简介:Chalcopyrite-typeCuInSe2nanoparticlesaresuccessfullypreparedbyusingIn2Se3nanoparticlesasaprecursorreactedwithcopperchloride(CuCl)solutionviaaphasetransformationprocessinlowtemperature.Thereactiontimeisakeyparameter.Afterthereactiontimeincreasingfrom0.5hto8h,In2Se3andCuClreactwitheachothergraduallyviaphasetransformationintoCuInSe2withoutanyintermediatephase.ThecrystallinestructureandmorphologyoftheCuInSe2nanoparticlesarecharacterizedbyX-raydiffraction(XRD)andfieldemissionscanningelectronmicroscopy(FESEM).ThediameterofCuInSe2nanoparticleswithgooddispersibilityrangesfrom10nmto20nm.ThebandgapoftheCuInSe2nanoparticlesis1.04eVcalculatedfromtheultraviolet-visible(UV-VIS)spectrum.
简介:Inthispaper,wedemonstratetheacetylehe(C2H2)sensorwithhighsensitivityusingahollow-corephotonicbandgapfiber(HC-PCF).ExperimentsformeasuringC2H2concentrationsingasmixtureareperformed.Usinga2m-longHC-PCFasgascell,thespectrumofacetyleneatn1+n3bandhasbeenmeasured,andtheP11-branchhasbeenselectedforthepurposeofsensing.Aminimumdetectivityof143partspermillionbyvolume(ppmv)forthesystemconfigurationisestimated.
简介:一个透明的3-巯基丙基三甲氧基硅烷(MPTMS)/银/氧化钼复合阳极制备绿色有机发光二极管(OLED)。研究了亮度复合阳极和有机电致发光器件的工作电压的影响。通过优化各层的MPTMS/银/氧化钼结构的厚度,对MPTMS/银的透光率(8nm)/MoO3(30nm)达到75%以上在520nm左右。的薄层电阻为3.78?/□,与此相应的MPTMS/Ag(8nm)/MoO3(30nm)的结构。为优化阳极的有机电致发光器件的电致发光(EL),最大电流效率达到4.5cd/A,最大亮度是37和036cd/m2。此外,通过优化阳极的有机电致发光器件具有非常低的工作电压(2.6V)获得100cd/m2的亮度。我们认为,改进的设备性能主要是由于增强的空穴注入造成的减少孔注入势垒高度。我们的研究结果表明,使用MPTMS-SAMs/银/氧化钼作为复合阳极可以在低工作电压和高亮度OLED的制作一个简单的和有前途的技术。
简介:srzn2(PO4)2:在大气中的高温固相反应合成Sm3+荧光粉。srzn2(PO4)2:Sm3+荧光粉是通过紫外光有效激发(UV)和蓝色光,和发射峰被分配到2-6h54G5//2过渡(563nm),2-6h74G5//2(597nm和605nm)和2-6h94G5//2(644nm和653nm)。对srzn2发射强度(PO4)2:Sm3+的Sm3+浓度的影响,其浓度猝灭效应srzn2(PO4)2:钐也观察到。当掺杂离子(=Li,Na和K)离子的发光强度,srzn2(PO4)2:Sm3+可以明显增强。在国际照明委员会(CIE)的srzn2色坐标(PO4)2:Sm3+定位在橙红色的区域。结果表明,该荧光粉具有潜在的应用在白光发光二极管(LED)。
简介::Twonovelpoly[(3-alkyhhiophene-2,5-diyl)-(benzylidenequinomethane-2,5-diyl)s]derivatives,poly[(3-butylthiophene-2,5-diyl)-(p-N,N-dimethylamino)benzylidenequinomethane-2,5-diyl)](PBTDMABQ)andpoly[-(3-octylthiophene2,5-diyl)-(p-N,N-dimethylamino)benzylidenequinomethane-2,5-diyl)](POTDMABQ),weresynthesized.Thebandgapsofthetwopolymersarecalculatedas1.75eVforPBTDMABQand1.69eVforPOTDMABQ,respectively.Thehomogenousfilmsofthetwopolymerswerepreparedandtheirthird-ordernonlinearopticalpropertieswerestudiedbythebackwarddegeneratefour-wavemixingat532nm.Byusingtherelativemeasurementtechnique,thethird-ordernonlinearopticalsusceptibilitiesofPBTDMABQandPOTDMABQarecalculatedas5.62×10^-9and1.22×10^-8ESU,respectively.Itisfoundthatsubstitutedalkygroupshavestrongeffectsonthebandgapandnonlinearopticalpropertiesofthetwopolymers.Therelativelybigthird-ordernonlinearopticalsusceptibilitiesandsmallbandgapofPOTDMABQresultedmainlyfromthelongeralkylwithstrongelectron-donatingabilitycanenhancethedelocationdegreeofconjugatedπelectronics.