简介:[1]BASFUSP4479906[2]BASFBP1443541[3]BASFDE3618265[4]WangL.,WuZ.,ChinaLeather,26(8),11,(1997)[5]YuanL.,DinY.,ChineseChemistryBulletin,(2),19(1988)[6]KurokiH.,ChemistryofDyeingTheory(ChineseTranslation),TextileIndustryPress,Beijing,89(1982)[7]WangS.,LiP.,WuZ.DyestuffIndustry(Chinese),34(4),1,(1997)[8]Tian,Y.,Wu,Z.,Wang,G.,Zhang,S.J.ChineseChem.Eng.,46,156(1995)[9]Tian,Y.,Wang,G.,Wu,Z.,J.ChineseChem.Eng.,47,75(1996)[10]Lycka,A.,DyesandPigment,32,11(1996)[11]Griffith,J.,ColourandConstitutionofOrganicMolecules,AcademicPress,London,191(1976)
简介:Dibromobiphenylreactedwithcynomethylanioninammoniaunderirradiationtoformnucleophilicbis-substitutedproductinhighyieldwithoutsubstantialmonosubstitutedproduct.Quantumyieldsfortheformationsofbis-andmonosubstitutedproductswerefoundtobe85.6and2.3×10-6respectively,whilethecorrespondingpseudo-first-orderrateswere6.9×10-3and5.2×10-10mol.L-1.S-1.Blockupthepossibleelectrontransferof4-brome-4’-cyanomethylbiphenylylradicalanionto4-cyanometbyl-biphenylylradicalandbromineion.
简介:Weexperimentallydemonstratea4×4nonblockingsiliconthermo-optic(TO)switchfabricconsistingofthreestagesoftunablegeneralizedMach–Zehnderinterferometers.All24routingstatesfornonblockingswitchingarecharacterized.Thedevice’sfootprintis4.6mm×1.0mm.Measurementsshowthattheworstcrosstalkofallswitchingstatesis-7.2dB.Theon-chipinsertionlossisintherangeof3.7–13.1dB.TheaverageTOswitchingpowerconsumptionis104.8mW.
简介:Thesynthesisofopen-fiameworkmetalphosphateshasbeenasubjectofintenseresearchowingtotheirinterestingstructuralchemistryandpotentialapplicationsasionexchangers,catalystsandadsorbents.Alargenumberofthesematerialsaresynthesizedinthepresenceoforganicaminesasstructure-directingagents.Recently,manyresearchactivitieshavefocusedonthesynthesisofinorganic-organichybridframeworks.Ascomparedwithinorganicligands,theadvantageofusingorganicmultidentateligandsistheefficacyofrationaldesignofcrystallinesolidsthroughtheircoordinatingpropensitiesandgeometries.
简介:Thesynthesisandphasebehaviorofaseriesof4’-alkyloxy-4-hydroxybiphenylswerediscribed.Theeffectsofreactionconditionsontheyieldsofproductswereinvestigated.Thecharacterizationsofthermotropicliquidcrystallineproductsforthetypeandthermalpropertiesarediscussedthroughtheuseofdifferentialscanningcalorimetry,polarizingmicroscopy.
简介:Reactionsofthe6-hydroxy-thiopyrano[3,4-c]pyridine-5-carbonitrilederivative1withα-halo-carbonylcompoundsgavetheortho-substitutedintermediates2a-cwhichwereconvertedintofuro[2,3-b]thiopyrano[4,3-d]pyridines3a-cbyfusionofafuranmoietyunderbasicconditions.Furthercyclizationof3a-cledtoafusionofapyrimidinering,yieldingthetetracyclicproducts6,7and8.Inaddition,condensationof6withvariousaromaticaldehydesaffordedthecorrespondingimines9a,b.Mannichreactionof7gaveproducts10a,b.
简介:Thestructureofpolyimidefrom1,4-bis(3’,4’-dicarboxyphenoxy)benzeneand4,4’-oxydianilinefilmspecimensbeforeandafterhotstretchinghasbeeninvestigatedbyWAXD,DSCandFTIR.AsevidencedbyboththeWAXDandDSCresults,itcouldbebelievedthatstraininducedcrystallizationdidtakeplaceafterhotstretching.Meanwhile,shiftingpositionandsplittingofsomebandpeaksexistedontheFTIRspectrogramswereexplainedintermsoftheclosepackingofchainsandthechangesofinter-molecularcharge-transferinteractionbetweenimidegroupsandaromaticgroupsuponcrystallization.
简介:On △I=4 Bifurcation PhenomenaOn△I=4BifurcationPhenomena¥ZhangJingye;YangSunandMikeGuidryTheexperiments-bythenew7--raydetector...
简介:Emissionquenchingof[Ru(bpy)2(4,4’-dcbpy)](PF6)2(1)bybenzenamine,4-[2-[5-[4-[4-dimethylamino]phenyl]-4,5-di-hydro-1-phenyl-1H-pyrazol-3-yl]-ethenyl]-N,N-dimetyl(2)or1,5-diphenyl-3-(2-phenothiazine)-2-pyrazoline(3)wasobserved.Measurementsoftheemissiondecayof1beforeandafteradditionof2or3bysinglephotoncountingtechniquecon-finnedtheobservations.Theemissionquenchingof1by2or3wassubmittedtoStern-Volmerequation.Itwascalculatedthatthequenchingrateconstants(kq)are5.5×109(mol/L)-1s-1for2and4.0×109(mol/L)-1s-1for3,respectively.Theseresultsindicatedacharacterofdynamicquenchingprocess.Thesinglet-stateof2or3wasalsoquenchedby1.ThequenchingbehaviorsdidnotconformtotheStern-Volmerequationandinvolvedbothstaticanddynamicquenchingprocesses.Theapparentquenchingrateconstant(kapp)wascalculatedtobe3×109(mol/L)-1fortheinteractionofexcited2with1,and1.2×109(mol/L)-1forthatofexcited3wit
简介:Therearemoreandmorecountriestoakeanefforttothestudiesofvanadiumalloyforfusionapplication.NIFSinJapanhasrecentlydevelopedan80kgheatV4Cr4Tialloy(NIFS-heat2)aftertheproductionofa500kgscaleV4Cr4TiinU.S.severalyearsago.PropertyevaluationofthealloyhasbeenputintoaninternationalcollaborationprogramunderthecoordinationofIEA(InternationalEnergyAgency).SWIPhasjoinedthecollabrationonthehydrogenembrittlementresistanceevaluationofthealloyt.
简介:让x:Mn是有非零主管弯曲的脐的免费hypersurface。然后,x与Laguerre公制的g被联系,Laguerre张肌\mathbbL\mathbb{L},Laguerre形式C,和一个Laguerre秒基础形成\mathbbB\mathbb{B}它是在Laguerre下面的x的invariants转变组。如果它的Laguerre形式消失,hypersurfacex被称为Laguerreisoparametric并且\mathbbB\mathbb的特征值{B}是不变的。在这份报纸,我们在4分类所有Laguerreisoparametrichypersurfaces。
简介:SinceitserliestyearsofR&D[1],theGEANT4simulationtoolkithasbeendevelopedfollowingsoftwareprocessstandardswhichdictatedtheoverallevolutionoftheproject.Thecomplexityofthesoftwareinvolved,thewideareasofapplicationofthesoftwareproduct,thehugeamountofcodeandCategorycomplexity,thesizeanddistributednatureoftheCollaborationitselfareallingredientswhichinvolveandcorrelatetogetherawidevarietyofsoftwareprocesses.Althoughin"production"andavailabletothepublicsinceDecember1998,theGEANT4softwareproduct[1]includesCategoryDomainswhicharestillunderactivedevelopment.Thereforetheyrequiredifferenttreatmentalsointermsofimprovementofthedevelopmentcycle,system,testingandusersupport,ThisarticleismeanttodescribesomeofthesoftwareprocessesastheyareappliedinGEANT4forbothdevelopment,testingandmaintenanceofthesoftware.