简介:利用化学多元醇法合成Gd2O3:Tb^3+纳米粒子,通过对NaOH的加入速率的控制,能将纳米粒子的直径从1-2nm能增大到4nm。利用透射电子显微镜,紫外分光光度计对Gd2O3:Tb^3+纳米粒子的形貌和尺寸、发光进行表征分析。结果表明:分多次加入NaOH比一次性加入NaOH能获得更大尺寸的Gd2O3:Tb^3+纳米粒子。
简介:Single-gritgrindingofa2.5Dwovencompositewasinvestigatedbythefinite-elementmethod(FEM)usingaunit-cellmodel.Accordingtoourhypotheses,theaxisofthewarpyarnwasasinusoidalcurveandthecrosssectionoftheweftyarnwasshapedlikeabiconvexlens.AVUMATsubroutinewasusedtoconstructtheconstitutivemodelofthe2.5Dwovencomposite.ThegrindingprocessofthecompositewasanalyzedusinganFEMsimulationwiththeABAQUS/Explicitsoftware.Avalidationexperimentwasalsocarriedout.Thesimulationresultsshowedthatagrindingcrackwaswellsimulated.Furthermore,thejunctionsbetweenthewarpyarnandweftyarnwerefoundtobeseriouslydamagedandcrackswereobservedtoextendoutwardalongthewarpfiberduringgrinding,ingoodagreementwiththeexperimentalresults.Inaddition,thestrainofweftyarnswasobviouslygreaterthanthatofwarpyarnswhenthegrindingdirectionwasperpendiculartotheweftyarnsandparalleltotheaxisofthewarpyarns.Theseresultsdemonstratethatthemesostructurestronglyinfluencesthegrindingdamageinflictedonwovencomposites.
简介:用正丁醇和柠檬酸为原料,WO3/MOO3/SiO2为催化剂催化合成柠檬酸三丁酯。通过考察醇与酸的物质的量比,反应温度和反应时间,催化剂用量和溶剂用量对酯化反应的影响。确定合成柠檬酸三丁酯的最佳反应条件为n(正丁醇)/n(柠檬酸)=4.5,催化剂用量为反应物柠檬酸质量的6%,反应温度130—140℃,反应时间3.5h,酯化率最高达98.5%,产率最高迭94.3%。WO3/MOO3/SiO2催化剂可重复使用,其催化活性基本不变。实验对合成的产品进行了红外光谱分析及折光率的测定,与文献值相符。