturetransformationfroma{111}orientationtoa{110}orientation.TheRamanspectrumshowsthatthespheruliticdiamondfilmcontainsmorenon-diamondphases(graphite,amorphouscarbonanddiamond-likecarbon,etc)andhaslowerchemicalqualitythandiamondfilmsonaWC-6%Cosubstrate.Thediamondcoatinggrainsizesbecameaboutfourtimessmallerwhenthedepositiontemperaturesonthesubstratesurfacewerereducedfrom1000to900℃.Comparedwithspheruliticdiamondfilms,theprismdiamondfilmsexhibitbetteradhesionontheWC-6%Cosubstrate.
简介:Numericalsimulationofthemixedconvectioninducedbybuoyancy,crystalrotation,andalsounbalancedsurfacetensionatthemelt-gasinterfaceisconductedbymeansofthefinitevolumemethodinthemodeloftheCzochralskicrystalgrowth.TheroleofMarangoniconvectionintheheatandmasstransferisinvestigatedbythecomparisonofthemodelswithandwithoutsurfacetensionincluded,andourresultsindicatethatMarangoniconvectionplaysanimportantroleintheheatandmasstransferneartheinterfaceofmeltandcrystal,andalsotheconvectionstructure.
简介:Thenovelcomplex[K(18-C-6)]2[Cd(mnt)2][18-C-6-18-crown-6,nmt=1,2-dicyanoethene-1,2-dithiolate,C2S2-(CN)2^2-]wassynthesizedandcharacterizedbyelementalanalysis,IRspectrumandX-raydiffractionanalysis.Thecomplexdisplaystwo-dimensionalnetworkstructureof[K(18-C-6)]complexsegmentsand[Cd(nmt)2]complexsegmentbridgedbyS-K-S,S-K-NandN-K-Ninteractionsbetweenadjacent[K(18-C-6)]and[Cd(mnt)2]units.
简介:Thedefectchangesin6H-SiCafterannealingand10MeVelectronirradiationhavebeenstudiedbyusingavariable-energypositronbeam.Itwasfoundthatafterannealing,thedefectconcentrationinn-type6H-SiCdecreasedduetorecombinationwithinterstitials.Whenthesamplewasannealedat1400℃for30mininvacuum,a20-nmthicknessSilayerwasfoundonthetopoftheSiCsubstrate,thisisadirectproofoftheSiatomsdiffusingtosurfacewhenannealedathightemperaturestages.After10MeVelectronirradiation,forn-type6H-SiC,theSparameterincreasedfrom0.4739to0.4822,andtherelativepositron-trappingratewasabout27.878timesoftheoriginsample,thisshowsthattherearesomedefectscreatedinn-type6H-SiC.Forp-type6H-SiC,itisveryunclear,thismaybebecauseoftheoppositechargeofvacancydefects.
简介:Theeffectsofinterfacialmodifieronthemechanicalpropertiesofkaolin-filledpolyamide6(PA6)havebeenstudied.Theinterracialinteractionbetweenpolyamide6andkaolinhasbeencharacterizedbymeansofinfraredspectroscopy(IR)andscanningelectronmicroscopy(SEM).TheresultsshowthattheroleoftheinterracialmodifierliesinforminganelasticinterlayerwithgoodadhesionbetweenkaolinandPA6.Acompositewithhighimpactstrength,hightensilestrengthandhighelasticmoduluscanbeobtainedbyinsertingtheelasticinterfacialmodifierintotherigid-particle-filledpolymersystem.
简介:GeneralizedSteiriertriplesystems,GS(2,3,n,g),areequivalenttomaximumconstantweightcodesoveranalphabetofsizeg+1withdistance3andweight3inwhicheachcodewordhaslengthn.ThenecessaryconditionsfortheexistenceofaGS(2,3,n,g)are(n-1)g≡0(mod2),n(n-1)g2≡0(mod6),andn≥g+2.Thesenecessaryconditionsareshowntobesufficientbyseveralauthorsfor2≤g≤11.Inthispaper,threenewresultsareobtained.First,itisshownthatforanygiveng,g≡0(mod6)andg≥12,ifthereexistsaGS(2.3.n.g)foralln,g+2≤n≤7g+13.thenthenecessaryconditionsarealsosufficient.Next,itisalsoshownthatforanygiveng,g≡3(mod6)andg≥15,ifthereexistsaGS(2,3,n,g)foralln,n≡1(mod2)andg+2≤n≤7g+6,thenthenecessaryconditionsarealsosufficient.Finally,asanapplication,itisprovedthatthenecessaryconditionsfortheexistenceofaGS(2,3,n,g)arealsosufficientforg=12,15.
简介:DimerizationConstantDeterminationof6-O-Benzoyl-β-CyclodextrininAqueousSolution.DimerizationConstantDeterminationof6-O-Benzoyl?..
简介:Inthispaper,ageneralsolutionforthree-dimensionalstaticpiezothermoelasticprob-lemsofcrystalclass6mmsolidsispresented.Tnegeneralsolutioninvolvesfourpiezoelasticpotentialfunctionsandapiezothermoelasticpotentialfunction,ofwhichfourpiezoelasticpotentialfunctionsaregovernedbyweightedharmonicdifferentia[equations.ComparedwiththegeneralsolutiongivenbyAshidaetal.,inwhichsevenpotentialfunctionsareintroduced,thegeneralsolutionproposedinthepresentpaperismorerigorouslyderived.Moreover,ithasasimpleformandisconvenientforappli-cation.Asanillustrativeexample,theproblemofapyroelectrichalf-spacesubjectedtoaxisymmetricheatingisstudied.Numericalresultsofdisplacements,stresses,electricpotentialandelectricdisplace-mentsareobtainedforacadmiumselenidehalf-space.Thermallyinduceddisplacementsandstressdis-tributionarecomparedwiththoseobtainedforthesamematerialwithoutpiezoelectricandpyroelectriceffects.
简介:Poly-3-methylthiophene(P3MT)在房间温度被综合离子的液体1-butyl-3-methylimi-dazoliumhexafluorophosphate([BMIM]PF6)由经常的潜在、经常的电流分别地。P3MT电影的结构和形态学被FTIR光谱和SEM描绘。undoped(减小)并且做(氧化)在离子的液体准备的P3MT电影的形式可逆、稳定。P3MT电影有维生素酸和罐头的electrocatalytic氧化的强壮的特征分开维生素酸和多巴胺的氧化山峰。潜在的步的二个方法被用来观察这部电影的反应时间,这部电影被发现有完美的electrochromic反应。